La diffusion intraparticulaire dans la clinoptilolite application aux ions Na+ et NH4+Intracrystalline self-diffusion of ions in clinoptilolite ammonia and sodium cations studies

Studies on NH₄⁺ removal by mean of a zeolite: clinoptilolite, previously realised have led the authors to examine the exchange mechanisms between cations on the clinoptilolite grains.The use of clinoptilolite as conventional ion exchange resin (1, 2, 3, 4, 5, 6) for elimination of ammonia ion from waste waters or drinking water (7, 8, 12) poses a great number of difficulties, principally during regeneration.This text presents a brief theorical presentation of the material and the ion-exchange, especially in the case of isotopic exchange, allowing the introduction of the fundamental equation (2) and its approximate expression:

$\text{U(t)}\text{1?exp}\text{?}\text{D}\text{tπ}{}^2\text{r}{}^2{}_0{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$

with U(t) the exchanged fraction at time t.The experimental study concerns the NH₄⁺ cation exchange with Na⁺ ions on clinoptilolite.In this case, the curve u(t) and ln(l ? u²) vs time shows the non-applicability of the above formula (Fig. 5).Our subject was to examine the divergence causes and to propose for our regeneration problem a semi-empiric law which form is:

$\text{U(t)}\text{1?exp}\text{?}\text{β}\text{D}\text{tπ}{}^2\text{r}{}^2{}_0{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$

with

$\text{β=[1?U(t)]}\text{2}\text{3}$

.The validated relation (Fig. 7) for the Na⁺/NH₄⁺ exchanges lead us to find the D_Na⁺ and D_NH2⁺ coefficients consistent with the literature.Using the experimental results from AMES, we show that our formula can be applied to other exchange cases (e.g. Sr⁺/NH₄⁺) (Fig. 8). The form of the β relation seems coherent with the proposed film diffusion interpretation.     

Assembly of antibodies in lipid membranes for biosensor development

An investigation of the incorporation of antibody in lipid films of a composition that has been used for biosensor preparation is reported. IgG that is incorporated into lipid monolayers prepared from 7:3 mixtures of dipalmitoyl phosphatidylcholine and dipalmitoyl phosphatidic acid is edge-active, and enters and penetrates the fluid region of the mixed-phase system when monolayers are held at low pressure (< 20 mN/m). It was found that there is an "exclusion pressure" observed in pressure-area (pi-A) curves that are collected for monolayers that contain antibody. This term refers to a specific threshold of lateral pressure (which is reached by monolayer compression) that can cause explusion of antibody from the interior of a membrane. Microscopic images of monolayers containing the fluorescent phospholipid nitrobenzoxadiazole dipalmitoyl phosphatidylethanolamine (NBD-PE), or antibody labeled with tetramethylrhodamine isothiocyanate (TRITC), were used to determine the structure of membranes, and the location of effects on structure caused by IgG. Ellipsometric measurements of lipid monolayers that were cast onto silicon wafers by the Langmuir-Blodgett method were used to study the thickness of monolayers and to investigate the structural changes that occurred at the "exclusion pressure." Both the use of fluorescent antigen and ellipsometry indicated that antibody binding activity was present and was dependent on compression pressure. The effects of pH and ionic strength of subphase, antibody concentration, incubation time, and lateral pressure have been examined. The results may indicate the conditions that can be used to improve the incorporation of active IgG for preparation of biosensors that are based on lipid membranes.     

