Stoffaustausch zwischen flüssigem Eisen und Schlacke beim Sprühraffinationsverfahren

Erläuterung des Sprühraffinationsverfahrens, bei dem eine Schmelze mit inertem Gas verdüst wird und die entstehenden Metalltropfen durch eine Raffinationsschlacke fallen. Erörterung der Gesetzmäßigkeiten für die Stoffaustauschvorgänge zwischen Metalltropfen und Schlacke. Bestimmung der mittleren Tropfengröße beim Versprühen von kohlenstoffgesättigtem Roheisen. Untersuchung der Wirkung der Sprühraffination am Beispiel der Entschwefelung des Roheisens mit Schlacken des Systems CaO–CaF₂–Al₂O₃ bei 1600 °C. Ermittlung des Stoffübergangskoeffizienten des Schwefels für den umgekehrt transitorischen Phasenkontakt und Vergleich mit Werten bei anderen Techniken des Phasenkontaktes Metall-Schlacke.     

Effect of rapid solidification and small additions of Zn and Bi on the structure and properties of Sn-Cu eutectic alloy

The Sn-Cu eutectic alloy has been produced by rapid solidification using the melt-spinning technique, and both Zn and Bi have been added individually to it, in the ratio 0.5 wt.%. X-ray diffraction (XRD) analysis and differential thermal analysis (DTA) have been carried out. Resistivity, Vickers microhardness (HV), and yield stress (σ_y) have been measured. Also a new method for measuring creep has been described using a HV tester. The creep measured by this method is termed “microcreep.” It is a quick, nondestructive method and requires a small sample, about 1 cm², with thickness 1 mm or less. The results show that formation of Cu₃₉Sn₁₁ occurs due to the addition of both Zn and Bi. The addition of Zn increases HV and σ_y, but slightly lowers the creep resistance; however, the addition of Bi deteriorates the creep resistance. Also, it is found that the creep rate of as-quenched melt-spun alloys is high.     

Metachromic interactions between azo and triphenylmethane dyes in aqueous solution. II. The effect of organic solvents on the interaction

The interaction between dilute aqueous solutions of the disazo dye Brilliant Orange and the triphenylmethane dye Crystal Violet results in a decrease in the absorption of Crystal Violet in the region 550–600 nm and the appearance of a new absorption at 494 nm. The decrease in absorbance at 590 nm is characteristic of the metachromic interactions of Crystal Violet with a wide variety of polyanion substrates while the increase at 494 nm is due to the conversion of Brilliant Orange from its azo to its hydrazone tautomer. The relative effects of a variety of organic solvents in reversing the interaction has been investigated.     

Determination of the effective mass for highly degenerate copper selenide from reflectivity measurements

An investigation was made of the plasma reflection of light and the results were used to find the effective mass of highly degenerate copper selenide,p>10²⁰ cm^–3, as a function of carrier concentrationp. The study of the temperature dependence of effective mass, electrical conductivity, thermoelectric power and Hall mobility carried out in the present work gives an idea of the nature of the valence bands in these materials.     

LES–ODT study of turbulent premixed interacting flames

The LES–ODT model is implemented for the study of twin turbulent premixed flames in decaying isotropic turbulence. The approach is based on the coupling of large-eddy simulation (LES) for mass and momentum with a fixed 3D lattice of 1D fine-grained solutions based on the one-dimensional turbulence (ODT) model. The ODT solutions for momentum and reactive scalars are designed to capture subgrid scale physics that is not captured by LES. The LES–ODT formulation is capable of capturing important fine-scale processes, such as flame–flame interactions, which play an important role in flame shortening in turbulent premixed flames, and the role of preferential diffusion on curved flames’ structures.     

