Integration Concepts for the Fabrication of LTCC Structures

At the Keck Smart Materials Integration Laboratory at Penn State University, low-temperature co-fired ceramic (LTCC) material systems have been used to fabricate a number of devices for a variety of applications. This article presents an overview of the integration of the concepts and materials that we have used to achieve miniaturization and unique device function. Examples of microwave filters, metamaterial antennas, and a dielectrophoretic cell sorter will be presented, with emphasis on device modeling and design, prototype construction methods, and test results.     

Characterisation and tribological evaluation of nitrogen-containing molybdenum–copper PVD metallic nanocomposite films

This paper reports on the structural, mechanical and tribological properties of molybdenum–copper nanocomposite films ‘doped’ with small amounts of nitrogen, which contain either no nitride phase (i.e. the nitrogen is held in interstitial solid solution, mainly in molybdenum) or small amounts of lower nitrides (i.e. Mo₂N). All films were deposited on Si wafers, AISI M2 high speed steel and AISI 316 stainless steel by reactive sputtering using a hot-filament-enhanced dc unbalanced magnetron system. A systematic approach was adopted to investigate the evolution of metal/metal and ceramic/metal phase combinations with increasing nitrogen content (up to 40 at.% N) in the film. Coating composition and microstructure were determined by cross-sectional TEM, SEM and XPS. XRD was used to identify (where possible) metallic and metal-nitride phases. Mechanical properties such as hardness and elastic modulus were determined by low load Knoop and instrumented Vickers indentation measurements. Reciprocating sliding, micro-abrasion and impact tests were performed to assess tribological performance.

It was found that increasing the nitrogen gas flow rate from 0 to 15 sccm (and therefore nitrogen content in the film from 0 to 24 at.% N), refined significantly the coating microstructure from columnar to a dense and more equiaxed morphology, increasing the hardness whilst maintaining (almost constant) elastic modulus values, close to that of molybdenum metal. Further increases in the nitrogen gas flow rate resulted in films that appeared to contain significant fractions of the Mo₂N ceramic phase. SEM and cross-sectional TEM analyses of the film deposited at a nitrogen flow rate of 20 sccm (containing 36 at.% N) demonstrated a microstructure consisting of 50–100 nm wide columns, which contain small regions of contrast in dark-field images, of the order of 3–5 nm wide. A maximum hardness of 32 GPa and the highest hardness/modulus ratio was however found in the (predominantly metallic) film deposited at a nitrogen gas flow rate of 15 sccm. This film also performed best in both micro-abrasion and impact wear tests; in contrast, the ‘ceramic’ film (deposited at 20 sccm nitrogen flow rate) performed better in reciprocating sliding wear.     

如何对付“强制缔约”合同

对于一名为自动化公司提供咨询的律师来说,一件让人很不爽的事情就是有时候摆在我面前的事情是如此之多。下面是一个例子：比方说控制工程有限公司（Control Engineers Limited,CEL）希望让我就一个新项目提供一些法律意见。出现在我的收件箱中的是一份来自于CEL的客户的小礼物．其中包括一份40页的“一般条件说明”．一份5页的“特殊情况说明”．一些令人生畏的规格．以及一份打印精美的采购合同。     

Laser processing of an aluminium AA6061 alloy involving injection of SiC particulate

In the present laser processing work, the powder injection technique was investigated as a method for producing a surface metal matrix composite (MMC) containing large SiC particulates (SiC_p) (105–150 m). This size is known to enhance the wear resistance of bulk aluminium-based composites. The effects of the laser-processing conditions, the powder feeding rate and the surface situations necessary to produce a well incorporated MMC on the surface were studied, and the microstructure examined. In previous work, laser processing involving the preplacement of SiC_p was developed to create an AI-SiC_p (45 m) MMC layer on aluminium alloy surfaces. Some of these ideas were used in conjunction with the injection process in the present work to enhance the surface-wear resistance. The wear resistance of an MMC obtained by a single laser track with the injection technique was determined and compared with the base alloy and the MMC layer produced by the preplacement technique.     

