Synthesis, isolation, spectroscopic and electrochemical characterization of some calcium-containing metallofullerenes

A few Ca-containing mono-metallofullerenes, i.e. Ca@C₇₆, Ca@C₈₈, Ca@C₉₀ (I, II), were synthesized by an improved DC arc discharge method and isolated by a multi-stage HPLC method for the first time. These isomer-separated metallofullerenes were characterized by LD-TOF MS and UV-vis-NIR spectrometry. Their HOMO-LUMO band gaps and possible molecular geometries are discussed according to the absorption spectra in this report. In addition, the cyclic and differential pulse voltammetry of Ca@C₇₆ was conducted in MeCN/C₆H₅CH₃ (1:4 v/v). The voltammograms of Ca@C₈₂ (II, III) and Ca@C₈₄ (II) were also recorded. Their electrochemical behaviors are discussed compared with those of corresponding ytterbium metallofullerenes. The features of the Ca metallofullerenes’ electronic structures are also discussed.     

Studies of structure and cycleability of LiMn2O4 and LiNd0.01Mn1.99O4 as cathode for Li-ion batteries

Lithium manganese oxides LiMn₂O₄ and rare earth elements doped LiNd_0.01Mn_1.99O₄ were synthesized by microwave method. The structure and the electrochemical performances of the samples were characterized. XRD data shows both samples exhibit the same pure spinel phase. But due to the introduction of Nd³⁺ ion into the unit cell, the lattice parameter of the Nd-doped spinel was larger than that of the undoped one. The two samples had a similar morphology including small particle size and homogeneous particle distribution as tested by SEM. The cyclic voltammmetry and constant-current charge-discharge tested that Nd-doped spinel displayed a better reversibility and cycleability.     

农村基层民主政治建设存在的主要问题及对策

党的十一届三中全会以来．我国农村基层民主政治建设取得了长足的进步,但也存在基层干部素质不高、村民不能正确行使权利、相关法律法规不完善等问题。要规范、完善和落实各项民主制度、提高农村基层干部和村民的素质,从而推进我国农村基层民主政治建设更好发展。     

浅谈构建安全的长江海事电子政务网络体系

电子政务已成为长江海事局工作信息化的重点工程。对长江海事电子政务网络建设的基础安全服务设施、安全管理保障体系、安全技术支撑平台和响应与恢复机制等问题进行了分析,并结合实践经验,提出了建立安全可靠的长江海事电子政务网络体系的对策。     

对"第二交现代化"理论的异议

改革开放以来逐步形成的中国特色社会主义现代化理论,始终服务于本世纪中页建设社会主义现代化国家的目标.十六大以来,中国特色社会主义现代化理论逐渐引入后现代化和可持续发展理论,表明中国利用后发优势走科学发展的捷径.到本世纪中期,中国的三步走战略目标完成之前,中国现代化理论处于传统现代化理论时期,这一时期的现代化理论称作中国特色社会主义现代化理论.     

提高MG2×150/700-WD型采煤机截割部轴承寿命周期的设计改进

通过改进结构及轴承类型,提高MG2×150/700-WD型交流电牵引采煤机截割部轴承使用周期。     

临川区土地生态环境安全评价研究

通过对临川区土地生态环境的研究,采用德尔菲法、等距划分法、加权指数法,确定该区域生态环境评价指标、权重、以及安全等级,得出临川区各乡镇的生态环境安全指数,为临川区土地生态环境安全建设提出建议。     

我国电子签名法所面临的问题及对策研究

《中华人民共和国电子签名法》是我国信息化领域的第一部法律。本文阐述了《电子签名法》的主要内容,分析了它在当今信息化产业中的重要作用以及存在的不足,并且对其应采取的对策进行了探究。     

Fabrication and characterization of nano silver powder prepared by spray pyrolysis

Silver powder was fabricated by spray pyrolysis, using 2%–20% AgNO₃ solution, 336–500 mL/h flux of AgNO₃ solution, 0.28–0.32 MPa flux of carrier gas and in the 620–820 °C temperature range. The effects of furnace set temperature, concentration of AgNO₃ aqueous solution, flux of AgNO₃ aqueous solution as well as carrier gas on the morphology and particle size distribution of silver powder, were investigated. The experimental results showed that with the high concentration of AgNO₃ aqueous solution, the average grain size of silver decreased with the increasing of furnace set temperature. But the gain size distribution was not homogenous, the discontinuous grain growth occurred. With the low concentration of AgNO₃ aqueous solution, the higher furnace set temperature made the nano sliver grains sintered together to grow. Nano silver powder about 100 nm was fabricated by spray pyrolysis, using 2wt% AgNO₃ solutions, 336 mL/h flux of AgNO₃ aqueous solution, 0.32 MPa flux of carrier gas at 720 °C furnace set temperature.     

工程咨询在低碳经济发展中要有所作为

一、低碳经济将成为未来经济发展方向 所谓低碳经济是指以低能耗、低物耗、低排放、低污染为特征的绿色经济发展模式。它要求以最少的温室气体排放获得最大的经济产出。是人类社会继农业文明、工业文明之后的又一次重大进步,是生态文明建设的内在要求。