A new interpretation of interferometric fringe patterns

The interferometric method of Nisida and Saito, the absolute retardation method of Post and the double-exposure holo-interferometric method of Hovanesian, Brcic and Powell are correlated and shown to give identical fringe patterns as regards intensity. Various discrepancies in Nisida and Saito's interpretation of their fringe patterns are pointed out, and the simultaneous presence and relative predominance of isochromatic and isopachic half-tones are discussed. The principles of photography and the concept of half-tones are used to explain the formation of concomitant isochromatics and isopachics and to give a new interpretation to these fringe patterns.     

Graft copolymerization onto starch. II. Grafting of acrylonitrile to granular native potato starch by manganic pyrophosphate initiation. Effect of reaction conditions on grafting parameters

The effect of reaction conditions on the composition of native potato starch–polyacrylonitrile graft copolymers initiated by manganic pyrophosphate onto starch slurries at 30°C has been examined. In general, when the Mn³⁺ ion concentration was increased from 0.15 × 10^?3M to 3.0 × 10^?3M (other conditions kept constant), an increase in conversion of monomer to polymer and % add-on was observed, whereas frequency of grafts (anhydroglucose units, AGU, per grafted chain) decreased. Also, the average molecular weights of grafts showed a decrease from 2.2 × 10⁵ to 1.5 × 10⁵. Increasing the concentration ratio of starch to monomer during polymerization by a factor of 3 produced an increase in the conversion of monomer to polymer, whereas an increase in frequency of grafts (AGU/chain) was obtained. Values of % add-on and average molecular weights of the grafts showed, however, a decreasing tendency. It was observed that grafting onto starch took place readily even at acid additions as low as 10 × 10^?3M H₂SO₄ (pH ?1.8). Selective solvent extraction of homopolymer and extremely low conversions of monomer to polymer (0.1%–1.5%) in duplicate runs without addition of starch indicated that grafting efficiencies were high in all cases. An attempt has been made to interpret the results in terms of variations in factors such as initial ratio of (Mn³⁺)/(AGU), termination rate of acrylonitrile chain radicals by oxidation by Mn³⁺ ions, oxidation rate of radicals formed on anhydroglucose units by Mn³⁺ ions, and physical factors such as diffusion rate of Mn³⁺ ions through the polyacrylonitrile-grafted starch granules for terminating the radicals.     

An optimization study for preventing silica gelation and improving filtration effectiveness during pH reduction of high concentration silica solutions

The steam generation processes at the steam-assisted gravity drainage facilities result in huge quantities of wastewater streams, which are characterized by high pH and high silica levels. These concentrated streams need to be neutralized before their disposal via down-hole injection. The neutralization of these high-pH brines results in the formation of a gel-like substance, which makes it difficult to filter the amorphous silica gel. The wastewater used in this study was synthetically prepared using sodium metasilicate to mimic high-concentration silica solutions. Our experiments did not show any advantage of a two-step pH-neutralization process over the single-step process for suppressing silica gelation. A systematic experimental campaign was undertaken to investigate the effects of SiO₂ concentration, NaCl:SiO₂ ratio, and pH on the residual silica concentration, percent silica removal, filtration rate, and filtration effectiveness. For NaCl:SiO₂ ratios higher than 4.5, silica precipitation during pH reduction did not lead to the formation of gel or sol. The response surface methodology (RSM), based on the Doehlert design of experiments, was implemented to optimize the responses and provide high efficacy with fewer experiments. The results from the analysis of variance (ANOVA) analyses of the experimental data were used to evaluate the significance of each term in the quadratic model. 3D response surfaces and 2D contour plots were generated for determining the optimal ranges of independent factors for achieving the maximum silica removal, the highest filtration rate, the best filtration effectiveness, and the minimum residual silica concentration. An optimum operating region was established from the RSM analysis and overlay plot.     

POLYELECTROLYTE MULTILAYER STAMPING IN AQUEOUS PHASE AND NON-CONTACT MODE

Polyelectrolyte multilayer (PEM) transfer printing has been previously achieved by stamping under dry conditions. Here, we show for the first time, that PEM can be transferred from a stamp to the base substrate under aqueous conditions whereby the two surfaces are in a non-contact mode. Degradable multilayers of (PAA/PEG)(10.5) followed by non-degradable multilayers of (PDAC/SPS)(80.5) were fabricated under acidic pH conditions on either PDMS or glass (stamp), and subsequently transferred over top of another multilayer prepared on a different substrate (base substrate), with a spacing of ~ 200 μm between the stamping surface and the base substrate. This multilayer transfer was performed under physiological pH conditions. This process is referred to herein as non-contact, aqueous-phase multilayer (NAM) transfer. NAM transfer can be useful for applications such as fabricating three-dimensional (3-D) cellular scaffolds. We attempted to create a 3-D cellular scaffold using NAM transfer, and characterized the scaffolds with conventional and fluorescence microscopy.     