Determination of all elastic constants of orthotropic plate specimens from group velocity data

This paper presents a novel method of nondestructively determining all nine elastic constants of fiber-reinforced orthotropic plate specimens. Group velocities of bulk quasi-longitudinal (QL), pure transverse (PT), and surface skimming pseudo-longitudinal modes are measured in glass-fiber (GF) and carbon-fiber (CF) reinforced Poly Ether Ether Ketone (PEEK) specimens by a point-source/point-receiver (PS/PR) technique. First, the pure index longitudinal moduliC ₁₁,C ₂₂, andC ₃₃, are obtained from the longitudinal (L) group velocities measured in three principal directions. Next, the pure index shear moduli,C ₄₄,C ₅₅, andC ₆₆, are determined by measuring the shear horizontally (SH) polarized PT group velocities in the symmetry planes. Finally, the mixed index elastic constantsC _ij (i j) are calculated from QL group velocities measured in the symmetry planes and using analytic formulas.     

The expanding small heat-shock protein family, and structure predictions of the conserved "alpha-crystallin domain"

The ever-increasing number of proteins identified as belonging to the family of small heat-shock proteins (shsps) and alpha-crystallins enables us to reassess the phylogeny of this ubiquitous protein family. While the prokaryotic and fungal representatives are not properly resolved, most of the plant and animal shsps and related proteins are clearly grouped in distinct clades, reflecting a history of repeated gene duplications. The members of the shsp family are characterized by the presence of a conserved homologous "alpha-crystallin domain," which sometimes is present in duplicate. Predictions are made of secondary structure and solvent accessibility of this domain, which together with hydropathy profiles and intron positions support the presence of two similar hydrophobic beta-sheet-rich motifs, connected by a hydrophilic alpha-helical region. Together with an overview of the newly characterized members of the shsp family, these data help to define this family as being involved as stable structural proteins and as molecular chaperones during normal development and induced under pathological and stressful conditions.     

Volatile compounds from interdigital gland of male white-tailed deer (Odocoileus virginianus)

Interdigital secretions were collected from eight male white-tailed deer of various ages. Analysis of volatiles was performed by gas chromatography-mass spectrometry with a modified headspace technique. Forty-six volatile compounds were found including alkanes, arenes, aldehydes, ketones, aliphatic acids, esters, pyrroles, furans, and sulfur compounds. Eleven occurred in higher concentrations (P0.10) in dominant (3.5-year-old) than in subordinate (1.5-year-old) animals. Dominant males typically have higher serum testosterone levels, and fatty acids and esters fluctuate with sebum production, which is under hormonal control. Therefore, these compounds may reflect testosterone levels and act as chemical signals indicating the presence of a dominant male. Interdigital volatiles also may act as generalized scent trail markers.     

Development and testing of a holographic projection system

We describe the development and testing of a holographic projection system that is used to produce micro-optical devices. The projector uses a two-dimensional two-phase-level diffraction grating to produce multiple coherent beams and an interferometric optical system behind the grating to recombine the beams to produce interference patterns that have been recorded within a photosensitive substrate. The two different substrates that we used are a diazo imaging material and a bisbenzocyclobutene (BCB) polymeric resin for fabrication of surface relief microstructures. After the exposed photosensitive substrate is developed, the recorded interference pattern forms a micro-optical device. The analysis and testing of these micro-optical devices show promise that this technique can form patterns uniformly over a region of several centimeters in diameter on flat or curved substrates. The experimental testing results of these micro-optical devices demonstrate that this method is a simple and energy efficient system to produce microstructures compared with other methods. These devices may be used as a new generation of directional light filters or monolithic microlenslet arrays that may have applications in communications, display, and components technologies.     

Flap prefabrication: effectiveness of different vascular carriers

A new experimental model of a vascular carrier to prefabricate a "secondary" island flap, the popliteal musculovascular pedicle, was developed in the rat. Using quantitative skin-surface fluorometry 30 minutes after sodium fluorescein injection and a flap survival area in the prefabricated 8 x 2.5-cm abdominal composite island flap, we compared the revascularization ability of our muscular carrier to nonrevascularized controls: the skeletonized arteriovenous pedicle and the fasciovascular pedicle. The free composite graft with no vascular carrier exhibited near-total necrosis. The skeletonized vascular pedicle demonstrated 15.2% +/- 7.8% perfusion of normal skin on dye fluorescence index measurements and 50% flap survival. The fasciovascular pedicle exhibited better revascularization, with a dye fluorescence index of 36.2 +/- 15.5 (p < 0.01) and 90% +/- 10% flap survival (p < 0.001). India ink injection study and histological examination of our model provided visual evidence of revascularization from the musculovascular pedicle, along with preservation of the carrier's muscular architecture. The musculovascular pedicle is a reliable carrier for making new, vascularized composite flaps.