Morphologies and tensile properties of elastomer-modified epoxy and polycarbonate blended systems

The morphologies and tensile properties of an elastomer-modified epoxy (EME)/polycarbonate (PC) binary system and an EME/diglycidyl ether of bisphenol A (DGEBA)/PC ternary system were examined. In the EME system, a continuous elastomer-rich phase formed, while in the EME/DGEBA systems (unblended with PC), a continuous epoxy-rich phase formed. In both of these systems, two-phase structures were observed. In contrast, a microdispersed structure was observed when the PC was blended with either the EME or with the EME/DGEBA systems. It is suggested that blending of the epoxy with PC caused an increased solubility of the former into the elastomer phase. The tensile strength and tensile elongation of both the EME and EME/DGEBA systems were improved by blending with PC. In the EME/PC blend, the tensile elongation reached its maximum value (60%) at a PC content of approximately 10 p.h.r. (parts per hundred resin by weight), with this maximum being approximately one and a half times higher than that of the unblended EME. Tensile strength was also clearly increased by blending with small amounts of PC, but soon reached a steady value. In the EME/DGEBA/PC blends, the tensile properties were dependent on the weight ratio of EME to DGEBA. In the absence of PC, as this ratio increased, the tensile elongation also increased, while at the same time the tensile strength decreased. The tensile properties were also improved in this system, by blending with PC. From the results obtained, it was clear that the improvement in tensile properties was closely related to the changes in morphology. Therefore, blending of the PC induced a microdispersed structure and improved the elongation of the epoxy resin.     

Reduction characteristics of Fe-Bi-P mixed oxide catalysts and their ammoxidation activities of propylene

The characteristics of Fe-Bi-P mixed oxide catalysts of different compositions for reduction by propylene or ammonia and the ammoxidation activities of propylene were studied using a McBain type thermobalance and the pulse reaction technique respectively. By comparing the dependency of the reduction characteristics and catalytic activity with oxide composition and also the reduction rates and reoxidation rates of the reduced catalyst it was concluded that the ammoxidation of propylene on Fe-Bi-P mixed oxide catalyst proceeds through alternate repetition of reduction by propylene and reoxidation by oxygen, and that abstraction of allylic hydrogen from adsorbed C₃H₆ is the rate determining step.     

Electroinduced aldol condensation

Passing a catalytic amount of electricity (7.5 × 10^?3 F mol^?1) into solution of aldehydes in DMF leads to formation of α, β-unsaturated carbonyl compounds through the aldol-type condensation with extremely high current efficiency (1 × 10⁴%).     

SpaceGlue: linking spaces for adaptive service location

We describe a mechanism called SpaceGlue for adaptively locating services based on the preferences and locations of users in a distributed and dynamic network environment. In SpaceGlue, services are bound to physical locations, and a mobile user accesses local services depending on the current space he/she is visiting. SpaceGlue dynamically identifies the relationships between different spaces and links or “glues” spaces together depending on how previous users moved among them and used those services. Once spaces have been glued, users receive a recommendation of remote services (i.e., services provided in a remote space) reflecting the preferences of the crowd of users visiting the area. The strengths of bonds are implicitly evaluated by users and adjusted by the system on the basis of their evaluation. SpaceGlue is an alternative to existing schemes such as data mining and recommendation systems and it is suitable for distributed and dynamic environments. The bonding algorithm for SpaceGlue incrementally computes the relationships or “bonds” between different spaces in a distributed way. We implemented SpaceGlue using a distributed network application platform Ja-Net and evaluated it by simulation to show that it adaptively locates services reflecting trends in user preferences. By using “Mutual Information (MI)” and “F-measure” as measures to indicate the level of such trends and the accuracy of service recommendation, the simulation results showed that (1) in SpaceGlue, the F-measure increases depending on the level of MI (i.e., the more significant the trends, the greater the F-measure values), (2) SpaceGlue achives better precision and F-measure than “Flooding case (i.e., every service information is broadcast to everybody)” and “No glue case” by narrowing appropriate partners to send recommendations based on bonds, and (3) SpaceGlue achieves better F-measure with large number of spaces and users than other cases (i.e., “flooding” and “no glue”). Tomoko Itao is an alumna of NTT Network Innovation Laboratories     

Dynamic behavior of a solid particle bed in a liquid pool: SIMMER-III code verification

Dynamic behavior of solid particle beds in a liquid pool against pressure transients was investigated to model the mobility of core materials in a postulated disrupted core of a liquid metal fast reactor. A series of experiments was performed with a particle bed of different bed heights, comprising different monotype solid particles, where variable initial pressures of the originally pressurized nitrogen gas were adopted as the pressure sources. Computational simulations of the experiments were performed using SIMMER-III, a fast reactor safety analysis code. Comparisons between simulated and experimental results show that the physical model for multiphase flows used in the SIMMER-III code can reasonably represent the transient behaviors of pool multiphase flows with rich solid phases, as observed in the current experiments. This demonstrates the basic validity of the SIMMER-III code on simulating the dynamic behaviors induced by pressure transients in a low-energy disrupted core of a liquid metal fast reactor with rich solid phases.     

