Determination of partial resistance factors for unreinforced masonry shear walls

Partial safety factors for resistance applied in the design equation of semi‐probabilistic formats can be obtained from the evaluation of a test database. These partial safety factors are influenced by two factors, the material uncertainty and the model uncertainty. This topic is covered in a former publication [1]. It includes the determination of a partial factor for the model uncertainty of unreinforced masonry shear walls. In this study the authors examine the next step, and calculate the partial factor of resistance applying the same method, as recommended i n EN 1990 – Annex D. In addition to the Coefficient of Variation (COV) for the model uncertainty, the calculation of the resistance partial factor considers deviations in geometry, as well as loading and material properties. The influence of the material uncertainty on structural performance is considered in the calculation by means of a weighted average of all COV values for various types of material properties, based on the number of relevant failure modes in the test database. In the last step, the resistance partial factors for models defined in DIN EN 1996‐1‐1/NA and DIN EN 1996‐1‐1/NA – Annex K are calculated by applying the probabilistic methods recommended in EN 1990 – Annex D and the model bias.     

Effect of the ZrO<Subscript>2</Subscript> concentration on the crystallization behavior and the mechanical properties of high-strength MgO–Al<Subscript>2</Subscript>O<Subscript>3</Subscript>–SiO<Subscript>2</Subscript> glass–ceramics

High-strength, colorless glass–ceramics in the MgO/Al₂O₃/SiO₂ system with high concentrations of ZrO₂ and a great potential for technical application, e.g., as high-performance hard disc substrates, are investigated. ZrO₂ concentrations from 6 to 9 mol% are added to a stoichiometric cordierite glass to investigate the influence of the concentration of the nucleating agent on the crystallization behavior and the mechanical properties. The phase formation and the microstructure of the glass–ceramics are studied using X-ray diffraction and scanning electron microscopy including electron backscatter diffraction. It is shown that the volume crystallization of ZrO₂, a low-/high-quartz solid solution (low-/high-QSS), and spinel is accompanied by the surface crystallization of indialite. This phase offers a much smaller coefficient of thermal expansion than the other crystal phases, which may induce high compressive stresses in the surface layer of the glass–ceramics after cooling and seems to result in excellent mechanical properties of the material. Biaxial flexural strengths of up to 1 GPa were measured. Higher ZrO₂ concentrations reduce the surface crystallization of indialite and decrease the mean size of the crystals resulting in a higher translucency. The volume-crystallizing phases and the mechanical properties of the glass–ceramics do not seem to be significantly affected by the analyzed ZrO₂ concentrations.     

Fibrillation tendency of cellulosic fibers,part 6: Effects of treatments with additive polymers

The influences of the treatments with various polymers on fibrillation and abrasion resistances of lyocell materials were investigated with respect to the type of polymer, the polymer concentration, and the drying temperature. Fibril number, generated with agitation using ball‐bearings (FN_ball), was decreased with increasing the concentration of aminofunctional polysiloxane because of reduction in water retention capacity (WRV) in fibers. The never‐dried lyocell fiber showed smaller decrease in FN_ball because of its higher WRV when compared to dried fibers. The treatment with aminofunctional polysiloxane enhanced not only the fibrillation resistance but also abrasion resistance, which was indicated as rotation number of abrasive bar in the abrasion test (RN_abr). No fibrillation was obtained in the fiber treated with 10 g/L aminofunctional polysiloxane at 120°C for 20 min, while the fibers treated at 60 and 170°C for 15 min were fibrillated in the agitation and abrasion tests. The addition of secondary polyethylene derivative also reduced the fibrillation tendency of lyocell; however, the extent of the reduction was lesser when compared with aminofunctional polysiloxane. The treatments with polyacrylate, polyurethane, and polyisocyanate derivatives improved the fibrillation resistance in lyocell fabrics, while fiber abrasion resistance was not significantly improved by the treatment with those additives, except in polyisocyanate. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4140–4147, 2006     

Raman and infrared spectroscopic investigations on aqueous alkali metal phosphate solutions and density functional theory calculations of phosphate-water clusters

