Synthesis of High Refractive Index Silicone Materials Incorporating Aromatic Moieties with Adjacent Linkage Groups for Flexible Electronic Displays

The refractive index study of copoly(arylene-siloxane)s constructed with amide, ester, or ether linkage units was conducted to synthesize a step-growth polymer for application in flexible displays. The copoly(arylene-siloxane) based materials have potential use in optical applications due to their durability, flexibility, and possession of good optical clarity properties when compared to conventional silica-filled polydimethylsiloxane-based materials. Measurement of refractive index (RI) was used as the main mode of analysis due to its direct correlation to optical clarity and material flexibility. Synthesis and characterization, including RI compiled data, was performed for six series of step-growth polymers. Effects of different linkage units, namely amides, esters, and ethers, adjacent to at least one six-membered cyclic unit (aromatic or aliphatic) were evaluated. It was observed that the refractive index of these polymers was directly proportional to the aryl content; however, the influence on RI was not equal across all types of linkage units. The highest RI copolymer, poly(4,4-methylenediphenyl diisocyanate-co-carbinol-terminated polydimethylsiloxane) (MDI-SD1.0k), yielded refractive index 1.470 and molecular weight (M_n) 16,100 g/mol; however, the copolymer poly(toluene-2,4-diisocyanate-co-carbinol-terminated polydimethylsiloxane) (TDI-SD) had the highest RI (1.462) per phenyl content. The 4,4-methylenediphenyl diisocyanate (MDI), toluene-2,4-diisocyanate (TDI), and hydrogenated methylenediphenyl-4,4-diisocyanate (HMDI) amide containing linkages best improved the refractive indices of the materials studied.     

Towards the Remote Sensing of Matorral Vegetation Physiology: Relationships between Spectral Reflectance, Pigment, and Biophysical Characteristics of Semiarid Bushland Canopies

This study investigates the relationships between the spectral reflectance characteristics and the concentrations of photosynthetic pigments and biophysical attributes of a structurally complex, spatially heterogeneous vegetation canopy with varying background properties. A field experiment was performed in the Guadalentin basin, Spain using matorral vegetation canopies dominated by Rosmarinus officinalis, Cistus albidus, and Anthyllis cytosoides. A spectroradiometer was used to record the reflectance of a series of sites at which measurements were made of the concentrations per unit ground area and per unit leaf mass of chlorophyll a and b and the carotenoids, together with leaf area index and percent canopy cover. A range of spectral characteristics was examined which have been found previously to be related to pigment concentrations and biophysical properties of vegetation. For matorral vegetation many of these spectral characteristics were unrelated or only weakly related to canopy properties. However, it was found that pigment concentrations per unit ground area were related to ratios of reflectance in narrow spectral bands within the near-infrared region, ratios of bands within the red region, and characteristics of the amplitude of first derivative spectra in the red edge region. Pigment concentrations per unit leaf mass were correlated with ratios of bands around the nearinfrared “shoulder” and the amplitude of the first derivative in certain visible wavelengths. LAI and percent cover were related to ratios of reflectance in narrow bands on the near-infrared plateau and red edge features of canopy reflectance spectra, as well as with the amplitude of the first derivative in the red edge and visible regions respectively.     

Content-based navigation of music using melodic pitch contours

We describe a system which supports dynamic user interaction with multimedia information using content-based hypermedia navigation techniques, specialising in a technique for navigation of musical content. The model combines the principles of open hypermedia, whereby hypermedia link information is maintained by a link service, with content-based retrieval techniques in which a database is queried based on a feature of the multimedia content; our approach could be described as ‘content-based retrieval of hypermedia links’. The experimental system focuses on temporal media and consists of a set of component-based navigational hypermedia tools. We propose the use of melodic pitch contours in this context and we present techniques for storing and querying contours, together with experimental results. Techniques for integrating the contour database with open hypermedia systems are also discussed.     

Biophysical controls on the directional spectral reflectance properties of bracken (Pteridium aquilinum) canopies: Results of a field experiment

Bracken presents a serious environmental problem in many regions of the world and remote sensing offers the potential of monitoring the invasion and management of this plant. This study evaluates this potential by reporting the results of an investigation of the relationships between the biophysical properties of a bracken canopy and its spectral reflectance and how such relationships are effected by view angle. An experiment was carried out through the bracken growing season at sites in West Sussex, UK. In the principal plane of the Sun, red reflectance becomes lower and relatively less variable with view angle as the canopy develops, while near-infrared reflectance increases and becomes relatively more variable with view angle. As Leaf Area Index (LAI) increases, the variability of the Normalized Difference Vegetation Index (NDVI) with view angle decreases, while the simple ratio vegetation index (SR) behaves in almost the opposite manner. Polar plots, illustrating full directional reflectance distributions, reveal that as the canopy develops the hot spot in red reflectance at the retro-solar angle diminishes, to be replaced by enhanced red reflectance at high zenith angles in the forward-scatter direction. Near-infrared reflectance behaves very differently, as a hot spot at the retro-solar angle becomes more pronounced as the canopy grows. The angular distribution of NDVI and SR varies markedly over the growing season, however both indices are well correlated with canopy biophysical properties for most view angles sampled, apart from the extreme off-nadir. Red edge position was largely insensitive to view angle, but had a good correlation with LAI, as did percenage reflectance at the red edge position.     

Logic and Interaction: Foreword to the Special Issue

Journal of Logic, Language and Information -     

An aide for instruction on integrated engineering design and support

Effective management of engineering information is critically needed for the design of future complex engineering systems. Yet engineers are not trained in engineering data base management concepts. To help address this issue, a prototype integrated design system has been developed for the Air Force to aide research and instruction on key integration concepts, including (1) the use of a shared data base to eliminate redundancies and inconsistencies; (2) the use of a relational data base management system to store, locate, and retrieve data from the shared data base; (3) the development of interfacing programs to act as interpreters between the application programs and the common data base; and (4) the role of executive software to manage the integrated system. Key software used includes a computer-aided design system, a structural analysis program, various graphics packages, and a relational data base management system. To assess system flexibility, additional programs were added to the system. The design of the data base proved to be an important step in this implementation. Several methodologies useful in the design of the data base were investigated and subsequently used to organize the data base for the integrated design system. Results discussed include system development, and applications, as well as the effectiveness of the integrated system's configuration.     

Potentiometric biosensor employing catalytic antibodies as the molecular recognition element

Catalytic antibodies are introduced as an important new class of biomolecules for molecular recognition in biosensors in which the binding sites are continually regenerated by the catalytic reaction of the substrate. Consequently, molecular recognition by catalytic antibodies can yield reversible immunoblosensors. In this example, a prototype potentiometric biosensor is described in which a micro-pH electrode is modified with a catalytic antibody that catalyzes the hydrolysis of phenyl acetate, producing hydrogen ions that can be monitored by the electrode. The reversible response is linear with the log of substrate concentration over a range of 20-500 microM with a detection limit of 5 microM under the conditions of this study. Alternative applications of catalytic antibodies in other biosensor configurations are discussed.