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41.
Possible Phase Transition at Low mK Temperatures in Liquid Helium Mixture Films Adsorbed on Graphite
F. Ziouzia H. Patel J. Nyéki B. P. Cowan J. Saunders 《Journal of Low Temperature Physics》2004,134(1-2):79-84
We report heat capacity and magnetisation measurements of 3He adsorbed on the surface of graphite plated with three atomic layers of 4He. For 3He coverages n 3>4 nm?2 the heat capacity corresponds to a 2D Fermi fluid. The inferred hydrodynamic mass of the 3He quasiparticles is 1.38±0.05 m3. The 3He effective mass ratio increases with coverage to 2.4 at n 3=4 nm?2, due to Fermi liquid interactions. The heat capacity isotherm exhibits a steplike increase centred on n 3=4.5 nm?2, similar to that previously observed on four layers of 4He. This is associated with the population of the first excited Andreev surface bound state. However, in the present case, as n 3 is increased through the step a pronounced anomalous feature develops in the temperature dependence of the heat capacity, around 10 mK. Below 5 mK the heat capacity is approximately linear in temperature. With n 3=7 nm?2, we find that this behaviour is very sensitive to small changes in the 4He third layer coverage, around the completed third layer. Measurements of the 3He magnetisation,, by continuous wave NMR methods, find a significant increase with decreasing temperature below around 20 mK. Together the data suggest that a phase transition takes place in the film at low mK temperatures. 相似文献
42.
43.
Sam C. Saunders 《技术计量学》2013,55(2):361-377
If the distribution of life length is a member of a specified subset of distributions which have increasing failure rates, we find a method of determining functions of the sample data which can be used to provide lower tolerance bounds of given confidence or a service life with specified assurance of no failures among a given number of items to be produced. The method of finding such functions of the observations is shown to be optimal in a sense and the calculation of a lower bound for the probability of no failure in the future production is carried out when such functions are used. The confidence in the tolerance bound and the assurance of no failure in a production lot of specified size are compared when using bounds obtained from these functions. 相似文献
44.
We assume a financial market governed by a diffusion process reverting to a stochastic mean which is itself governed by an unobservable ergodic diffusion, similar to those observed in electricity and other energy markets. We develop a moment method algorithm for the estimation of the parameters of both the observable process and the unobservable stochastic mean. Our approach is contrasted with other methods for parameter estimation of partially observed diffusions, and applications to the modelling of interest rates and commodity prices are discussed. 相似文献
45.
S. R. J. Saunders M. K. Hossain B. Kent D. M. Lloyd 《Materials at High Temperatures》2013,30(2):63-73
The results of an investigation of the sulphidation behaviour of lncoloy BOOH and AISI 310 stainless steel in coal combustion conditions at temperatures between 650°C and 900°C are presented. Laboratory tests were carried out in controlled environments in the presence of solids representative of fluidized bed combustor operation. The morphology and composition of scale formed during sulphidation was examined and compared with that from tube samples removed from test rigs operated by the National Coal Board. The results have shown that at 900°C a gas mixture corresponding to the equilibrium conditions close to the coexistence point for CaS04, CaO and CaS on the phase stability diagram is sufficient to induce sulphidation. However, at lower temperatures an interaction between the deposit and the protective oxide is necessary and in some cases the presence of typical contaminants found in coals is an added requirement. The morphology of the corrosion products found in practice can be reproduced under controlled conditions in laboratory tests. The results are interpreted in terms of likely mechanisms of the processes involved. 相似文献
46.
Zn in Athenian Black Gloss Ceramic Slips: A Trace Element Marker for Fabrication Technology 下载免费PDF全文
Marc Walton Karen Trentelman Ilaria Cianchetta Jeffrey Maish David Saunders Brendan Foran Apurva Mehta 《Journal of the American Ceramic Society》2015,98(2):430-436
The black‐colored pottery slips produced in Athens from the 6th to 4th centuries B.C., had a consistent composition achieved through processing and refinement of raw clay. Little direct evidence has been established as to what were these refinement methods. To better understand how the slip material was prepared, the major and trace elemental compositions of 19 slips from different ceramic vessels and their corresponding bodies of Athenian red‐figure and black‐figure vases were determined using laser ablation inductively coupled plasma mass spectrometry (LA‐ICPMS). Notably higher Zn concentrations were found in the slips (271–1959 ppm) than in their corresponding body ceramics (<361 ppm). The Zn concentrations in the slips were also found to be above the natural background for typical clay (between 10 and 300 ppm) suggesting an unintentional anthropogenic enrichment of this metal. Based on the abnormally high Zn content of the slip, it is speculated that the clay was treated using vitriol (concentrated acid mine runoff which is rich in Zn), to induce flocculation and remove carbonate mineral phases from the raw material that, if present, would prevent the slip from vitrifying. This same signature of elevated levels of Zn with a corresponding Ce anomaly is also observed for black glosses produced in Corinthian and Etrurian (Italy) workshops indicating that these trace element signatures were imparted to the material by means of shared methods of manufacturing instead of being indicative of a single unique source for this material. 相似文献
47.
