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Molecular design of interfacial layers based on conjugated polythiophenes for polymer and hybrid solar cells
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Judith E Houston Sébastien Richeter Sébastien Clément Rachel C Evans 《Polymer International》2017,66(10):1333-1348
In the past two decades, bulk heterojunction organic photovoltaic (OPV) devices have emerged as attractive candidates for solar energy conversion due to their lightweight design and potential for low‐cost, high‐throughput, solution‐phase processability. Interfacial engineering is a proven efficient approach to achieve OPV devices with high power conversion efficiencies. This mini‐review provides an overview of the key structural considerations necessary when undertaking the molecular design of conjugated polyelectrolytes, for application as interfacial layers (ILs). The different roles of ILs are outlined, together with the advantages and disadvantages of competing classes of IL materials. Particular emphasis is placed on the design and synthesis of water‐soluble polythiophene‐based IL materials and the influence of their structural characteristics on their performance as a promising class of IL material. Finally, the challenges and opportunities for polythiophenes as IL materials for OPV devices and other solution‐processed solar cell technologies (e.g. perovskite solar cells) are discussed. © 2017 Society of Chemical Industry 相似文献
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Tropical Librarianship W. J. Plumbe The Scarecrow Press, Inc. Matuchen, N.J. and London, 1987 相似文献
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Those who have been convicted of crimes are subjected to a stigma that affects many aspects of their social lives. The “felon” label brings collateral consequences that make it difficult to obtain basic human needs, including housing. This study uses the audit method to examine the effects of race, gender, and criminal history on housing outcomes. Testers, exhibiting characteristics suggestive of race and gender and disclosing one of three offenses, placed phone calls to rental property owners across the Midwest to inquire about renting a property. We found powerful negative effects for those with a criminal record seeking apartments, regardless of whether the offense was sexual or drug-related. However, we found no differences between minority and non-minority testers. We explain these findings in the context of housing as an essential resource for formerly incarcerated individuals. 相似文献
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Martin Danaher Conor Shanahan Francis Butler Rhodri Evans Dan O’Sullivan Denise Glynn 《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2016,33(7):1155-1165
A ranking system for veterinary medicinal products and coccidiostat feed additives has been developed as a tool to be applied in a risk-based approach to the residue testing programme for foods of animal origin in the Irish National Residue Control Plan (NRCP). Three characteristics of substances that may occur as residues in food are included in the developed risk ranking system: Potency, as measured by the acceptable daily intake assigned by the European Medicines Agency Committee for Medicinal Products for Veterinary Use, to each substance; Usage, as measured by the three factors of Number of Doses, use on Individual animals or for Group treatment, and Withdrawal Period; and Residue Occurrence, as measured by the number of Non-Compliant Samples in the NRCP. For both Number of Doses and Non-Compliant Samples, data for the 5-year period 2008–12 have been used. The risk ranking system for substances was developed for beef cattle, sheep and goats, pigs, chickens and dairy cattle using a scoring system applied to the various parameters described above to give an overall score based on the following equation: Potency × Usage (Number of Doses + Individual/Group Use + Withdrawal Period) × Residue Occurrence. Applying this risk ranking system, the following substances are ranked very highly: antimicrobials such as amoxicillin (for all species except pigs), marbofloxacillin (for beef cattle), oxytetracycline (for all species except chickens), sulfadiazine with trimethoprim (for pigs and chickens) and tilmicosin (for chickens); antiparasitic drugs, such as the benzimidazoles triclabendazole (for beef and dairy cattle), fenbendazole/oxfendazole (for sheep/goats and dairy cattle) and albendazole (for dairy cattle), the avermectin ivermectin (for beef cattle), and anti-fluke drugs closantel and rafoxanide (for sheep/goats); the anticoccidials monensin, narasin, nicarbazin and toltrazuril (for chickens). The risk ranking system described is a relatively simple system designed to provide a reliable basis for selecting the veterinary medicinal products and coccidiostat feed additives that might be prioritised for residue testing. 相似文献
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