Phosphate (PO(4)(3-)) solutions in water and heavy water have been studied by Raman and infrared spectroscopy over a broad concentration range (0.0091-5.280 mol/L) including a hydrate melt at 23 degrees C. In the low wavenumber range, spectra in R-format have been constructed and the R normalization procedure has been briefly discussed. The vibrational modes of the tetrahedral PO(4)(3-)(aq) (T(d) symmetry) have been assigned and compared to the calculated values derived from the density functional theory (DFT) method for the unhydrated PO(4)(3-)(T(d)) and phosphate-water clusters: PO(4)(3-).H(2)O (C(2v)), PO(4)(3-).2H(2)O (D(2d)), PO(4)(3-).4H(2)O (D(2d)), PO(4)(3-).6H(2)O (T(d)), and PO(4)(3-).12H(2)O (T), a cluster with a complete first hydration sphere of water molecules. A cluster with a second hydration sphere of 12 water molecules and 6 in the first sphere, PO(4)(3-).18H(2)O (T), has also been calculated. Agreement between measured and calculated vibrational modes is best in the case of the PO(4)(3-).12H(2)O cluster and the PO(4)(3-).18H(2)O cluster but far less so in the case of the unhydrated PO(4)(3-) or phosphate-water cluster with a lower number of water molecules than 12. The asymmetric, broad band shape of v(1)(a(1)) PO(4)(3-) in aqueous solutions has been measured as a function of concentration and the asymmetric and broad band shape was explained. However, the same mode in heavy water has only half the full width at half-height compared to the mode in normal water. The PO(4)(3-) is strongly hydrated in aqueous solutions. This has been verified by Raman spectroscopy comparing v(2)(H(2)O), the deformation mode of water, and the stretching modes, the v(1)OH and v(3)OH of water, in K(3)PO(4) solutions as a function of concentration and comparison with the same modes in pure water. A mode at approximately 240 cm(-1) (isotropic R spectrum) has been detected and assigned to the restricted translational mode of the strong hydrogen bonds formed between phosphate and water, P-O...HOH. In very concentrated K(3)PO(4) solutions (C(0) > or = 3.70 mol/L) and in the hydrate melt, formation of contact ion pairs (CIPs) could be detected. The phosphate in the CIPs shows a symmetry lowering of the T(d) symmetry to C(3v). In the less concentrated solutions, PO(4)(3-)(aq) solvent separated ion pairs and doubly solvent separated ion pairs exist, while in very dilute solutions fully hydrated ions are present (C(0) < or = 0.005 mol/L). Quantitative Raman measurements have been carried out to follow the hydrolysis of PO(4)(3-)(aq) over a very broad concentration range. From the hydrolysis data, the pK(3) value for H(3)PO(4) has been determined to be 12.45 at 23 degrees C.     

The collective effect of finite-sized inhomogeneities on the spatial spread of populations in two dimensions

The dynamics of a population expanding into unoccupied habitat has been primarily studied for situations in which growth and dispersal parameters are uniform in space or vary in one dimension. Here, we study the influence of finite-sized individual inhomogeneities and their collective effect on front speed if randomly placed in a two-dimensional habitat. We use an individual-based model to investigate the front dynamics for a region in which dispersal or growth of individuals is reduced to zero (obstacles) or increased above the background (hotspots), respectively. In a regime where front dynamics is determined by a local front speed only, a principle of least time can be employed to predict front speed and shape. The resulting analytical solutions motivate an event-based algorithm illustrating the effects of several obstacles or hotspots. We finally apply the principle of least time to large heterogeneous environments by solving the Eikonal equation numerically. Obstacles lead to a slow-down that is dominated by the number density and width of obstacles, but not by their precise shape. Hotspots result in a speed-up, which we characterize as function of hotspot strength and density. Our findings emphasize the importance of taking the dimensionality of the environment into account.     

Solar water splitting with p-SiC film on p-Si: Photoelectrochemical behavior and XPS characterization

The electrochemical properties of single-crystalline p-type 3C-SiC films on p-Si substrate were investigated as an electrode in H₂SO₄ aqueous solutions in dark and under white light illumination. The photoelectrochemical (PEC) measurements indicates the p-type 3C-SiC film on p-Si substrate can generate a cathodic photocurrent as a photocathode, which corresponds to hydrogen production, and generate an anodic photocurrent as a photoanode, which corresponds to oxygen evolution. The surface chemical states of the films were investigated by XPS. In order to observe the surface chemical state changes after PEC test, the range of applied potential to the electrode was divided into three zones: −3.6 to 0 V, 0–1.5 V and 1.5–4 V vs. Ag/AgCl. After separated PEC tests in these three areas, XPS shows the surface of the SiC film in the range of −3.6 to 0 V and 0–1.5 V was stable without oxidation except the band bending occurred. But in the range of 1.5–4 V the film surface was oxidized due to anodic oxidation.