Mo丝网上双层Ir/W高温抗氧化涂层的制备与表征

为改善溅射依涂层与钼基体之间的结合力,在钼基体与依涂层之间制备了钨粘结层,并成功在钼丝网上制备了双层的铱/钨涂层。研究表明,钨粘结层的制备能有效改善铱涂层与钼基体之间的结合力,从而有效抑制铱涂层的剥落。对于制备态的样品,W粘结层与铱涂层以及钼基体之间未出现明显的互扩散。X射线衍射结果表明,溅射铱涂层为多晶结构且呈(111)择优取向生长。根据Movchan-Demchishin模型,所制备的双层铱/钨涂层的显微结构与“1区”结构类似,该结构表明所制备的涂层横向结合力弱,在拉应力状态下易发生开裂。     

Coach simplified structure modeling and optimization study based on the PBM method

For the coach industry, rapid modeling and efficient optimization methods are desirable for structure modeling and optimization based on simplified structures, especially for use early in the concept phase and with capabilities of accurately expressing the mechanical properties of structure and with flexible section forms. However, the present dimension-based methods cannot easily meet these requirements. To achieve these goals, the property-based modeling (PBM) beam modeling method is studied based on the PBM theory and in conjunction with the characteristics of coach structure of taking beam as the main component. For a beam component of concrete length, its mechanical characteristics are primarily affected by the section properties. Four section parameters are adopted to describe the mechanical properties of a beam, including the section area, the principal moments of inertia about the two principal axles, and the torsion constant of the section. Based on the equivalent stiffness strategy, expressions for the above section parameters are derived, and the PBM beam element is implemented in HyperMesh software. A case is realized using this method, in which the structure of a passenger coach is simplified. The model precision is validated by comparing the basic performance of the total structure with that of the original structure, including the bending and torsion stiffness and the first-order bending and torsional modal frequencies. Sensitivity analysis is conducted to choose design variables. The optimal Latin hypercube experiment design is adopted to sample the test points, and polynomial response surfaces are used to fit these points. To improve the bending and torsion stiffness and the first-order torsional frequency and taking the allowable maximum stresses of the braking and left turning conditions as constraints, the multi-objective optimization of the structure is conducted using the NSGA-II genetic algorithm on the ISIGHT platform. The result of the Pareto solution set is acquired, and the selection strategy of the final solution is discussed. The case study demonstrates that the mechanical performances of the structure can be well-modeled and simulated by PBM beam. Because of the merits of fewer parameters and convenience of use, this method is suitable to be applied in the concept stage. Another merit is that the optimization results are the requirements for the mechanical performance of the beam section instead of those of the shape and dimensions, bringing flexibility to the succeeding design.     

Frequency weighting filter design for automotive ride comfort evaluation

Few study gives guidance to design weighting filters according to the frequency weighting factors,and the additional evaluation method of automotive ride comfort is not made good use of in some countries.Based on the regularities of the weighting factors,a method is proposed and the vertical and horizontal weighting filters are developed.The whole frequency range is divided several times into two parts with respective regularity.For each division,a parallel filter constituted by a low-and a high-pass filter with the same cutoff frequency and the quality factor is utilized to achieve section factors.The cascading of these parallel filters obtains entire factors.These filters own a high order.But,low order filters are preferred in some applications.The bilinear transformation method and the least P-norm optimal infinite impulse response(IIR) filter design method are employed to develop low order filters to approximate the weightings in the standard.In addition,with the window method,the linear phase finite impulse response(FIR) filter is designed to keep the signal from distorting and to obtain the staircase weighting.For the same case,the traditional method produces 0.330 7 m · s~(–2) weighted root mean square(r.m.s.) acceleration and the filtering method gives 0.311 9 m · s~(–2) r.m.s.The fourth order filter for approximation of vertical weighting obtains 0.313 9 m · s~(–2) r.m.s.Crest factors of the acceleration signal weighted by the weighting filter and the fourth order filter are 3.002 7 and 3.011 1,respectively.This paper proposes several methods to design frequency weighting filters for automotive ride comfort evaluation,and these developed weighting filters are effective.     

FRFT在转子起停车状态评估中的应用研究进展

转子起停车过程中由传统的等时间间隔采样所获得的机械动态信号已不再保持原有的周期特性,采用经典的基于傅里叶变换的谱分析方法进行信号处理不再有效。针对转子起停车状态评估中幅值、频率的非平稳特性所带来的问题,引入分数阶傅里叶变换研究了基于起停车信息的故障定性分析和定量识别方法,提出了基于分数阶全息原理的转子起停车故障特征提取方法,并在此基础上实现了基于分数阶主分量原理的转子故障特征模式定量分类。实验验证表明,该方法解决了转子起停车过程中瞬变信息的获取问题,能有效提取出起停车过程振动信号中的典型故障特征,可以实现对转子不同故障类型及不同故障程度的准确分类。     

基于深度学习特征匹配的铸件微小缺陷自动定位方法

针对射线实时成像检测中精密铸件微小缺陷自动定位的需要,提出一种基于深度学习特征匹配的铸件缺陷三维定位方法。模拟选择注意机制的中央-周边差算法,提出以视觉显著度为尺度,从射线图像复杂背景中检测出微小缺陷及其区域,以定义的区域中央点为待匹配点;然后,提出构造深度卷积神经网络自动提取微小缺陷区域的深度学习特征,通过深度学习特征矢量的相似度,实现在不同视角下投影图像中的同一微小缺陷点的自动匹配;最后,基于平移视差测距原理计算缺陷匹配点的三维空间坐标。实验表明,基于深度学习特征匹配的方法能够正确搜索平移前后投影图像中的同一缺陷点,以此为基础,利用视差测距原理实现了微小缺陷匹配点的自动准确定位,深度定位误差小于5.52%,能够满足对精密铸件微小缺陷智能评判的需要。     

