Non‐Covalent Functionalization of Graphene Using Self‐Assembly of Alkane‐Amines

A simple, versatile method for non‐covalent functionalization of graphene based on solution‐phase assembly of alkane‐amine layers is presented. Second‐order Møller–Plesset (MP2) perturbation theory on a cluster model (methylamine on pyrene) yields a binding energy of ≈220 meV for the amine–graphene interaction, which is strong enough to enable formation of a stable aminodecane layer at room temperature. Atomistic molecular dynamics simulations on an assembly of 1‐aminodecane molecules indicate that a self‐assembled monolayer can form, with the alkane chains oriented perpendicular to the graphene basal plane. The calculated monolayer height (≈1.7 nm) is in good agreement with atomic force microscopy data acquired for graphene functionalized with 1‐aminodecane, which yield a continuous layer with mean thickness ≈1.7 nm, albeit with some island defects. Raman data also confirm that self‐assembly of alkane‐amines is a non‐covalent process, i.e., it does not perturb the sp² hybridization of the graphene. Passivation and adsorbate n‐doping of graphene field‐effect devices using 1‐aminodecane, as well as high‐density binding of plasmonic metal nanoparticles and seeded atomic layer deposition of inorganic dielectrics using 1,10‐diaminodecane are also reported.     

Tomographic fluorescence imaging in tissue phantoms: a novel reconstruction algorithm and imaging geometry

A novel image reconstruction algorithm has been developed and demonstrated for fluorescence-enhanced frequency-domain photon migration (FDPM) tomography from measurements of area illumination with modulated excitation light and area collection of emitted fluorescence light using a gain modulated image-intensified charge-coupled device (ICCD) camera. The image reconstruction problem was formulated as a nonlinear least-squares-type simple bounds constrained optimization problem based upon the penalty/modified barrier function (PMBF) method and the coupled diffusion equations. The simple bounds constraints are included in the objective function of the PMBF method and the gradient-based truncated Newton method with trust region is used to minimize the function for the large-scale problem (39919 unknowns, 2973 measurements). Three-dimensional (3-D) images of fluorescence absorption coefficients were reconstructed using the algorithm from experimental reflectance measurements under conditions of perfect and imperfect distribution of fluorophore within a single target. To our knowledge, this is the first time that targets have been reconstructed in three-dimensions from reflectance measurements with a clinically relevant phantom.     

Evaluation of Corn/Soybeans Separability Using Thematic Mapper And Thematic Mapper Simulator Data

Multitemporal Thematic Mapper, Thematic Mapper Simulator, and detailed ground truth data were collected for a 9-by 1-km sample segment in Webster County, Iowa, in the summer of 1982. Three dates were acquired each with Thematic Mapper Simulator (June 7, June 23, and July 31) and Thematic Mapper (August 2, September 3, and October 21). The Thematic Mapper Simulator data were converted to equivalent TM count values using TM and TMS calibration data and model based estimates of atmospheric effects. The July 31, TMS image was compared to the August 2, TM image to verify the conversion process. A quantitative measure of proportion estimation variance (Fisher information) was used to evaluate the corn/soybeans separability for each TM band as a function of time during the growing season. The additional bands in the middle infrared allowed corn and soybeans to be separated much earlier than was possible with the visible and near-infrared bands alone. Using the TM and TMS data, temporal profiles of the TM principal components were developed. The greenness and brightness exhibited behavior similar to MSS greenness and brightness for corn and soybeans.     

Microstructure and Crystal Structure in TAGS Compositions

GeTe, a small bandgap semiconductor that has native p-type defects due to Ge vacancies, is an important constituent in the thermoelectric material known as TAGS. TAGS is an acronym for alloys of GeTe with AgSbTe₂, and compositions are normally designated as TAGS-x, where x is the fraction of GeTe. TAGS-85 is the most important with regard to applications, and there is also commercial interest in TAGS-80. The crystal structure of GeTe_1+δ has a composition-dependent phase transformation at a temperature ranging from 430°C (δ = 0) to ~400°C (δ = 0.02). The high-temperature form is cubic. The low-temperature form is rhombohedral for δ < 0.01, as is the case for good thermoelectric performance. Addition of AgSbTe₂ shifts the phase transformation to lower temperatures, and one of the goals of this work is a systematic study of the dependence of transformation temperature on the parameter x. We present results on phase transformations and associated instabilities in TAGS compositions in the range of 70 at.% to 85 at.% GeTe.     