OXIDATION AND REDUCTION OF MANGANESE ACETYLACETONATE COMPLEXES IN SOLVENT EXTRACTION SYSTEMS AND IN ORGANIC SOLVENTS BY ATMOSPHERIC OXYGEN

Partial oxidation of manganese(II) and Partial reduction of manganese(III) in acetylacetonate complexes occured in liqudd-liquid systems containing carbon tetrachloride and an aqueous sodium perchlorate solution buffered by sodium hydrogenecarbonate solution equilibrium was assumed to be established after a two phase agitation for several days. Howeve, when the manganese(II) complex was dissolved in air-saturated nonpolar organic solvents such as carbon tetrachloride benzene, and chloroform, it was quantitatively oxidized to the trivalent complex within one hour and the rate was dependent on both the oxygen and ligand. The rate was lower when the solvent was polar and also when an adduct-forming ligand with the bis-chelate such as trioctylphosphine oxide was added into carbon tetrachloride.     

Automatic estimation of the ergonomics parameters of assembly operations

The ergonomics of assembly operations affects standard operation times and assembly reliability. It is a complicated time-consuming task to estimate the ergonomics parameters of operations in assembly cells. Assembly operations are simulated in a virtual environment, and ergonomic parameters including the visibility of an assembling part, posture and reachability of an operator are quantified automatically by using images of the assembling part which are automatically generated. The highest score among the image is selected as the ergonomics score of the assembly operation. The proposed method is tested by applying it to the assembly operations of a PC. Results demonstrated the feasibility of the proposed method.     

A macroscopic cross-section model for BWR pin-by-pin core analysis

A macroscopic cross-section model used in boiling water reactor (BWR) pin-by-pin core analysis is studied. In the pin-by-pin core calculation method, pin-cell averaged cross sections are calculated for many combinations of core state and depletion history variables and are tabulated prior to core calculations. Variations of cross sections in a core simulator are caused by two different phenomena (i.e. instantaneous and history effects). We treat them through the core state variables and the exposure-averaged core state variables, respectively. Furthermore, the cross-term effect among the core state and the depletion history variables is considered. In order to confirm the calculation accuracy and discuss the treatment of the cross-term effect, the k-infinity and the pin-by-pin fission rate distributions in a single fuel assembly geometry are compared. Some cross-term effects could be negligible since the impacts of them are sufficiently small. However, the cross-term effects among the control rod history (or the void history) and other variables have large impacts; thus, the consideration of them is crucial. The present macroscopic cross-section model, which considers such dominant cross-term effects, well reproduces the reference results and can be a candidate in practical applications for BWR pin-by-pin core analysis on the normal operations.     

Quantitative method for specific nucleic acid sequences using competitive polymerase chain reaction with an alternately binding probe

We have developed a simple, cost-effective, and accurate method for the quantification of specific nucleic acid sequences by the combined use of competitive PCR and a sequence-specific fluorescent probe that binds to either the gene of interest (target) or internal standard (competitor), referred to as alternately binding probe (ABProbe). In this method, the target and competitor were coamplified with the ABProbe, and then the fluorescence intensity was measured. The ratio of the target to the competitor can be calculated from the fluorescence intensity of the ABProbe using fluorescence quenching and fluorescence resonance energy transfer, that is, the starting quantity of the target is successfully calculated by end-point fluorescence measurement. Therefore, this method eliminates the complex post-PCR steps and expensive devices for real-time fluorescence measurement. We called this method alternately binding probe competitive PCR (ABC-PCR). We quantified amoA as a model target by ABC-PCR and real-time PCR. By comparison, the sensitivity, accuracy, and precision of ABC-PCR were similar to those of real-time PCR. Moreover, ABC-PCR was able to correctly quantify DNA even when PCR was inhibited by humic acid; therefore, this method will enable accurate DNA quantification for biological samples that contain PCR inhibitors.