玻璃基多孔骨水泥的制备和性能研究

将SiO2-CaO-P2O5系统生物活性玻璃粉末、甘露醇和磷酸铵调和液均匀混合制得多孔玻璃基骨水泥.利用XRD、FTIR和SEM对骨水泥的晶相和显微结构进行了观察和分析,并对其显气孔率和力学强度进行了测试.实验结果表明,随着浸泡时间的增加,骨水泥固化体中生成了HAP晶体,HAP晶体呈短柱状,交织分布于玻璃颗粒间隙,尺寸大约为200nm;甘露醇晶体能在生理模拟液的浸泡下降解,降解后留下的孔隙显著增加了骨水泥的显气孔率,并且随着甘露醇含量的增加而增加,而体积密度和力学强度则呈下降的趋势.     

防范入侵的静态分析技术比较

建立了一个具有常见漏洞的测试代码,然后通过扫描测试代码来比较3个典型应用静态分析技术来防范入侵的常用工具。比较结果揭示了检查漏洞库函数的工具漏报率较低,但误报率较高;基于约束分析的工具误报率较低,但漏报率较高;利用软件模型来检测漏洞的工具在检测违背指定安全规则的漏洞时漏报率较低,但在检测具有许多安全漏洞类型的程序时漏报率却非常低。     

Resveratrol inhibits migration and invasion of human breast‐cancer cells

Metastasis is the primary cause of death from breast cancer. Cell migration and invasion play important roles in neoplastic metastasis. The insulin‐like growth factor (IGF‐1) stimulates cell migration through activation of PI‐3K/Akt signaling pathway. IGF‐1 induces the tumorigenicity of many types of cancer cells and is critical for metastatic cell spread in estrogen receptor (ER)‐negative breast‐cancer cells. Matrix metalloproteinase‐2 (MMP‐2) is a key enzyme in the degradation of extracellular matrices and its expression has been dysregulated in breast cancer invasion and metastasis. Resveratrol exhibited potential anticarcinogenic activities in several studies. However, the inhibitory effects of resveratrol on the expression of MMP‐2, migration and invasion of breast‐cancer cell have not been demonstrated yet. In the present study, we investigated the anti‐invasive mechanism of resveratrol in human breast cancer MDA‐MB 435cells. Here, we showed that IGF‐1 is a potent stimulant of the migration of ER‐negative human breast‐cancer cells. Resveratrol could inhibit IGF‐1‐mediated cell migration of MDA‐MB 435 in vitro. The inhibitory effect of resveratrol was mediated in part through the suppression of the activation of PI‐3K/Akt signaling pathway. Furthermore, IGF‐1‐mediated expression of MMP‐2 was significantly inhibited by resveratrol in concomitance with alteration of cell invasion.     

Crystallization behavior,heat resistance,and mechanical performances of PLLA/myo‐inositol blends

In this work, use of myo‐inositol as a biobased nucleating agent (NA) for PLLA was researched. Effects of myo‐inositol on non‐isothermal and isothermal crystallization behaviors of PLLA at temperatures ranged from 85 °C to 130 °C were studied by using DSC, POM and WAXD. Isothermal crystallization kinetics results showed that the incorporation of myo‐inositol enhanced significantly the crystallization rate of the PLLA samples. It was confirmed that the optimum isothermal crystallization temperature range was 100 to 110 °C. The above results were instructive to confirm proper heat treatment time and temperature for compression or injection molding to fabricate highly crystallized PLLA articles. The relations among heat treatment time, crystallinity, heat resistance, and mechanical performances of the neat PLLA and PLLA/1% myo‐inositol specimens prepared by compression molding were investigated. Compared with the PLLA specimens, the PLLA/1% myo‐inositol specimens showed a shorter heat treatment time to reach the maximum crystallinity. Vicat softening temperature, as well as tensile strength, modulus, and toughness of the PLLA/1% myo‐inositol specimens was improved when crystallinity increased from 5.4% to 38.1%. Considering the nontoxicity and biocompatibility of myo‐inositol, PLLA/myo‐inositol blends would be potential to prepare some products, which are required higher health standard and can be used in elevated temperature environments. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44732.     