Measurement of 900 °C Isothermal Section in the Mo-Ni-Zr System

The isothermal section of the Mo-Ni-Zr system at 900 °C was investigated by characterization of eighteen equilibrium alloys. Electron probe microanalysis (EPMA) and x-ray diffraction (XRD) were used to identify the phases and obtain their compositions. The existence of two ternary compounds, Zr₆₅Mo_18?x Ni_16.5+x (τ₁, cF96-Ti₂Ni) and Zr₆₅Mo_27.3Ni_7.7 (τ₂, hP28-Hf₉Mo₄B), was confirmed in the Zr-rich corner, and the compositions of the two phases were determined. The isothermal section of the Mo-Ni-Zr system at 900 °C consists of 15 three-phase regions and 29 two-phase regions. The following three-phase equilibria were well established: (1) (Ni) + Ni₇Zr₂ + Ni₅Zr, (2) MoNi + MoNi₃ + Ni₇Zr₂, (3) Ni₇Zr₂ + MoNi + (Mo), (4) (Mo) + Ni₇Zr₂ + Ni₃Zr, (5) (Mo) + Ni₃Zr + Ni₂₁Zr₈, (6) (Mo) + Ni₂₁Zr₈ + Ni₁₀Zr₇, (7) (Mo) + Ni₁₀Zr₇ + NiZr, (8) (Mo) + Mo₂Zr + NiZr, (9) NiZr₂ + Mo₂Zr + τ₁, (10) τ₁ + Mo₂Zr + τ₂, (11) τ₂ + Mo₂Zr + (Zr)ht, (12) NiZr₂ + τ₁ + (Zr)ht and (13) τ₁ + τ₂ + (Zr)ht. Several binary phases, such as MoNi₃, Ni₇Zr₂ and Mo₂Zr, dissolve appreciable amount of the third component.     

Ultra-high strength Mg-9Gd-4Y-0.5Zr alloy with bi-modal structure processed by traditional extrusion

It is usual to observe that multi-scale structures can lead to combined strength and ductility both in aluminum alloys and steels, but related research has been seldom reported yet in magnesium alloys. In this study, applying traditional one step extrusion, we have successfully obtained a bimodal (Mg-9Gd-4Y-0.5Zr) alloy capable of ultra-high strength. The characterized sample reveal a bi-modal microstructure with two constitutions, i.e. stretched coarse-grain region with strong basal fiber texture and recrystallization fine-grain region. The bi-modal structured sample exhibit excellent mechanical properties with an ultimate strength 508 MPa and elongation 8% via 400 °C extrusion and subsequently 200 °C-60 h peak aging process. Ultra-high strength can be attributed to its strong extrusion texture in stretched coarse grains and dispersed nano-scale precipitates. This unique bimodal structure could be produced easily by one step extrusion, which is quite reliable and low costs in industrial applications of magnesium alloys with ultra-high strength as well as ideal ductility.     

Oxidation and Hot Corrosion Behavior of Plasma-Sprayed MCrAlY–Cr<Subscript>2</Subscript>O<Subscript>3</Subscript> Coatings

The oxidation and hot corrosion behavior of two atmospheric plasma-sprayed NiCoCrAlY–Cr₂O₃ and CoNiCrAlY–Cr₂O₃ coatings, which are primarily designed for wear applications at high temperature, were investigated in this study. The two coatings were exposed to air and molten salt (75%Na₂SO₄–25%NaCl) environment at 800 °C under cyclic conditions. Oxidation and hot corrosion kinetic curves were obtained by thermogravimetric technique. X-ray diffraction analysis and scanning electron microscopy with energy-dispersive x-ray spectrometry were employed to characterize the coatings’ microstructure, surface oxides, and composition. The results showed that both coatings provided the necessary oxidation resistance with oxidation rates of about 1.03 × 10^?2 and 1.36 × 10^?2 mg/cm² h, respectively. The excellent oxidation behavior of these two coatings is attributed to formation of protective (Ni,Co)Cr₂O₄ spinel on the surface, while as-deposited Cr₂O₃ in the coatings also acted as a barrier to diffusion of oxidative and corrosive substances. The greater presence of Co in the CoNiCrAlY–Cr₂O₃ coating restrained internal diffusion of sulfur and slowed down the coating’s degradation. Thus, the CoNiCrAlY–Cr₂O₃ coating was found to be more protective than the NiCoCrAlY–Cr₂O₃ coating under hot corrosion condition.     

Synthesis and dynamic mechanical study of core–shell structure epoxy/polyacrylate composite particle

A material with high damping property and based on epoxy/polyacrylate (EP/PA) composite particles was synthesized by two-stage emulsion polymerization. Transmission electron microscopy (TEM) showed that the composite particles have a spherical morphology, a core–shell structure and a diameter of 100 nm–130 nm. Fourier transform infrared spectra (FTIR) indicated the cross-linking between EP groups in the core layer and carboxyl groups in the shell layer of the composite particles during film formation. The cross-linking reaction improved the dynamic mechanical property by the interaction of core and shell polymers. The effects of the cross-linking agent and ratio of the two polymers on the damping capacity were studied by dynamic mechanical analysis (DMA). DMA results revealed that a certain amount of acrylic acid could markedly enhance the loss factor (tan δ) and slightly widen the damping temperature range. When the EP/PA ratio was 1:7, peak values for tan δ of the composite materials could reach 2.10, exceeding the value for most damping materials. The result implies that the EP/PA composites have great potential application in damping steel surface coatings.