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811.
In this review, the most relevant aspects of skeletal isomerization of n-butene to isobutene are discussed: the nature of the active sites, the prevailing mechanism of the skeletal isomerization, and the relation of this to that of n-butane. It is concluded that the prevailing mechanism of skeletal isomerization of n-butene is monomolecular (in contrast to butane isomerization) and requires Br?nsted acid (OH) active sites. The selectivity and catalytic stability can be influenced by the shape selectivity of zeolites and zeotypes. These effects are explained on the basis of the knowledge on the prevailing mechanism. 相似文献
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Band theory and Mott insulators: Hubbard U instead of Stoner I 总被引:2,自引:0,他引:2
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AL Muliukin KA Lusta MN Griaznova AN Kozlova MV Duzha VI Duda GI El'-Registan 《Canadian Metallurgical Quarterly》1996,65(6):782-789
Under certain cultivation conditions, the bacteria Bacillus cereus and Micrococcus luteus form cystlike refractive cells (up to 60% of the total number) that retain viability over a long time, are metabolically inactive and thermotolerant and possess specific ultrastructure. These properties allow them to be attributed to a new type of resting forms of microorganisms. 相似文献
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A patient is described, who was examined 1 year after surgery for mandibular cyst diagnosed as radicular near the !5 tooth and for plasty of the secondary osseous cavity with hydroxyapatite granulate. X-Ray examination revealed a cystic cavity near the roots of teeth !234. Histologic examination of tissue fragments and the remainder of hydroxyapatite granulate, obtained by cystectomy, helped diagnose a primordial cyst. Intensive bone regeneration was observed at the site of hydroxyapatite granule accumulation and fusion of the new bone with the granules to form a solid osseogranular complex. The authors recommend hydroxyapatite ceramic granules for surgical treatment of minor and medium bone defects and for corrective bone plasty. 相似文献