固载于SBA-15分子筛中的同双核金属配合物催化剂

合成了3种同双核金属配合物[M2LCl3]Cl(L代表配体三亚乙基四胺,M代表Co,Cu,Cr),采用微波加热法合成了SBA-15分子筛,采用浸渍法将3种同双核金属配合物分别固载在表面官能化的SBA-15分子筛(SBA-15-NH2分子筛)中制得负载型催化剂。傅里叶变换红外光谱、X射线衍射、紫外可见光谱和热分析表征结果表明,同双核金属配合物被固载后,其结构仍保持完整。以环己烷氧化反应为探针反应,考察了[Co2LCl3]Cl/SBA-15-NH2,[Cu2LCl3]Cl/SBA-15-NH2,[Cr2LCl3]Cl/SBA-15-NH2催化剂的活性,环己烷转化率分别为11.0%,49.5%,57.9%;对于[Cr2LCl3]Cl/SBA-15-NH2催化剂,当分别以乙睛、丙酮和冰醋酸为溶剂时,环己烷转化率分别为57.9%,52.1%,34.2%,3次重复实验的环己烷转化率分别为57.9%,47.8%,46.5%,表明该催化剂具有较好的活性和重复使用性。     

中国香港电信盈科公司近期经营业绩分析

中国香港电信与盈科数码动力有限公司合并以后更名为电信盈科。它由一家以技术为主的电信公司转型为亚太地区、特别是两岸三地的商界及个人客户提供服务的综合通信服务供应商，主要提供电话服务、互联网、商企电贸服务、数据中心、客户联络中心、环球通信服务和基建业务。分析了2001-2002年上半年其电信、商企电贸、基建以及与Telstra结盟等业务市场的经营情况。     

食品工厂设计方案多级模糊评价方法的研究

食品工厂设计方案的评价受众多因素影响,采用模糊评价和层次分析法,不仅考虑了所有因素的影响,而且保留了各级评价的全部信息,减少了评价过程中人为因素的影响,提高食品工厂设计方案评价的科学性和准确性.     

Low surface energy films based on partially fluorinated isocyanates: the effects of curing temperature

Self-stratification strategy can be used to prepare films in which both bulk and surface properties can be optimized. By using this approach, only a very small quantity of fluorinated species is needed to generate a surface with low surface energy. When cross-linking is involved during film formation, we are dealing with a competition behavior between the diffusion of fluorinated species and the formation of cross-linked network. In this study low surface energy polymeric films were prepared on the basis of partially fluorinated polyisocyanates, in combination with hydroxyl-end-capped three-armed solventless liquid oligoesters and modified hyperbranched polyesters. At a fluorine concentration of only 0.5 wt.%, contact angles of water and hexadecane can reach 120° and 80°, respectively. A surface energy as low as 10–15 mN/m can be obtained upon the addition of less than 1 wt.% of fluorine in the films. It was shown, from real time ATR-FTIR and contact angle measurements, that the curing temperatures demonstrated significant effects on the cross-linking rate as well as on the wettability of the films.     

供电器可供放大器最大级数的计算

有线电视电缆网采用供电器进行集中供电，要计算一个额定容量的供电器可供放大器的最大级数，算式是很复杂的，而用VisaulFOXPRO6．0编写一个小程序，利用电脑对上述问题进行处理，就变得简单易用。     

马克法输铝管用胶结剂的研制及应用

用粘土熟料、软质粘土及复合结合剂研制的胶结剂,用于马克法铸钢输铝管系统的胶结,其使用性能和使用寿命达到或超过了进口胶结剂的水平。     

精密深孔表面环状硬挤条纹的产生机理与控制

本文建立了不同条件下环状硬挤条纹的生成模型,详细分析了其产生机理.用理论解析和试验验证了所建模型的可靠性,最后提出了控制其产生的方法.     

Monolithic SiGe Up‐/Down‐Conversion Mixers with Active Baluns

The purpose of this paper is to describe the implementation of monolithically matching circuits, interface circuits, and RF core circuits to the same substrate. We designed and fabricated on‐chip 1 to 6 GHz up‐conversion and 1 to 8 GHz down‐conversion mixers using a 0.8 µm SiGe hetero‐junction bipolar transistor (HBT) process technology. To fabricate a SiGe HBT, we used a reduced pressure chemical vapor deposition (RPCVD) system to grow a base epitaxial layer, and we adopted local oxidation of silicon (LOCOS) isolation to separate the device terminals. An up‐conversion mixer was implemented on‐chip using an intermediate frequency (IF) matching circuit, local oscillator (LO)/radio frequency (RF) wideband matching circuits, LO/IF input balun circuits, and an RF output balun circuit. The measured results of the fabricated up‐conversion mixer show a positive power conversion gain from 1 to 6 GHz and a bandwidth of about 4.5 GHz. Also, the down‐conversion mixer was implemented on‐chip using LO/RF wideband matching circuits, LO/RF input balun circuits, and an IF output balun circuit. The measured results of the fabricated down‐conversion mixer show a positive power conversion gain from 1 to 8 GHz and a bandwidth of about 4.5 GHz.     

求解机械装配规划的新方法

本文提出一个求解机械装配规划的算法,其计算量～O(sN~2),其中s是零件所有可能装配方向的个数,N是工件的零件数(一般s～O(N)).而现行的求机械装配规划的算法,其计算量均随N的增加按指数律增加.