Small treatise about e-manipulation for honest people

Information warfare is nowadays a well-known concept. However, articles are mainly split into two categories. The first one deals with how information must be managed in a system (e.g. a company or a state), in order to achieve information dominance, that is providing more and better information than the others so that they have to follow what is produced. The second one is more on how information can be used as a weapon. Dominance is one goal, but not the only one: deception, intoxication or misinformation are others. In this article, we chose the second approach. The goal when using information as a weapon is to influence a target so that it does what the attacker wants, or to cause effects. We chose also to focus on a specific battlefield: Internet. One particularly important aspect of the Internet is that it is both a container and contents. For instance, web sites are providing articles, but they are also some servers, referenced by search engines. As such, we combined this duality to increase the effects of the operations given as example. We illustrate the operation through examples, where both information is created, but also its container is improved. We show how Search Engine Optimization can be used for information warfare. Combining oriented action techniques and information based techniques make each of them much more efficient. This article shows how information warfare can be conducted on Internet. The goal is to illustrate how very few people can organize an information based attack, targeting either a company or a state for instance.     

Utilisation de la clinoptilolite en potabilisation des eaux—elimination de l'ion NH4

The objective of this study is to develop a technique to remove ammonium ion from water intended for potable purposes. An ion exchange method is used with a selective ion exchanger, a natural cation zeolite, clinoptilolite. Glass columns (Fig. 1) are used for laboratory experiments. These experiments show that the NH₄⁺ exchange capacity is very small compared to its total capacity 2.17 meq g⁻¹; its value depends essentially on the NH₄⁺ initial concentration and less on the Ca²⁺ concentration in the influent water. Figure 3 illustrates the practical exchange capacity relative to the initial concentration of ammonium ion for a soft water (Ca²⁺ = 35–50 mg l⁻¹). We were particularly interested in waters weak in ammonium ion concentration (NH₄⁺ = 1–3 mg l⁻¹). In this case and for 1 and 2 mg l⁻¹ NH₄⁺ concentration in water, the practical capacity is only 0.06 and 0.108 meq g⁻¹ respectively. The leakage is smaller than the ECC limit (European Community Council) for drinking waters (NH₄⁺ 0.5 mg l⁻¹) and the treated volume of water to breakthrough, defined at 0.5 mg l⁻¹ of NH₄⁺, is 720 BV (BV = bed volume) in both cases.In another way Fig. 6 shows that hard waters (due to Ca²⁺ ions) are more difficult to treat than soft waters. The practical capacity is smaller than before and the NH₄⁺-leakage is greater. To lessen NH₄⁺-leakage to less than 0.5 mg l⁻¹ for soft waters down-flow and up-flow, regeneration is used. Figure 7 shows that up-flow regeneration is more attractive than down-flow regeneration.Cycle reproducibility (Figs 4 and 5) shows that the regeneration conditions satisfied our requirements: in this case, the salt consumption is 180 eq of salt per eq of NH₄⁺ eliminated. This prompted us to try to reuse the regenerant (with NH₄⁺ ion). An increase of NH₄⁺-leakage is noticed in the presence of an NH₄⁺-residual in the regenerant. This increase is more significant with down-flow regeneration.After these laboratory experiments, we carried out a semi-industrial pilot-plant. Our objective was first to verify the laboratory results and secondly to study clinoptilolite behaviour relative to the time it was used. Two plexiglass columns comprise the pilot-plant shown in Fig. 9; soft water is used for these experiments. The first column is regenerated with fresh salt solution. The cycles obtained, considering their initial NH₄⁺-concentration, are reproduced in Fig. 10. For 2 mg l⁻¹ NH₄⁺ in the influent water, the leakage is about 0.2 mg l⁻¹ and the treated volume to breakthrough (0.5 mg l⁻¹ of NH₄⁺) is about 750 BV. The second column is regenerated with a recycled solution. The quality of the cycles decreases with the number of reuse of the regenerant as shown in Fig. 11. Nevertheless, it is interesting to note that after 3 reuses, the performance decrease is only 25% and the leakage, although it increases is smaller than 0.5 mg l⁻¹.Pilot results allowed us to propose a treatment of 30,000 m³ day⁻¹; the cost per cubic meter water treated, relative to NH₄⁺-removal, is about 0.165 FF (0.033 US $) for a plant and 0.77 FF (0.014 US $) for the same plant at the seaside. Using two serial columns decreased the cost by about 40–50%.     

