Function of sulfur dioxide in the kinetic mechanism of oxidation of carbon

Retardation of the gasification reaction of carbon with oxygen by SO₂ was observed. Rates of oxidation were determined by thermal gravimetric analysis (TGA) of a nuclear graphite in the temperature range of 550–700°C, and of a coconut charcoal in the temperature range of 400–505°C. The oxidant gases were dry air containing 0–6% SO₂. Reduction of the rate by SO₂ varied with burn-off. Differential thermal analysis (DTA) was also applied to detect the retardation effect of SO₂. The technique of infrared internal reflection spectroscopy (IRS) was used to examine the surface species of reacted charcoal samples. Absorption bands were assigned to surface carbonyls, lactones, and a chemisorbed SO₂ in the form of sulfate. Chemisorption of SO₂ was attributed to cause the retardation of the oxidation reaction.     

蜕变测试和断言检查的比较与实验研究

在软件测试中,测试预言是一种用于检查程序在测试中是否正常运行的机制.然而在某些实际情况下,还无法制定测试预言或者难以有效地应用测试预言.针对此类测试预言问题,蜕变测试于近年应运而生,但蜕变测试的效率问题还没有被充分地加以研究.作者用控制实验的方法研究了使用蜕变测试的成本及效率,进而将蜕变测试和常用的断言检查两种方法的错误检测率和时间成本进行了比较和分析.实验结果表明,相比于断言检查方法,蜕变测试具有检测到更多错误的潜力.通过分析蜕变测试的效率和性能,与断言测试相比,蜕变测试的错误检测率更高效而效率有待提高,可适用于较为粗粒度的测试需求.     

Computing integrals over polynomially defined regions and their boundaries in 2 and 3 dimensions

We use the cylindrical algebraic decomposition algorithms implemented in Mathematica to produce procedures to analytically compute integrals over polynomially defined regions and their boundaries in two and three dimensions. Using these results, we can implement the divergence theorem in three dimensions or the Green's theorems in two dimensions. These theorems are of central importance in the applications of multidimensional integration. They also provide a strong correctness test for the implementation of our results in a computer algebra system. The resulting software can solve many of the two and some of the three dimensional integration problems in vector calculus textbooks. The three dimensional results are being extended. The results in this paper are being included in an automated student assistant for vector calculus.     

Experimental study of laser recording and heterodyne detecting of microstructures in volume media

Results of an experimental study of a two-beam laser method of recording and heterodyne detection of elementary microstructures (microgratings) in “thick” recording media are described. The study is performed on iron-doped lithium niobate crystals and on thick photopolymer materials in the single-photon absorption mode. The size of the volume micrograting is demonstrated to depend on the operating wavelength, numerical aperture of the focusing microobjective, and refractive index of the medium. The experiments are performed with microgratings 1.0 × 1.4 × 5.7 μm in the X, Y, and Z directions, respectively. Characteristics of individual microgratings and matrices of microgratings recorded at different depths of recording media are given.     

Chiasma interference as a function of genetic distance

For many organisms, meiotic double crossing over is less frequent than expected on the assumption that exchanges occur at random with respect to each other. This "interference," which can be almost total for nearby intervals, diminishes as the intervals in which the double crossovers are scored are moved farther apart. Most models for interference have assumed, at least implicitly, that the intensity of interference depends inversely on the physical distance separating the intervals. However, several observations suggest that interference depends on genetic distance (Morgans) rather than physical distance (base pairs or micrometers). Accordingly, we devise a model in which interference is related directly to genetic distance. Its central feature is that recombinational intermediates (C's) have two fates--they can be resolved with crossing over (Cx) or without (Co). We suppose that C's are distributed at random with respect to each other (no interference); interference results from constraints on the resolution of C's. The basic constraint is that each pair of neighboring Cx's must have between them a certain number of Co's. The required number of intervening Co's for a given organism or chromosome is estimated from the fraction of gene conversions that are unaccompanied by crossover of flanking markers. The predictions of the model are compared with data from Drosophila and Neurospora.     

Self-Reported Gambling-Related Suicidality Among Gambling Helpline Callers.

Problem gamblers often attribute suicidal ideation or attempts to their gambling. Logistic regression analyses were applied to data from problem gamblers (N = 986) calling a helpline. Problem gamblers reporting gambling-related suicidality (n = 252; 25.6%) were more likely than those denying it (n = 734; 74.4%) to acknowledge family, financial, legal, and mental and substance-related problems. Of problem gamblers acknowledging gambling-related suicidality, those reporting gambling-related suicide attempts (n = 53; 21.5%) were more likely than those denying them (n = 193; 78.5%) to acknowledge gambling-related illegal behaviors, mental health and substance abuse treatment, and family histories of alcohol problems, and were less likely to report prior gambling treatment. The findings suggest that increased gambling severity is associated with gambling-related suicidality. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Neighborhood Cohesion as a Buffer Against Hostile Maternal Parenting.

This study explored the moderating effects of children's neighborhoods on the link between hostile parenting and externalizing behavior. Participants were 1st- or 2nd-grade children in an urban northeastern community. Children were administered the Parenting and Neighborhood scales of the Child Puppet Interview, and mothers completed questionnaires on neighborhood quality and parenting practices. Census tract measures of neighborhood quality and teachers' reports of children's externalizing behavior also were obtained. Results indicated that children's and mothers' perceptions of neighborhood involvement-cohesion buffered the link between hostile parenting and externalizing problems. Children's externalizing behavior was unrelated to census tract variables. Findings highlight the protective effect of neighborhood social cohesion and the utility of including young children's perspectives in research on neighborhoods and families. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Controlled microtribology of a metal oxide surface

The rational control of the friction and wear (damage) of engineering, as opposed to model, surfaces under practical conditions such as high contact pressures has long been a technological challenge with much fundamental interest. Lubricant fluids and physisorbed surfactant monolayers (boundary lubricants) are effective friction modifiers but often fail at high loads. We show that the chemisorption of a suitably designed single-chained phosphonate surfactant onto crystalline α-alumina surfaces produces robust protective monolayers that significantly reduce the friction forces and wear even at high loads. The mechanisms are explained, which point to some general principles that offer a basis for scale-up in many different engineering systems. This revised version was published online in June 2006 with corrections to the Cover Date.     

Mapping of coastal-water turbidity using LANDSAT imagery

Secchi disk depth was recorded in the field all along the Swedish coastline and compared with LANDSAT data. Chromaticity analysis was applied in the evaluation to allow for Sun angle and atmospheric corrections. The data were used to study the relative nutrient and solids loading situations around the Swedish coast and as a basis for the applicability of laser bathymetry for water depth soundings