Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

方波扫描路径确定声源声功率误差特性分析

改进了矩形测量面方波扫描路径测量声功率的误差模型 ,以单极子、偶极子及四极子声源为例 ,给出了扫描方向、测量面离声源的距离及扫描线的密度的选取对理论误差的分布图形。分析结果表明 :对选定的测量面 ,在扫描线密度小的情况下 ,通过调整声源离测量面的距离 ,可以在声源近处找到一个最优点或较优点 ,使理论误差为零或很小 ;在绝大多数情况下 ,沿测量面长边扫描误差比沿短边扫描小。     

The Effects of Filtered Channel Quality Feedback on Throughput of Proportional Fair Algorithm

1　IntroductionSchedulingalgorithmsarewidelystudiedforwirelesspacketdatasystems,whichgenerallyhavetwobasiccategories,oneisoptimizedforsystemthroughputandfairness[1～ 2 ] ,andtheotherisforthequalityofservice[3～6] .Forsystemswherepack etdataaretimedivisionmultiplexedacrossusersonthedownlink ,orfromBaseStation (BS)tomultipleMobileStations(MS) ,theBSusesschedulingalgo rithmstodecidewhichuseristransmittedto .ItisindicatedinRefs.[7,8]thatschedulingonlyoneus eratatimeisoptimalfromthepointofviewo…     

Effect of nitrocarburizing on sulphide layer during nitrocarburizing-sulphurating treatment

Compared with the single sulphurating treatment, the duplex treatment of nitrocarburizing-sulphurating can more effectively improve the properties of steel such as friction-reducing, wear resistance and anti-scuffing. Under the same processing parameters, the sulphide layers were fabricated on the surface of CrMoCu alloy cast iron by single ion-sulphurating treatment and nitrocarburizing-sulphurating duplex treatment, respectively. Through the analysis of the sulphide, the effect of the nitrocarburizing on the fabrication of the sulphide layer was investigated. And the result shows that the fabrication of sulphide layer is promoted by the nitrocarburizing treatment.     

大港油田CNG加气站技术特点

天然气作为我国最主要能源之一，其应用领域在不断地扩展。由于天然气受管网敷设的限制。在压缩、储运等方面的技术也引起了众多企业的重视，并成为一些企业发展的战略目标。2004年大港油田依靠地域和气源的优势，建成了天津市首座CNG加气站。经过一年来的生产运行，显现出较好的经济效益和良好的发展前景。从环保性、安全性和经济性等方面阐述了CNG技术特点和发展的优势，对大港油田已建CNG加气站的主要设备、工艺流程、技术特点以及市场发展前景进行了较详尽的阐述。     

一种数字语音通信系统的DSP实现

介绍了一种甚低频低码率数字通信系统的实现方案，该方案中的软件采用混合编程的方法，硬件则用DSP实现，文章给出了整个系统的DSP软硬件调试方法，并通过调试结果表明该方案具有很好的可行性和实时性。     

自治Agents的面向服务的协商模型

提出了一个基于自治Agents的面向服务的协商模型。模型主要包括两大模块：首先定义了一系列的战略和战术过程，使得Agents可以产生初始建议，评价对方的建议，以及在此基础上做出反建议；其次，定义了两个层次的Agent通信机制。二者相辅相成，实现了Agents间合作的动态形成和随机协调，使得Agents可以承担因环境的不确定性而需动态协作的复杂任务。     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

DataSocket技术在远程测试中的研究与应用

本文介绍了一种实时数据传输技术-DataSocket,并给出了具体实例说明了如何将利用DataSocket技术来实现远程测试。