Pavement Structures Damage Caused by Hurricane Katrina Flooding

In September of 2005, Hurricane Katrina devastated New Orleans and caused sustained flooding. Limited pre- and postflooding tests indicated that the pavement structures tested were adversely impacted by the flood water. Consequently, the Louisiana Dept. of Transportation and Development hired an independent contractor to structurally test approximately 383 km (238?mi) of the region’s federally aided urban highway system both inside and outside of the flooding area. Falling weight deflectometer (FWD) tests were performed every 161 m (0.1?mi) over each selected roadway, along with other field tests. The FWD data were imported into a geographical information system and plotted against a USGS geo-referenced map. Comparative analyses were made possible through the use of extensive flood maps made available through NOAA and FEMA. This arrangement made it possible to classify spatially and graphically all test points on the basis of flooding versus nonflooding, short flooding duration versus longer flooding duration, shallow flooding versus deep flooding, and thin pavements versus thick pavements. Three pavement types, asphaltic concrete, Portland cement concrete, and composite, were considered in this analysis. The statistical inference about the difference in the means of compared data groups was conducted with 95% confidence.     

Developmental changes in the hypoxic response of the hypoglossus respiratory motor output in vitro

The transverse brain stem slice of mice containing the pre-B?tzinger complex (PBC), a region essential for respiratory rhythm generation in vitro, was used to study developmental changes of the response of the in vitro respiratory network to severe hypoxia (anoxia). This preparation generates, at different postnatal stages [postnatal day (P)0-22], spontaneous rhythmic activity in hypoglossal (XII) rootlets that are known to occur in synchrony with periodic bursts of neurons in the PBC. It is assumed that this rhythmic activity reflects respiratory rhythmic activity. At all examined stages anoxia led to a biphasic response: the frequency of rhythmic XII activity initially increased ("primary augmentation") and then decreased ("secondary depression"). In neonates (P0-7), anoxia did not significantly affect the amplitude of integrated XII bursts. Secondary depression never led to a cessation of rhythmic activity. In mice older than P7, augmentation was accompanied by a significant increase in the amplitude of XII bursts. A significant decrease of the amplitude of XII bursts occurred during secondary depression. This depression led always to cessation of rhythmic activity in XII rootlets. The anoxia-induced response of the respiratory rhythmic XII motor output is biphasic and changes during development in a similar way to the in vivo respiratory network. Whether this biphasic response is due to a biphasic response of the respiratory rhythm generator and/or to a biphasic modulation of the XII motor nucleus remains unresolved and needs further cellular analysis. We propose that the transverse slice is a useful model system for examination of the mechanisms underlying the hypoxic response.     

Measuring memory for source: some theoretical assumptions and technical limitations

In a search for pathogenetic mechanisms underlying retention hyperkeratosis, we examined the pH gradient over the stratum corneum in 13 male patients suffering from either x-linked recessive (XRI) or autosomal dominant ichthyosis vulgaris. For recording pH values, a flat glass electrode was repeatedly applied to the skin during tape stripping of mildly involved forearm skin. Before stripping, surface pH was higher in ichthyosis vulgaris (5.3 +/- 0.7; n = 7) than in XRI (4.6 +/- 0.4; n = 6; p < 0.05) and healthy control men (4.5 +/- 0.2; n = 7; p < 0.01). Removal of stratum corneum, which required 100-240 strippings in ichthyotic skin and 80-120 strippings in healthy control skin, disclosed markedly different pH variations in the two types of ichthyosis. The major abnormality in ichthyosis vulgaris skin was that a neutral pH was attained already halfway through the horny layer, possibly reflecting a congenital lack of acidic breakdown products from keratohyaline. By contrast, stripping of XRI skin revealed a shallow pH gradient that plateaued at 6.2-6.6, instead of about 7 as in normal and ichthyosis vulgaris skin. A likely explanation is the XRI-associated accumulation of cholesterol sulfate in lower stratum corneum. Our results suggest that the "acid mantle" of normal skin, which penetrates deep into the stratum corneum, is the combined result of cornification-associated organic acids and back-diffusion of acid material from the surface. Because corneocyte desquamation involves many pH-dependent enzymes, abnormalities in the transcorneal pH gradient might play a role in the pathogenesis of ichthyosis.     