玻璃熔窑池壁侵蚀机理的研究(二)

运用X射线衍射分析,对池壁各特征点处侵蚀前后的耐火材料试样通过受侵材料的X谱图所呈现出的衍射峰图进行所含晶相的分析,研究玻璃窑池壁的侵蚀机理以及不同点处的差异.     

Isothermal melt crystallization and performance evaluation of polylactide/thermoplastic polyester blends with multi‐functional epoxy

A multi‐functional epoxy (ADR) was used to improve compatibilization of poly(lactic acid) (PLA)/ thermoplastic polyester elastomer (TPEE) blends. Influence of ADR on isothermal melt crystallization of the blends was investigated. The results show that isothermal melt crystallization rate of the samples increases with ADR loading. It can be attributed to a nucleation enhancement resulted from an increase of molecular weight and melt viscosity created by the chain extension/branched process of PLA in the presence of ADR. In addition, the maximum crystallinity of the samples shows a decrease with increasing ADR loading because of the chain extended and branched reaction. Quenched and crystallized samples were fabricated using compression molding under different cooling conditions in‐mold. Effects of crystallinity and ADR on mechanical performances of the PLA/TPEE sample were investigated. With increasing the crystallinity, the PLA/TPEE sample shows a marked enhancement in heat resistance. However, the tensile ductility of the crystallized PLA/TPEE sample drastically decreases due to the formation of firm crystal crosslinking and the incompatibility between PLA and TPEE. It is notable that the tensile ductility of the crystallized samples is improved with the introduction of ADR owing to its reactive compatibilization effect. Finally, the crystallized PLA/TPEE/ADR samples with improved heat resistance and relative higher ductility are obtained. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46343.     

上海源水中DOM的分子质量及去除特性

采用分子质量排除高性能液相色谱仪 (SE—HPLC)对长江和黄浦江原水及经常规处理出水中溶解性有机物 (DOM)的分子质量分布进行了测定 ,原水中DOM分子质量分别为 80 0～ 44 0 0u和 80 0～ 1130 0u。长江原水经常规处理后的DOM分子质量分布基本不变 ,对不同分子质量的物质均有不同程度的去除 ,且分子质量越低 ,常规处理对UV2 60 的去除率也越小 ;而黄浦江原水经常规处理后有机物的分子质量分布向低分子侧推移 ,表明对大分子的去除率优于小分子 ,特别是对分子质量 <30 0 0u有机物的去除率极低。     

基于数字体散斑法煤样内部三维应变场的测量

煤岩内部三维应力应变场的测量对冲击地压、气体吸附及煤与瓦斯突出的机理研究具有重要意义,但在实验室中很少有方法能够直接测量煤岩内部三维应力应变场。采用新近发展的数字体散斑法与微焦点工业CT相结合的方法分别测量了单轴压缩和CO2气体吸附过程中煤样内部的变形,由变形获得煤样内部的三维应变场。研究表明,煤样内部天然结构可以作为携带变形信息的散斑结构,用于变形测量。通过单轴压缩煤样内部等效应变及体积应变的可视化,直观地显示出试件内部应变局部化区域孕育发展的过程,煤样的变形破坏具有明显的应变局部化特征,应变局部化区域与煤样最终破坏断裂区域位置一致。利用DVSP法测得了煤样吸附CO2过程中的三维应变场,并与应变片测量结果进行了对比,两者具有较好的一致性。通过体积应变的分布图直观揭示出煤样在吸附气体过程中存在膨胀区与压缩区,由于非均质性造成内部变形不均匀。     

核壳结构磁性复合纳米粒的制备及研究进展

多功能磁性复合纳米粒在生物医学上具有广泛的应用和巨大的潜力.首先介绍了二氧化硅、金银贵金属和荧光半导体核壳磁性复合纳米粒的应用前景,重点阐述了溶胶-凝胶法、微乳液法、自组装技术和种子生长法在制备核壳结构磁性复合纳米粒中的应用,分析了磁性纳米粒存在的问题,展望了其发展的方向.     

果品无损检测技术的研究现状

无损检测是近年来发展起来的高科技技术之一 ,在工业和农业的应用方面得到了广泛的研究。文中综述了目前无损检测技术在国内外果蔬产品品质检验中的应用现状 ,并指出了果品品质无损检测技术的发展方向。