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Li‐Hua Shao Juergen Biener Hai‐Jun Jin Monika M. Biener Theodore F. Baumann Jörg Weissmüller 《Advanced functional materials》2012,22(14):3029-3034
A novel nanoporous carbon/electrolyte hybrid material is reported for use in actuation. The nanoporous carbon matrix provides a 3D network that combines mechanical strength, light weight, and low cost with an extremely high surface area. In contrast to lower dimensional nanomaterials, the nanoporous carbon matrix can be prepared in the form of macroscopic monolithic samples that can be loaded in compression. The hybrid material is formed by infiltrating the free internal pore volume of the carbon with an electrolyte. Actuation is prompted by polarizing the internal interfaces via an applied electric bias. It is found that the strain amplitude is proportional to the Brunauer‐Emmett‐Teller (BET) mass specific surface area, with reversible volume strain amplitudes up to the exceptionally high value of 6.6%. The mass‐specific strain energy density compares favorably to reported values for piezoceramics and for nanoporous metal actuators. 相似文献
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Simon Woodruff Jennifer K. Baerny Nathan Mattor Don Stoulil Ronald Miller Theodore Marston 《Journal of Fusion Energy》2012,31(4):305-316
The benefits of an energy source whose reactants are plentiful and whose products are benign is hard to measure, but at no time in history has this energy source been more needed. Nuclear fusion continues to promise to be this energy source. However, the path to market for fusion systems is still regularly a matter for long-term (20?+?year) plans. This white paper is intended to stimulate discussion of faster commercialization paths, distilling guidance from investors, utilities, and the wider energy research community (including from ARPA-E). There is great interest in a small modular fusion system that can be developed quickly and inexpensively. A simple model shows how compact modular fusion can produce a low cost development path by optimizing traditional systems that burn deuterium and tritium, operating not only at high magnetic field strength, but also by omitting some components that allow for the core to become more compact and easier to maintain. The dominant hurdles to the development of low cost, practical fusion systems are discussed, primarily in terms of the constraints placed on the cost of development stages in the private sector. The main finding presented here is that the bridge from DOE Office of Science to the energy market can come at the Proof of Principle development stage, providing the concept is sufficiently compact and inexpensive that its development allows for a normal technology commercialization path. 相似文献
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Panagiotis-Nikolaos Tzounis Leonidas N. Gergidis Theodore E. Matikas Antonios Charalambopoulos 《Composites Part B》2012,43(6):2605-2612
In the current paper, we have investigated the dependence of the effective elastic properties of a composite material on the fiber/matrix interface elastic property. The model composite consists of a single cylindrical fiber embedded in a concentric cylindrical matrix material. A three dimensional mathematical method has been developed connecting the interface properties with the effective axial Young’s modulus of the composite structure. Special effort has been devoted to decode information about the quality of the interface by exploiting the information provided by the elastic effective parameters. In particular, the effective modulus vs. stiffness coefficient curves have been generated for Ti/SiC composites. The aforementioned curves reveal the characteristics of the transition from the regime of perfect interface to the realm of complete debonding. 相似文献
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Seyed Hamed Barghi Theodore T. TsotsisMuhammad Sahimi 《International Journal of Hydrogen Energy》2014
The question of chemisorption versus physisorption during hydrogen storage in carbon nanotubes (CNTs) is addressed experimentally. We utilize a powerful measurement technique based on a magnetic suspension balance coupled with a residual gas analyzer, and report new data for hydrogen sorption at pressures of up to 100 bar at 25 °C. The measured sorption capacity is less than 0.2 wt.%, and there is hysteresis in the sorption isotherms when multi-walled CNTs are exposed to hydrogen after pretreatment at elevated temperatures. The cause of the hysteresis is then studied, and is shown to be due to a combination of weak sorption – physisorption – and strong sorption – chemisorption – in the CNTs. Analysis of the experimental data enables us to calculate separately the individual hydrogen physisorption and chemisorption isotherms in CNTs that, to our knowledge, are reported for the first time here. The maximum measured hydrogen physisorption and chemisorption are 0.13 wt.% and 0.058 wt.%, respectively. 相似文献
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Though condensed between the stages of design and completion, the conventional process of designing a building is time consuming, involving various stakeholders, planning processes and a wide team of consultants and contractors. What happens, though, if the time period of an architect's involvement is expanded? How might a more process-orientated approach shift the role of the architect? Tobias Armborst, Daniel D'Oca and Georgeen Theodore , principals of Interboro Partners in New York, describe how they have developed projects that have sought opportunities in expanding the timescale and remit of traditional practice. 相似文献