Design and application of real-time visual attention model for the exploration of 3D virtual environments

This paper studies the design and application of a novel visual attention model designed to compute user's gaze position automatically, i.e., without using a gaze-tracking system. The model we propose is specifically designed for real-time first-person exploration of 3D virtual environments. It is the first model adapted to this context which can compute in real time a continuous gaze point position instead of a set of 3D objects potentially observed by the user. To do so, contrary to previous models which use a mesh-based representation of visual objects, we introduce a representation based on surface-elements. Our model also simulates visual reflexes and the cognitive processes which take place in the brain such as the gaze behavior associated to first-person navigation in the virtual environment. Our visual attention model combines both bottom-up and top-down components to compute a continuous gaze point position on screen that hopefully matches the user's one. We conducted an experiment to study and compare the performance of our method with a state-of-the-art approach. Our results are found significantly better with sometimes more than 100 percent of accuracy gained. This suggests that computing a gaze point in a 3D virtual environment in real time is possible and is a valid approach, compared to object-based approaches. Finally, we expose different applications of our model when exploring virtual environments. We present different algorithms which can improve or adapt the visual feedback of virtual environments based on gaze information. We first propose a level-of-detail approach that heavily relies on multiple-texture sampling. We show that it is possible to use the gaze information of our visual attention model to increase visual quality where the user is looking, while maintaining a high-refresh rate. Second, we introduce the use of the visual attention model in three visual effects inspired by the human visual system namely: depth-of-field blur, camera- motions, and dynamic luminance. All these effects are computed based on the simulated gaze of the user, and are meant to improve user's sensations in future virtual reality applications.     

Adsorption studies of recalcitrant compounds of molasses spentwash on activated carbons

Due to high levels of residual chemical oxygen demand (COD) in the effluent of molasses spentwash (MSW) after anaerobic treatment, acceptable COD levels for discharge cannot be achieved without some form of post-treatment. In this study, the particulate composition of molasses spentwash after anaerobic digestion (MSWD), is characterised as to its particle size distribution, using micro- and ultrafiltration and three activated carbons are characterised as to their ability to reduce significantly the COD of MSWD effluent. The activated carbons tested as adsorbent, were characterised by XPS spectroscopy, elemental analysis, surface area, pore size distribution, and acid-base titration using the Boehm's method. Adsorption of phenol, used here as a reference compound, and of some organic compounds contained in MSWD (gallic acid, tannic acid, and melanoidin, respectively), was studied. It was clearly demonstrated that an activated carbon with a significant distribution of both micropores and mesopores and a significant amount of macropores that are assumed to act as conduits providing access to micro- and mesopores, have a good adsorption efficiency for compounds such as tannic acid and melanoidins. It is a good adsorbent for melanoidin and coloured compounds of MSWD, which represents a large source of the aqueous pollution in sugar cane industries.     

Implementing a Multi-Model Estimation Method

We revisit the problem of parameter estimation in computer vision, reconsidering and implementing what may be called the Kanatani's estimation method, presented here as a simple optimisation problem, so (a) without any direct reference to a probabilistic framework but (b) considering (i) non-linear implicit measurement equations and parameter constraints, plus (ii) robust estimation in the presence of outliers and (iii) multi-model comparisons.Here, (A) a projection algorithm based on generalisations of square-root decompositions allows an efficient and numerically stable local resolution of a set of non-linear equations. On the other hand, (B) a robust estimation module of a hierarchy of non-linear models has been designed and validated.A step ahead, (C) the software architecture of the estimation module is discussed with the goal of being integrated in reactive software environments or within applications with time constraints, while an experimentation considering the parameterisation of retinal displacements between two views is proposed as an illustration of the estimation module.