Achieving time-of-flight mobilities for amorphous organic semiconductors in a thin film transistor configuration

We observe bulk-like hole transport in amorphous organic semiconductors in a thin film transistor (TFT) configuration. Five different organic hole transporters (HTs) commonly used in organic light-emitting diodes are investigated. When these HTs are deposited on SiO₂ gate dielectric layer, the TFT mobilities are 1–2 orders of magnitude smaller than those obtained from bulk films (3–8 μm) using time-of-flight (TOF) technique. The reduction of hole mobilities can be attributed to the interactions between the organic HTs and the polar SiO bonds on the gate dielectric layer. Detailed temperature dependence studies, employing the Gaussian disorder model, indicate that the SiO₂ gate dielectric contributes between 60 and 90 meV of energetic disorder in the charge hopping manifold. Besides SiO₂ gate dielectric, similar effects can also be observed for other polar insulators including polymeric PMMA and BCB, or HMDS-modified SiO₂. However, when a common non-polar polymer, polystyrene (PS), is employed as the dielectric layer, the dipolar energetic disorder becomes negligible. Holes effectively experience bulk-like transport on the PS gate dielectric surface. TFT mobilities extracted from all five organic HTs are in excellent agreements with TOF mobilities. The present study should have broad applications in the transport characterization of amorphous organic semiconductors.     

Structural and Optical Properties of ZnO Nanotips Grown on GaN Using Metalorganic Chemical Vapor Deposition

ZnO nanotips are grown on epitaxial GaN/c-sapphire templates by metalorganic chemical vapor deposition. X-ray diffraction (XRD) studies indicate that the epitaxial relationship between ZnO nanotips and the GaN layer is (0002)ZnO||(0002)GaN and (101̄0)ZnO||(101̄0)GaN. Temperature-dependent photoluminescence (PL) spectra have been measured. Sharp free exciton and donor-bound exciton peaks are observed at 4.4 K with photon energies of 3.380 eV, 3.369 eV, and 3.364 eV, confirming high optical quality of ZnO nanotips. Free exciton emission dominates at temperatures above 50 K. The thermal dissociation of these bound excitons forms free excitons and neutral donors. The thermal activation energies of the bound excitons at 3.369 eV and 3.364 eV are 11 meV and 16 meV, respectively. Temperature-dependent free A exciton peak emission is fitted to the Varshni’s equation to study the variation of energy bandgap versus temperature.     

Synthesis of sulfur-doped ZnO nanowires by electrochemical deposition

Sulfur-doped zinc oxide (ZnO) nanowires have been successfully synthesized by an electric field-assisted electrochemical deposition in porous anodized aluminum oxide template at room temperature. X-ray diffraction and the selected area electron diffraction results show that the as-synthesized nanowires are single crystalline and have a highly preferential orientation. Transmission electron microscopy observations indicate that the nanowires are uniform with an average diameter of 70 nm and length up to several tens of micrometers. X-ray photoelectron spectroscopy further reveals the presence of S in the ZnO nanowires. Room-temperature photoluminescence is observed in the doped ZnO nanowires, which exhibits a violet emission and blue emissions besides the typical photoluminescence spectrum of a single crystal ZnO.     

Mitigating the gateway bottleneck via transparent cooperative caching in wireless mesh networks

Wireless mesh networks (WMNs) have been proposed to provide cheap, easily deployable and robust Internet access. The dominant Internet-access traffic from clients causes a congestion bottleneck around the gateway, which can significantly limit the throughput of the WMN clients in accessing the Internet. In this paper, we present MeshCache, a transparent caching system for WMNs that exploits the locality in client Internet-access traffic to mitigate the bottleneck effect at the gateway, thereby improving client-perceived performance. MeshCache leverages the fact that a WMN typically spans a small geographic area and hence mesh routers are easily over-provisioned with CPU, memory, and disk storage, and extends the individual wireless mesh routers in a WMN with built-in content caching functionality. It then performs cooperative caching among the wireless mesh routers.We explore two architecture designs for MeshCache: (1) caching at every client access mesh router upon file download, and (2) caching at each mesh router along the route the Internet-access traffic travels, which requires breaking a single end-to-end transport connection into multiple single-hop transport connections along the route. We also leverage the abundant research results from cooperative web caching in the Internet in designing cache selection protocols for efficiently locating caches containing data objects for these two architectures. We further compare these two MeshCache designs with caching at the gateway router only.Through extensive simulations and evaluations using a prototype implementation on a testbed, we find that MeshCache can significantly improve the performance of client nodes in WMNs. In particular, our experiments with a Squid-based MeshCache implementation deployed on the MAP mesh network testbed with 15 routers show that compared to caching at the gateway only, the MeshCache architecture with hop-by-hop caching reduces the load at the gateway by 38%, improves the average client throughput by 170%, and increases the number of transfers that achieve a throughput greater than 1 Mbps by a factor of 3.     