Highly efficient electrophosphorescent polymer light-emitting devices

We report a high performance polymer electroluminescent device based on a bi-layer structure consisting of a hole transporting layer (poly(vinylcarbazole)) and an electron transporting layer poly(9,9-bis(octyl)-fluorene-2,7-diyl) (BOc-PF) doped with platinum(II)-2,8,12,17-tetraethyl-3,7,13,18-tetramethylporphyrin (PtOX). The devices show red electrophosphorescence with a peak emission at 656 nm and a full width at half maximum of 18 nm, consistent with exclusive emission from the PtOX dopants. BOc-PF emission is not observed at any bias. The required doping levels for these phosphorescence-based polymer light-emitting diodes (PLEDs) are significantly lower than for other reported phosphorescence-based PLEDs or organic light-emitting diodes (OLEDs). A doping level of 1% or more give an LED with exclusive PtOX emission, whereas related PLEDs or OLEDs doped with phosphorescent dopants require doping levels of >5% to achieve exclusive dye dopant emission. The device external efficiency was enhanced from 1% to 2.3% when doped with PtOX. The lower doping level in BOc-PF/PtOX based PLEDs decreases triplet–triplet annihilation in these devices, leading to quantum efficiency that is only weakly dependent on current density. The luminescence transient decay time for this device is 500 μs.     

From trips to telcos — next generation service portals

A number of multi-billion dollar businesses (for example Dell, Amazon, Expedia and Google) have been built on top of Web portals that provide customers with a differentiating experience. How do these portals achieve this, and what lessons can BT learn? In this paper we describe technology that supports the development of portals which extend and improve the customer’s experience of interacting with a company by breaking away from the direct manipulation metaphor. We illustrate the approach with a case study and describe the results of the work we have done in terms of the limitations and capabilities of the approach developed.     

Analysis and Implementation of Multiple–Input, Multiple–Output VBLAST Receiver From Area and Power Efficiency Perspective

This paper presents an analysis of the vertical Bell Laboratories layered space time (VBLAST) receiver used in a multiple-input multiple-output (MIMO) wireless system from the hardware implementation perspective and identifies those processing elements that consume more area and power due to complex signal processing. This paper models a scalable VBLAST receiver based on minimum mean square error (MMSE) nulling criteria assuming a block flat fading channel. After identifying the major area and power consuming blocks, this paper proposes two area and power efficient VLSI architectures for the block that computes pseudoinverse of the channel matrix. This paper discusses different tradeoff issues in both architectures and compares them with the architectures in the literature     

Effect of barrier height on the uneven carrier distribution inasymmetric multiple-quantum-well InGaAsP lasers

Four asymmetric multiple-quantum-well (AMQW) laser structures have been grown and tested. The structures demonstrate that carriers are not evenly distributed across the active region of a MQW laser. Wells at the p-side of the active region are preferentially pumped indicating there are more carriers at the p-side of the active region than at the n-side. The structures also demonstrate that decreasing the height of the barriers reduces this effect and results in a more even carrier distribution. Thus, well position and barrier height are shown to be important design parameters for AMQW and conventional MQW lasers     

vBNS: not your father's Internet

The very-high-performance Backbone Network Service (vBNS) is an important part of ongoing efforts by government, industry, and academia to push the state of the art in Internet technologies and academic research applications. It is dedicated to serving research and education institutions whose scientific endeavors require networking performance not possible or not practical with commercial network services. Currently, the vBNS is implemented as an IP-over-ATM network-that is, its network layer (layer 3 of the open systems interconnection reference model promulgated by the International Organization for Standardization) runs the Internet Protocol on top of the asynchronous transfer mode protocol. Those protocols, in turn, run on a synchronous optical network (Sonet) OC-12-622.08-Mb/s-infrastructure. Though access was originally limited to five supercomputer centers and four network access points, the National Science Foundation's High-Performance Connections program is now expanding the vBNS to reach over 100 institutions. The vBNS also has connections to other research networks, both within the United States and abroad. Before describing the architecture of the vBNS, the services it provides, and the metrics developed to assess its performance, the article reviews the background against which it came into being. It also briefly discusses how the vBNS relates to the Next Generation Internet (NGI) and Internet2     

Enhancing echo cancellation via estimation of delay

The advent of packetized audio transmission, such as voice over IP (VoIP), has resulted in challenging requirements for echo cancellation technology. One key aspect of this technology is the need to characterize, quickly and accurately, the echo paths in the transmission media. Echo paths consist of a constant time delay with no echo signal and active regions in which the echo signal is present. When an adaptive filter echo cancellation algorithm is used, its performance can be greatly increased, and its complexity can be reduced if it is only applied to the active regions. This requires an algorithm to estimate the constant delay and locate the active regions. Traditionally, delay estimation has been based on direct application of cross-correlation. This method has poor performance because the input signals are highly correlated and has a high implementation cost because many cross-correlation lags have to be computed for longer time delays. The delay estimation addressed in this paper has two major advantages over the traditional methods. The first is that it has improved performance because the input signals are processed to have less correlation. The second is that the implementation cost is significantly reduced because fewer cross-correlation lags are computed, and an efficient method to estimate lags is created.