基于发电机对暂态势能集的电力系统暂态稳定快速评估 总被引:1,自引:0,他引:1
基于传统暂态能量函数方法,以简单3机3节点系统推导出一种基于发电机对暂态势能的系统暂态势能函数表达式。该暂态势能计算函数不需要全系统的网络拓扑参数或故障位置信息,仅需实时采集系统中少量的发电机机端电气状态量,计算方法简单有效。基于该发电机对暂态势能定义了受扰严重机组判别指标集,利用该指标的聚集特性在故障清除后极短时间内辨识系统的主导失稳模式,根据临界机组分群结果采用EEAC法快速计算当前故障模式下的系统暂态稳定裕度。IEEE 3机9节点、新英格兰10机39节点系统、某省级实际电网算例结果验证了该方法的正确性和有效性。 相似文献
48.
Epoxidized linolenic acid salts as multifunctional additives for the thermal stability of plasticized PVC 下载免费PDF全文
Fiaz S. Mohammed Mark Conley Steven R. Saunders Jackson Switzer Rani Jha Jeffrey M. Cogen Bharat I. Chaudhary Pamela Pollet Charles A. Eckert Charles L. Liotta 《应用聚合物科学杂志》2015,132(13)
Calcium and zinc salts of epoxidized linolenic acid were synthesized and used as multifunctional additives, to minimize or prevent the reaction of epoxidized soybean oil (ESO) with liberated hydrochloric acid (HCl) during the thermal degradation of poly(vinyl chloride) (PVC) in particular. These metal epoxy salts were incorporated as thermal stabilizers for both diisodecyl phthalate and ESO–plasticized PVC blends that underwent thermal degradation studies at 170°C. The overall performance of these metal epoxy salts was examined by thermal gravimetric analysis and visual color retention of the PVC blends. The weight loss profiles of the metal salt stabilized PVC were comparable to those of blends containing metal stearates. There were, however, vast improvements in color retention of the plasticized PVC using these novel additives. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41736. 相似文献
49.
Ana B. Lanham Adrian Oehmen Aaron M. Saunders Gilda Carvalho Per H. Nielsen Maria A.M. Reis 《Water research》2013
This study analysed the enhanced biological phosphorus removal (EBPR) microbial community and metabolic performance of five full-scale EBPR systems by using fluorescence in situ hybridisation combined with off-line batch tests fed with acetate under anaerobic–aerobic conditions. The phosphorus accumulating organisms (PAOs) in all systems were stable and showed little variability between each plant, while glycogen accumulating organisms (GAOs) were present in two of the plants. The metabolic activity of each sludge showed the frequent involvement of the anaerobic tricarboxylic acid cycle (TCA) in PAO metabolism for the anaerobic generation of reducing equivalents, in addition to the more frequently reported glycolysis pathway. Metabolic variability in the use of the two pathways was also observed, between different systems and in the same system over time. The metabolic dynamics was linked to the availability of glycogen, where a higher utilisation of the glycolysis pathway was observed in the two systems employing side-stream hydrolysis, and the TCA cycle was more active in the A2O systems. Full-scale plants that showed higher glycolysis activity also exhibited superior P removal performance, suggesting that promotion of the glycolysis pathway over the TCA cycle could be beneficial towards the optimisation of EBPR systems. 相似文献
50.
A survey of construction companies' secondary disability management practices was undertaken in the state of Victoria, Australia. The results indicate that formal rehabilitation and return‐to‐work programmes and practices are not adopted in many companies. Smaller construction firms were less likely to have adopted formal programmes or practices than medium‐to‐large firms. In particular, construction companies reported difficulties in the provision of suitable alternate or light duties for workers returning to work following an injury. Most companies regarded disability management practices to have increased operating costs while yielding little or no benefit in terms of reducing lost workdays. Strategies to overcome some of these impediments to rehabilitation and return‐to‐work in construction are recommended. 相似文献