Control and optimization of a three-phase catalytic slurry intensified continuous chemical reactor

Intensified continuous mini-reactors working in high pressure and temperature conditions are particularly effective at coping with mass transfer limitations during three-phase catalytic reactions. They are highly non-linear, multivariable systems and behave differently from conventional batch, fed-batch or continuous non-intensified reactors. In this paper, the optimization and control of this new process are presented using a two-layer approach consisting of a hierarchical control structure with an optimization layer which calculates the set points for an advanced controller. The latter is based on the concavity of the entropy function and the use of thermodynamic availability as a Lyapunov function. The three-phase catalytic o-cresol hydrogenation performed under high pressure and temperature in a small-scale pilot of the RAPTOR® reactor designed by the French company AETGROUP SAS, is taken as a representative test example to illustrate the strategy. The performance of the control structure is illustrated by simulation.     

Scandinavian Thins on Top of Cake: New and Improved Algorithms for Stacking and Packing

We show how to compute the smallest rectangle that can enclose any polygon, from a given set of polygons, in nearly linear time; we also present a PTAS for the problem, as well as a linear-time algorithm for the case when the polygons are rectangles themselves. We prove that finding a smallest convex polygon that encloses any of the given polygons is NP-hard, and give a PTAS for minimizing the perimeter of the convex enclosure. We also give efficient algorithms to find the smallest rectangle simultaneously enclosing a given pair of convex polygons.     

Malicious URI resolving in PDF documents

Nowadays, PDF (Portable Document Format) is used very frequently, especially by companies and even more and more by normal users. This can be a good explanation of the rising appeal of cybercriminals for this vector of attack. PDF is also often considered as safer as other document formats like those of Microsoft Office for example. Knowing the many possibilities offered by this format, we can wonder about the question of the confidence which should be given to such a document. Indeed, the use of HTTP(Hypertext Transfert Protocol) requests allows us to execute some arbitrary code outside of the PDF. Including, for example, JavaScript in Internet Explorer. It sill works, despite the updates from Adobe, this is still a pretty good open door to malicious actions. Basically, the purpose of this paper is to show that the simple use of an HTTP request from a PDF can be a pretty good vector for an attacker. Furthermore, this paper deals about how it can be relatively easy to reuse some vulnerabilities from outside the document. In addition, we will see that it’s possible to call an external PDF from another PDF. In fact, it can allow the attacker to adapt his attack by knowing the Adobe software version of the victim even before launching any malicious PDF. Knowledge of this security problem is not new but this article aims to show in detail how the attacker could place his attack.     

Mechanical testing of plasma-sprayed coatings of ceramics

Mechanical tests have been performed on two types of plasma-sprayed ceramic coatings: magnesium zirconate (ZM) on aluminium alloy and chromium oxide (CO) on cast iron. Tensile strength, shear strength, energy relaxation rate and crack velocity have been determined. Results obtained with double-torsion tests show good agreement with those of double-cantilever-beam tests. Fracture always occurred in the ceramic for the ZM coating and at the interface for the CO one. Finally, acoustic emission monitoring carried out during bending tests was used to point out different types of emission, and to correlate them with micrographic examinations in order to identify some damaging processes.[/p]     

Tight complexity bounds for the two-dimensional real knapsack problem

We study the complexity of the 2-dimensional knapsack problem , where . The problem is defined in terms of real numbers and we study it where an integral solution is sought under a real number model of computation. We obtain a tight complexity bound , where . Received: November 1998 / Accepted: December 1998     

Fracture mechanics models applied to delayed failure of LVL beams

Several theories for modelling fracture and slow growth of a crack in wood have been developed. The various models may be differentiated by the specifically regarded stress levels, failure mechanisms and averaging procedures. This paper deals with the application of viscoelastic fracture mechanics models to predict delayed failure of a timber element in bending. Simulations are compared to experimental results of bending tests carried out on LVL (Laminated Veneer Lumber) notched beams. This analysis emphasizes the influence of the geometry and of the size of the beam as well as of the damage area on the delayed failure.     

Rapid Screening of Lectins for Multivalency Effects with a Glycodendrimer Microarray

Multivalency is an important phenomenon in protein–carbohydrate interactions. In order to evaluate glycodendrimers as multivalent inhibitors of carbohydrate binding proteins, we displayed them on a microarray surface. Valencies were varied from 1 to 8, and corrections were made for the valencies so that all surfaces contained the same amount of the sugar ligand. Five different carbohydrates were attached to the dendrimers. A series of fluorescent lectins was evaluated, and for each of them a binding profile was obtained from a single experiment showing both the specificity of the lectin for a certain sugar and whether it prefers multivalent ligands or not. Very distinct binding patterns were seen for the various lectins. The results were rationalized with respect to the interbinding distances of the lectins.