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101.
A new phenolformaldehyde polymer resin containing potential soft‐type donor atoms (sulfur atoms) was synthesized by the reaction of sodium salt of 2,4‐dihydroxyacetophenone formaldehyde resin with carbon disulfide. The resin was characterized by elemental analysis, IR, and 1H‐NMR spectral studies. Because of its insolubility in aqueous media, the resin was successfully used in the removal of Pb(II) and Cd(II). Parameters such as the effect of pH, the effect of time, competitive studies, the effect of initial metal‐ion concentration, and the recyclability of the polymer resin were studied. The amount of metal removed by the resin was determined with atomic absorption spectrophotometry. The retention properties were strongly dependent on pH. The elution of metal ions was investigated in acid media. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1932–1936, 2004 相似文献
102.
Nanocomposites of iron oxide (Fe3O4) with a sulfonated polyaniline, poly(aniline‐co‐aminonaphthalenesulfonic acid) [SPAN(ANSA)], were synthesized through chemical oxidative copolymerization of aniline and 5‐amino‐2‐naphthalenesulfonic acid/1‐amino‐5‐naphthalenesulfonic acid in the presence of Fe3O4 nanoparticles. The nanocomposites [Fe3O4/SPAN(ANSA)‐NCs] were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X‐ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, elemental analysis, UV–visible spectroscopy, thermogravimetric analysis (TGA), superconductor quantum interference device (SQUID), and electrical conductivity measurements. The TEM images reveal that nanocrystalline Fe3O4 particles were homogeneously incorporated within the polymer matrix with the sizes in the range of 10–15 nm. XRD pattern reveals that pure Fe3O4 particles are having spinel structure, and nanocomposites are more crystalline in comparison to pristine polymers. Differential thermogravimetric (DTG) curves obtained through TGA informs that polymer chains in the composites have better thermal stability than that of the pristine copolymers. FTIR spectra provide information on the structure of the composites. The conductivity of the nanocomposites (~ 0.5 S cm?1) is higher than that of pristine PANI (~ 10?3 S cm?1). The charge transport behavior of the composites is explained through temperature difference of conductivity. The temperature dependence of conductivity fits with the quasi‐1D variable range hopping (quasi‐1D VRH) model. SQUID analysis reveals that the composites show ferromagnetic behavior at room temperature. The maximum saturation magnetization of the composite is 9.7 emu g?1. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
103.
Graft copolymerization of 2-hydroxyethyl methacrylate in combination with hydrophobic monomers onto soluble collagen was employed in the synthesis of hydrogels. The hydrogels were formed by simultaneous graft copolymerization and crosslinking. In order to study the effect of various crosslinking agents on the water retention character of the hydrogels, three different crosslinking agents, namely, N,N′-methylene bis acrylamide, 1,4-butanediol dimethacrylate, and hexamethylene urethanediacrylate were used. Hexamethylene urethanediacrylate crosslinked systems require a minimum amount of crosslinking agent to attain maximum water content in comparison to the other systems. 相似文献
104.
Sakina Khatoon Sunki Reddy Yella Reddy 《European Journal of Lipid Science and Technology》2005,107(11):786-791
Speciality plastic fats with no trans fatty acids suitable for use in bakery and as vanaspati are prepared by interesterification of blends of palm hard fraction (PSt) with mahua and mango fats at various proportions. It was found that the interesterified samples did not show significant differences in solid fat content (SFC) after 0.5 or 1 h reaction time. The blends containing PSt/mahua (1:1) showed three distinct endotherms, indicating a heterogeneity of triacylglycerols (TG), the proportions of which altered after interesterification. The SFC also showed improved plasticity after interesterification. Similar results were observed with other blends of PSt/mahua (1:2). These changes in melting behavior are due to alterations in TG composition, as the trisaturated‐type TG were reduced and the low‐melting TG increased after interesterification. The blends containing PSt/mango (1:1) showed improvement in plasticity after interesterification, whereas those containing PSt/mango (2:1) were hard and showed high solid contents at higher temperature and hence may not be suitable for bakery or as vanaspati. The blends with palm and mahua oils were softer and may be suitable for margarine‐type products. The results showed that the blends of PSt/mahua (1:1, 1:2) and PSt/mango (1:1) after interesterification for 1 h at 80 °C showed an SFC similar to those of commercial hydrogenated bakery shortenings and vanaspati. Hence, they could be used in these applications in place of hydrogenated fats as they are free from trans acids, which are reported to be risk factors involved in coronary heart disease. For softer consistency like margarine applications, the blends containing palm oil and mahua oil are suitable. 相似文献
105.
I.H. Farag S.B. Reddy Karri R. Breault K.Y. Tsai 《Chemical Engineering Communications》1986,48(4):331-348
The design of multistage fluidized beds for heat exchange necessitates the solution of the mass and energy balance equations combined with the equilibrium relations for each stage. This paper presents a novel way of applying well known methodology to a different technology, one where it has not been widely applied.
In the present work a McCabe-Thiele type of graphical approach is presented for both counter-current and cross-current contacting multiple fluidized beds. The necessary equations for a multistage calciner are developed and the application of the proposed method is demonstrated. Generalized fluidized bed efficiency for counter-current and cross-current multiple fluidized bed is presented. 相似文献
In the present work a McCabe-Thiele type of graphical approach is presented for both counter-current and cross-current contacting multiple fluidized beds. The necessary equations for a multistage calciner are developed and the application of the proposed method is demonstrated. Generalized fluidized bed efficiency for counter-current and cross-current multiple fluidized bed is presented. 相似文献
106.
