全文获取类型
收费全文 | 2116篇 |
免费 | 35篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 17篇 |
化学工业 | 204篇 |
金属工艺 | 6篇 |
机械仪表 | 15篇 |
建筑科学 | 28篇 |
矿业工程 | 2篇 |
能源动力 | 20篇 |
轻工业 | 42篇 |
水利工程 | 3篇 |
石油天然气 | 2篇 |
无线电 | 103篇 |
一般工业技术 | 176篇 |
冶金工业 | 1428篇 |
原子能技术 | 3篇 |
自动化技术 | 106篇 |
出版年
2023年 | 2篇 |
2022年 | 12篇 |
2021年 | 21篇 |
2020年 | 15篇 |
2019年 | 12篇 |
2018年 | 17篇 |
2017年 | 21篇 |
2016年 | 22篇 |
2015年 | 21篇 |
2014年 | 26篇 |
2013年 | 42篇 |
2012年 | 29篇 |
2011年 | 30篇 |
2010年 | 29篇 |
2009年 | 37篇 |
2008年 | 37篇 |
2007年 | 30篇 |
2006年 | 40篇 |
2005年 | 26篇 |
2004年 | 20篇 |
2003年 | 29篇 |
2002年 | 29篇 |
2001年 | 23篇 |
2000年 | 14篇 |
1999年 | 51篇 |
1998年 | 476篇 |
1997年 | 237篇 |
1996年 | 198篇 |
1995年 | 91篇 |
1994年 | 71篇 |
1993年 | 96篇 |
1992年 | 19篇 |
1991年 | 18篇 |
1990年 | 24篇 |
1989年 | 19篇 |
1988年 | 23篇 |
1987年 | 17篇 |
1986年 | 13篇 |
1985年 | 15篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 10篇 |
1981年 | 11篇 |
1980年 | 12篇 |
1978年 | 3篇 |
1977年 | 59篇 |
1976年 | 85篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有2155条查询结果,搜索用时 484 毫秒
71.
Kanaparthi Ramesh Yi Ling Eileen Goh C. G. Gwie Chang Jie Timothy John White Armando Borgna 《Journal of Porous Materials》2012,19(4):423-431
Nanocrystalline LaPxOy with various starting P to La ratios from 0.5 to 2.0 catalysts were prepared by a sol?Cgel method using cetyl trimethylammonium bromide (CTAB) as template. The catalysts were thoroughly characterized by N2 physisorption, powder X-ray diffraction (XRD), temperature programmed desorption (TPD) of NH3, solid state 31P and 1H nuclear magnetic resonance (NMR), and transmission electron microscopy (TEM) techniques. XRD results indicate the presence of predominantly monazite LaPO4 with minor amounts of (??3.0 wt%) rhabdophane LaPO4 phase in the samples with starting P/La ratios of 1.0 and 1.5. NH3-TPD results show an increasing trend in the total acidity with increase in P/La ratio. These catalysts were tested in the selective ethanol dehydration in the temperature range between 250 and 400?°C. The catalyst activity (??mol/h/m2) is increased with P/La ratio and the catalyst with highest P/La ratio of 2.0 exhibiting the highest ethanol dehydration activity. The ethanol conversion increased with reaction temperature, reaching 100% at 350?°C and remains unchanged at higher temperatures. On the other hand, the ethylene selectivity is also increased up to 350?°C and then decreased with further increase of reaction temperature. At a P/La ratio of 2, the CTAB templated LaPxOy catalyst showed higher catalytic activities compared to the LaPxOy by hydrothermal method without any template. 相似文献
72.
Yang Miang Goh Peter E.D. Love Greg Stagbouer Chris Annesley 《Accident; analysis and prevention》2012
The management of occupational health and safety (OHS) including safety culture interventions is comprised of complex problems that are often hard to scope and define. Due to the dynamic nature and complexity of OHS management, the concept of system dynamics (SD) is used to analyze accident prevention. In this paper, a system dynamics group model building (GMB) approach is used to create a causal loop diagram of the underlying factors influencing the OHS performance of a major drilling and mining contractor in Australia. While the organization has invested considerable resources into OHS their disabling injury frequency rate (DIFR) has not been decreasing. With this in mind, rich individualistic knowledge about the dynamics influencing the DIFR was acquired from experienced employees with operations, health and safety and training background using a GMB workshop. Findings derived from the workshop were used to develop a series of causal loop diagrams that includes a wide range of dynamics that can assist in better understanding the causal influences OHS performance. The causal loop diagram provides a tool for organizations to hypothesize the dynamics influencing effectiveness of OHS management, particularly the impact on DIFR. In addition the paper demonstrates that the SD GMB approach has significant potential in understanding and improving OHS management. 相似文献
73.