Determination of Menbutone in Bovine Milk and Meat Using Micellar Liquid Chromatography: Application to Injectable Dosage Forms

A simple, sensitive, and rapid method was developed for the routine identification and quantification of menbutone in different matrices by micellar liquid chromatography. Separation was performed in less than 4 min using a C₁₈ column with UV detection at 234 nm. A micellar solution composed of 0.12 M sodium dodecyl sulfate, 8 % n-butanol, and 0.3 % triethylamine in 0.02 M phosphoric acid at pH 6.0 was used as the mobile phase. The method was fully validated in accordance with International Conference on Harmonization (ICH) guidelines. The limits of detection and quantitation were 0.95 and 2.86 ng mL^?1, respectively. The method showed good repeatability, linearity, and sensitivity according to the evaluation of the validation parameters. The micellar method was successfully applied for the analysis of menbutone in its commercial injections with a mean % recovery value of 99.73?±?1.634 % and in spiked bovine milk and meat samples with a mean % recovery values in the range of 98.00–100.60 %. High extraction efficiency was obtained without matrix interference in the extraction process and in the subsequent chromatographic determination. No organic solvent was used during the pretreatment step. Hence, this method can be considered as an interesting example for green chemistry.     

The effect of hydrogen addition on premixed laminar acetylene–hydrogen–air and ethanol–hydrogen–air flames

In the present work, the laminar premixed acetylene–hydrogen–air and ethanol–hydrogen–air flames were investigated numerically. Laminar flame speeds, the adiabatic flame temperatures were obtained utilizing CHEMKIN PREMIX and EQUI codes, respectively. Sensitivity analysis was performed and flame structure was analyzed. The results show that for acetylene–hydrogen–air flames, combustion is promoted by H and O radicals. The highest flame speed (247 cm/s) was obtained in mixture with 95% H₂–5% C₂H₂ at λ = 1.0. The region between 0.95 < X_H2 < 1.0 was referred to as the acetylene-accelerating hydrogen combustion since the flame speed increases with increase the acetylene fraction in the mixture. Further increase in the acetylene fraction decreases the H radicals in the flame front. In ethanol–hydrogen–air mixtures, the mixture reactivity is determined by H, OH and O radicals. For X_H2 < 0.6, the flame speed in this regime increases linearly with increasing the hydrogen fraction. For X_H2 > 0.8, the hydrogen chemistry control the combustion and ethanol addition inhibits the reactivity and reduces linearly the laminar flame speed. For 0.6 < X_H2 < 0.8, the laminar flame speed increases exponentially with the increase of hydrogen fraction.     

Hydrogen absorption characteristics of mechanically alloyed Ti–Zr–Ni and Ti–V–Ni powders

A first investigation into the production of amorphous and nanostructured Ti-based alloys with nominal compositions Ti_41.5Zr_41.5Ni₁₇, Ti₆₁Zr₂₂Ni₁₇, Ti_41.5V_41.5Ni₁₇ and Ti₆₁V₂₂Ni₁₇ by mechanical alloying (MA) technique is presented. This technique was adopted to produce alloys' powders with high fresh surface area that were active for hydrogen storage. Hydrogen absorption characteristics and structure changes in the alloys after hydrogenation were investigated. Gas phase hydrogenation of the Ti–Zr–Ni alloys, at 573 K and an initial hydrogen pressure of 2 MPa, exhibited good hydriding properties and started at a maximal rate without induction period with a hydrogenation capacity up to 1.2 wt%. However, hydriding of Ti–V–Ni alloys at the same conditions exhibited slower rates. The Ti₆₁V₂₂Ni₁₇ composition showed high hydrogen absorption capacity of 1.8 wt% and exceeded 4 wt% at 345 K. In addition, the Ti–V–Ni alloys showed structure stability after hydrogenation and retained the amorphous structure.     

Influence des copolymères greffés sur les propriétés mécaniques des alliages de polyéthylène avec polystyrène

The use of graft copolymers polyethylene-graft-polystyrene (P(E-g-S)) in blends of low-density polyethylene and polystyrene is studied. The copolymers P(E-g-S) are prepared by polymerisation of styrene in the presence of hydroperoxylated polyethylene. Addition of 2,5 wt.-% P(E-g-S) to polyethylene-polystyrene blends considerably increases its breaking strength σ_R but much less so its elongation at break ε_R. A comparison of graft and block copolymers used as emulsifiers in polyethylene-poly-styrene blends at present shows that P(E-g-S) is intermediate between the former graft and block copolymers with regard to their influence on the mechanical properties of blends. Photographs of fractures in the blends show a tenfold smaller phase size upon adding P(E-g-S) to the blends.