Measurement of intrinsic rates for homogeneous gas‐phase reactions at high temperatures

A coiled quartz tubular reactor has been designed to measure the intrinsic reaction kinetics for homogeneous reactions at high temperatures up to 1100°C. Actual gas residence times were less than 100 ms. A simple and well‐studied test reaction (i.e., the decomposition of nitrous oxide, N₂O), with published intrinsic kinetics, was used to verify the operation of the experimental reactor. For this system, Peclet numbers (Pe = uL/DL) computed from experimental conversion data were greater than 1000, indicating that the plug flow assumption could be used with this reactor system to determine intrinsic rate expressions with errors of less than 5% for the conditions studied.     

Investigation of wax deposit ‘sloughing’ from paraffinic mixtures in pipe flow

Deposit ‘sloughing’ from ‘waxy’ crude oils has been described in the literature as a possible mechanism, leading to partial or complete dislodging of the deposit from the pipe wall due to changes in flow parameters. A bench‐scale flow loop apparatus was used to investigate ‘sloughing’ with prepared single‐phase ‘waxy’ mixtures of a multicomponent paraffinic wax dissolved in a multicomponent solvent. Experiments were performed to study the changes in the deposit‐layer thickness due to step increments in the ‘waxy’ mixture flow rate, the mixture temperature, and the coolant temperature. It was observed that the deposit‐layer thickness decreased with an increase in each of the three parameters; however, a complete or sudden dislodging of the deposit‐layer did not occur in any of the experiments. A steady‐state heat‐transfer model was used to predict the variation in the deposit mass or thickness due to changes in the selected parameters. In each case, the step‐wise decrease in the deposit thickness, as observed experimentally, was predicted to be caused by changes in the thermal resistance and/or thermal driving force.     

Nanofiber organic semiconductors: The effects of nanosize on the electrical charge transport and optical properties of bulk polyanilines

The electrical transport, optical, and microstructural properties of bulk polyaniline (PANI) and nano‐PANIs were investigated. A field emission scanning electron microscopy (SEM) image of bulk PANI showed macroscopic and aggregated granular particles. A SEM image of the nanostructured PANI showed the formation of one‐dimensional nano/microstructures. The formation of nanofibers was observed from the transmission electron microscopy image. The electrical conductivities of the bulk and nanostructured PANIs increased with increasing temperature, which indicated semiconductor behavior. The electrical conductivities of the bulk and nanostructured PANIs at room temperature were found to be 2.12 × 10^?5 and 1.80 × 10^?2 S/cm, respectively. The electrical conductivity of the nanostructured PANI was about 850 times higher than that of the bulk PANI. The obtained band gaps of the bulk and nanostructured PANIs were determined from diffuse reflectance measurements and were found to be 3.27 and 2.41 eV, respectively. The refractive index of the PANI samples changed from 1.3 to 1.61. The obtained results indicate that the electrical and optical properties of the PANI were inherently dependent on the nanostructure. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Synthesis of High Coercivity Core–Shell Nanorods Based on Nickel and Cobalt and Their Magnetic Properties

Hybrid magnetic nanostructures with high coercivity have immense application potential in various fields. Nickel (Ni) electrodeposited inside Cobalt (Co) nanotubes (a new system named Ni @ Co nanorods) were fabricated using a two-step potentiostatic electrodeposition method. Ni @ Co nanorods were crystalline, and they have an average diameter of 150 nm and length of ~15 μm. The X-ray diffraction studies revealed the existence of two separate phases corresponding to Ni and Co. Ni @ Co nanorods exhibited a very high longitudinal coercivity. The general mobility-assisted growth mechanism proposed for the growth of one-dimensional nanostructures inside nano porous alumina during potentiostatic electrodeposition is found to be valid in this case too.     

Chemical and nutritional quality of silage made from raw or cooked lizard fish (Saurida undosquamis) and blue crab (Portunus pelagicus)

Twelve silages were prepared from uncooked or cooked lizard fish (Saurida undosquamis) and blue crab (Portunus pelagicus) and stored at ambient temperature (30 ± 2 °C) for 60 days. The antioxidative effect of adding ethoxyquin was also investigated. Generally, the nutritional quality of all the silages was stable for up to 60 days of storage and the composition of raw materials was reflected in the composition of the silages. Crab had a lower level of crude protein than fish (85 versus 162 mg kg^?1), but a higher level of ash (96 versus 36 g kg^?1); moreover, there were significant differences in nutritional composition between uncooked and cooked materials. High level of ash in crab required addition of high levels of formic acid in crab‐related silages. At the end of the experiment cooked silages showed a tendency for spoilage; in particular, maggots were observed in cooked crab silages on the last few days of the experiment. Comparison of treatments with or without ethoxyquin showed that only rancidity of fish silage groups was higher without addition of ethoxyquin. Uncooked materials are more suitable for prolonged storage than cooked materials, and it is probably not necessary to add antioxidants to silages made from material with low lipid content. Copyright © 2009 Society of Chemical Industry