74.
Mao Zhi Goh Bee Hua Shou Qing Wang George Ofori 《Construction Management & Economics》2013,31(7):707-718
Total factor productivity (TFP) determines long‐term economic growth and is a comprehensive industry‐level productivity measure. This paper proposes Jorgenson's method as an appropriate TFP measurement for the construction industry. The method is less restrictive than the conventional Chau's approach, as it does not impose the Hick Neutral Technical Change assumption. Jorgenson's method is then applied to estimate TFP growth in the construction industry of Singapore over 1984–1998. TFP growth is found down by 1.53% per annum over this period, indicating that the performance of TFP in the construction industry lags behind the rest of economy. TFP growth is also found to be fluctuating over time and tends to move in tandem with the construction business cycle. As a monitor of progress towards TFP achievement, factors influencing TFP growth in the construction industry of Singapore over 1984–1997 are identified. Seven factors are found to be significantly related to TFP growth. Among them, economies of scale, R&D by the industry, investment allowance granted and labour unions are leading contributors to TFP growth; while foreign worker, construction accidents and pre‐cast are major hampers. The general methodology presented in this study can be applied to other countries. Future studies are required to find appropriate indicators for factors unquantified. 相似文献
75.
Investigation on the effect of spinning conditions on the properties of hollow fiber membrane for hemodialysis application
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Sumarni Mansur Mohd Hafiz Dzarfan Othman A. F. Ismail Siti Hamimah Sheikh Abdul Kadir Fatmawati Kamal Pei Sean Goh Hasrinah Hasbullah Bee Cheer Ng Mohd Sohaimi Abdullah 《应用聚合物科学杂志》2016,133(30)
Polyethersulfone (PES) hollow fiber membranes were fabricated via the dry‐wet phase inversion spinning technique, aiming to produce an asymmetric, micro porous ultrafiltration hollow‐fiber specifically for hemodialysis membrane. The objective of this study is to investigate the effect of spinning conditions on the morphological and permeation properties of the fabricated membrane. Among the parameters that were studied in this work are air gap distance, dope extrusion rate, bore fluid flow rate, and the take‐up speed. The contact angle was measured to determine the hydrophilicity of the fibers. Membrane with sufficient hydrophilicity properties is desired for hemodialysis application to avoid fouling and increase its biocompatibility. The influences of the hollow fiber's morphology (i.e., diameter and wall thickness) on the performance of the membranes were evaluated by pure water flux and BSA rejection. The experimental results showed that the dope extrusion rate to bore fluid flow rate ratio should be maintained at 1:1 ratio to produce a perfectly rounded asymmetric hollow fiber membrane. Moreover, the flux of the hollow fiber spun at higher air gap distance had better flux than the one spun at lower air gap distance. Furthermore, spinning asymmetric hollow fiber membranes at high air gap distance helps to produce a thin and porous skin layer, leading to a better flux but a relatively low percentage of rejection for BSA separation. Findings from this study would serve as primary data which will be a useful guide for fabricating a high performance hemodialysis hollow fiber membrane. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43633. 相似文献
76.
Synthesis and Characterization of NiO Nano‐Spheres by Templating on Chitosan as a Green Precursor
下载免费PDF全文
![点击此处可从《Journal of the American Ceramic Society》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Cheng Keong Choo Tze Lim Goh Ladan Shahcheraghi Gek Cheng Ngoh Ahmad Zuhairi Abdullah Bahman Amini Horri Babak Salamatinia 《Journal of the American Ceramic Society》2016,99(12):3874-3882
In this study, nickel oxide was prepared through the calcination of extrusion dripped chitosan/nickel nitrate beads. The morphology and structural properties of the products were studied using various characterization techniques. Uniformly distributed nickel oxide was formed as observed from the studies of surface morphology where the processing parameters play a huge role on the resulting morphology. TEM results have shown that nickel oxide with crystallite sizes of 10–30 nm was obtained. The Fourier‐transform infrared spectra studies show an intense peak at 525 cm?1, which is attributed to the vibration of Ni–O bond. Furthermore, the XRD results show NiO diffraction peaks correspond to (111), (200), (220), (311), and (222) which indicates that a bunsenite structure with a face‐centered cubic phase was produced in this study. The usage of 500°C as the lower limit in this study is justified due to the complete removal of the templating material as seen in the thermalgravimetric analysis studies. Furthermore, it was obtained that the largest surface area of nickel oxide synthesized using this technique is 48.024 m2/g with pore sizes of 19.843 nm. The usage of chitosan as a green template for the synthesis of nanoparticles has shown promising results which allows a more economical and sustainable approach for the fabrication of nanomaterials. 相似文献
77.