Pasupuleti Lakshmi Narayana Xiao-Song Wang Jong-Taek Yeom Anoop Kumar Maurya Won-Seok Bang Ommi Srikanth Maddika Harinatha Reddy Jae-Keun Hong Nagireddy Gari Subba Reddy 《应用聚合物科学杂志》2021,138(37):50956
In the present work, we developed an artificial neural networks (ANN) model to predict and analyze the polycaprolactone fiber diameter as a function of 3D melt electrospinning process parameters. A total of 35 datasets having various combinations of electrospinning writing process variables (collector speed, tip to nozzle distance, applied pressure, and voltage) and resultant fiber diameter were considered for model development. The designed stand-alone ANN software extracts relationships between the process variables and fiber diameter in a 3D melt electrospinning system. The developed model could predict the fiber diameter with reasonable accuracy for both train (28) and test (7) datasets. The relative index of importance revealed the significance of process variables on the fiber diameter. Virtual melt spinning system with the mean values of the process variables identifies the quantitative relationship between the fiber diameter and process variables. 相似文献
107.
Effects of porous carbon on sintered Al-Si-Mg matrix composites 总被引:5,自引:0,他引:5
The influence of microporous particulate carbon char on the mechanical, thermal, and tribological properties of wear-resistant
Al-13.5Si-2.5Mg alloy composites was studied. Large increases in surface area due to the formation of micropores in coconut
shell chars were achieved by high-temperature activation under CO2 gas flow. Activated char particles at 0.02 V
f
were used to reinforce the alloy. The composites were fabricated via a double-compaction reaction sintering technique under
vacuum at a compaction pressure of 250 MPa and sintering temperature of 600 °C. At more than 35% burn-off of the carbon chars
at the temperature of activation, 915 °C, the total surface area remained virtually unaffected. The ultimate tensile strength
and hardness decreased by 23% and 6 %, respectively; with increasing surface area of the reinforcement from 123 to 821 m2g−1. The yield strength and the percentage of elongation decreased by a factor of 2 and 5, respectively. No significant change
in sliding wear rate was observed but the coefficient of friction increased by 13 % (0.61 to 0.69). The coefficient of linear
thermal expansion was reduced by 16 % (11.7 × 10−6 to 9.8 × 10−6 °C−1), and remained unaffected at more than 35 % burn-off. Energy-dispersive spectrometry of the particles of the activated chars
showed that oxides of potassium and copper coated the open surfaces. Failure at the matrix-char interface was observed, and
this was attributed to localized presence of oxides at the interfaces as identified by electron probe microanalysis. Poor
wetting of the oxides by magnesium at the sintering conditions resulted in formation of weak matrix-char interface bonds.
J.U. Ejiofor, formerly of the Department of Metallurgical and Materials Engineering, The University of Alabama 相似文献
108.
109.
Total phosphorus (TP) removal in aged constructed wetlands poses a challenge, especially when treated with swine wastewater with high concentrations of phosphorus (P). Our earlier studies with anaerobic lagoon swine wastewater treatment in constructed wetlands showed a decline in P removal (45-22%) with increased years of operation. These particular wetlands have been treated with swine wastewater every year since the first application in 1997. Preliminary lab-scale studies were conducted to evaluate the efficiency of polyaluminium chloride (PAC) in the removal of phosphate-P (PO4-P) from swine wastewater. The experimental objective was to increase the phosphorus treatment efficiency in constructed wetland by adding PAC as a precipitating agent. PAC was added by continuous injection to each wetland system at a rate of 3 L day(-1) (1:5 dilution of concentrated PAC). Swine wastewater was added from an anaerobic lagoon to four constructed wetland cells (11m wide x 40m long) at TP loads of 5.4-6.1 kg ha(-1) day(-1) in two experimental periods, September to November of 2008 and 2009. Treatment efficiency of two wetland systems: marsh-pond-marsh (M-P-M) and continuous marsh (CM) was compared. The wetlands were planted with cattails (Typha latifolia L.) and bulrushes (Scirpus americanus). In 2008, PAC treatment showed an increase of 27.5 and 40.8% of TP removal over control in M-P-M and CM respectively. Similar trend was also observed in the following year. PAC as a flocculant and precipitating agent showed potential to enhance TP removal in constructed wetlands treated with swine wastewater. 相似文献
110.
Pomeranz Irith Reddy Sudhakar M. 《Dependable and Secure Computing, IEEE Transactions on》2009,6(3):231-240
We describe a method for online testing of delay faults based on the comparison of output responses of identical circuits. The method allows one of the circuits to participate in useful computations during the testing process, while the other circuit must be idle. We refer to this method as semiconcurrent online testing. While unknown input vectors are applied to the circuit that participates in useful computations, the proposed method applies modified vectors to the idle circuit. In this way, different conditions are created for the detection of delay faults, allowing identical delay faults that affect both circuits to be detected. In designing the modified vectors, we ensure that the expected fault-free responses of the two circuits are identical. We also ensure that the hardware for modifying the vectors applied to the idle circuit will be easy to implement on-chip. 相似文献