Pei Sean Goh Kar Chun Wong Tuck Whye Wong Ahmad Fauzi Ismail 《Frontiers of Chemical Science and Engineering》2022,16(5):564
Polyamide thin film composite membranes have dominated current reverse osmosis market on account of their excellent separation performances compared to the integrally skinned counterparts. Despite their very promising separation performance, chlorine-induced degradation resulted from the susceptibility of polyamide toward chlorine attack has been regarded as the Achilles’s heel of polyamide thin film composite. The free chlorine species present during chlorine treatment can impair membrane performance through chlorination and depolymerization of the polyamide selective layer. From material point of view, a chemically stable membrane is crucial for the sustainable application of membrane separation process as it warrants a longer membrane lifespan and reduces the cost involved in membrane replacement. Various strategies, particularly those involved membrane material optimization and surface modifications, have been established to address this issue. This review discusses membrane degradation by free chlorine attack and its correlation with the surface chemistry of polyamide. The advancement in the development of chlorine resistant polyamide thin film composite membranes is reviewed based on the state-of-the-art surface modifications and tailoring approaches which include the in situ and post-fabrication membrane modifications using a broad range of functional materials. The challenges and future directions in this field are also highlighted. 相似文献
78.
Polyethylene (PE) is one of the most produced synthetic resins in the world. Functionalized multiwalled carbon nanotube (MWCNT) is a potential nanoscale filler to realize the next generation strong and multifunctional PE composites. We demonstrate that MWCNTs grafted with short n‐alkyl groups are effective nanofillers for mechanical reinforcement of PE composites. At 1 wt% filler loading, the yield stress and Young's modulus improve significantly up to 54 and 63% compared with neat PE, respectively. Among ductile properties, tensile strength increases up to 30%; ultimate strain is preserved; and toughness increases up to 33%. More important, we show that short n‐alkyl groups can be grafted on MWCNTs much easier than long chain polymers. Further, we find that alkyl groups of C14–C18 chains have the optimum length for reinforcement. The optimum density of grafted alkyl groups is around 0.390–0.423 μmol/mg when the C14 alkyl groups are used. Overall, the results manifest that MWCNTs grafted with n‐alkyl groups with suitable length and density are efficient nanoscale fillers for high‐performance PE composites. POLYM. ENG. SCI., 54:336–344, 2014. © 2013 Society of Plastics Engineers 相似文献
79.
The mechanical properties of poly(1‐butene) reinforced by pristine multiwalled carbon nanotubes (MWNTs) and polypropylene‐grafted MWNTs (PP‐g‐MWNTs) were evaluated. The incorporation of pristine MWNTs to PB led to an improvement in stiffness, but not in strength, ductility, and toughness. In comparison, PP‐g‐MWNTs were able to improve the stiffness, strength, and toughness of PB significantly, without compromising the ductility. The mechanical properties of PB improved with increasing amount of PP‐g‐MWNTs up to an effective MWNT content of 1.5 wt%. Further increase in the effective MWNT content led to a downturn in mechanical properties due to the existence of MWNTs bundles as observed by microscopy. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
80.
Boon Tong Goh Chan Kee Wah Zarina Aspanut Saadah Abdul Rahman 《Journal of Materials Science: Materials in Electronics》2014,25(1):286-296
Hydrogenated nanocrystalline silicon (nc-Si:H) thin films deposited on c-Si and quartz substrates by layer-by-layer (LBL) technique using radio-frequency plasma enhanced chemical vapour deposition system. The effects of rf power on the interlayer elemental profiling, structural and optical properties of the films were investigated by Auger electron spectroscopy, Fourier transform infrared spectroscopy, Raman scattering spectroscopy, X-ray diffraction and optical transmission and reflection spectroscopy. The results revealed that the LBL deposition leads to a formation of different ranges of crystallite sizes of nc-Si corresponds 3–6 and 8–26 nm respectively. LBL deposition also demonstrated a capability to increase the crystalline volume fraction of nc-Si up to 65.3 % with the crystallite size in between 5 and 6 nm, at the rf power in between 80 and 100 W. However, the crystalline volume fraction decreased for the rf power above 100 W due to the growth of nc-Si was suppressed by the formation of SiO2. In addition, the onset of crystallization of the films deposited on c-Si and quartz substrates are different with increase in the rf power. The effects of rf power on the growth of nc-Si, and the hydrogen content, structural disorder, crystallite size of nc-Si and oxygen diffusion into the LBL layer with the change of optical energy gap under the variation of rf power are also discussed. 相似文献