Mechanism of O2-anneal induced Vfb shifts of Ru gated stacks

A systematic study of the flat-band voltage (V_fb) shift of Ru gated metal-oxide-semiconductor (MOS) capacitors subjected to thermal treatment in O₂ has been performed. The dependence of the V_fb shift on the thickness of Ru, anneal temperature and time is studied. The V_fb shift is ascribed to the shift of metal gates’ work function (WF), and is not significantly dependent on the type of dielectric (HfO₂ or SiO₂). From time-of-flight secondary ion mass spectrometry (TOF-SIMS) measurement, it was found that after thermal treatment in ¹⁸O₂, ¹⁸O penetrated through Ru and was incorporated in the Ru/dielectric interface region. We believe that the formation of the thin interfacial RuO_x layer is responsible for the V_fb shift.     

Resistance Compression Networks for Radio-Frequency Power Conversion

A limitation of many high-frequency resonant inverter topologies is their high sensitivity to loading conditions. This paper introduces a new class of matching networks that greatly reduces the load sensitivity of resonant inverters and radio frequency (RF) power amplifiers. These networks, which we term resistance compression networks, serve to substantially decrease the variation in effective resistance seen by a tuned RF inverter as loading conditions change. We explore the operation, performance characteristics, and design of these networks, and present experimental results demonstrating their performance. Their combination with rectifiers to form RF-to-dc converters having narrow-range resistive input characteristics is also treated. The application of resistance compression in resonant power conversion is demonstrated in a dc-dc power converter operating at 100MHz     

SrCaO Protective Layer for High-Efficiency PDPs

The sustain pulse voltage of the panel for 66-kPa Ne + Xe (5%-30%) is 20%-40% lower with a Sr_0.62Ca_0.38O protective layer than with a MgO protective layer. At a normal sustain voltage of 160-200 V, the luminous efficiency of the panel with the Sr_0.62 Ca_0.38O protective layer for Xe (30%) is about twice as high as with the MgO protective layer for Xe (10%). The luminances of these panels are almost the same. This high efficiency at normal sustain pulse voltage and normal luminance is obtained through the combined use of the Sr_0.62Ca_0.38O protective layer and high Xe content. With regard to ion bombardment, the Sr_0.62Ca_0.38O film has a 4.5 times longer life than SrO film and nearly 80% of the life of MgO film. We also calculated the values of theoretical secondary electron emission yield gamma_imin of MgO, SrO, and CaO without energy bands in the band gap for rare gas ions and found that [ gamma_imin of MgO] les [gamma_imin of CaO] < [gamma_imin of SrO] except for the one case with He. The breakdown voltage decreases with higher gamma_imin values. As expected, the discharge voltage of the panel is much lower with the SrO protective layer than with the MgO protective layer. The discharge voltages of the panels with Sr_0.62Ca_0.38O and SrO protective layers are almost the same. These findings show that the life of the SrO protective layer can be made 4.5 times longer without any increase in the discharge voltage by adding CaO (40 at.%)     

The Interaction Force Between a Permanent Magnet and a Superconducting Ring

The interaction force between a small magnet and a superconducting ring in assumptions of the Meissner state was analyzed using the dipole-dipole interaction model. Two configurations were evaluated: the vertical configuration when the magnetic moment lies parallel to the symmetry axis of the ring and the horizontal when it is perpendicular. The levitation force on the magnet increases by decreasing the distance from the center of the ring up to a maximum value and then decreases down to zero when the magnet is exactly at the center of the ring. The levitation force when the magnet is in the horizontal configuration is mostly higher than that when it is in the vertical configuration. Simulation results were compared with experimental results reported in literature.     

A DCM‐Type Red‐Fluorescent Dopant for High‐Performance Organic Electroluminescent Devices

2‐(2‐tert‐Butyl‐6‐((E)‐2‐(2,6,6‐trimethyl‐2,4,5,6‐tetrahydro‐1H‐pyrrolo[3,2,1‐ij]quinolin‐8‐yl)vinyl)‐4H‐pyran‐4‐ylidene)malononitrile (DCQTB) is designed and synthesized in high yield for application as the red‐light‐emitting dopant in organic light‐emitting diodes (OLEDs). Compared with 4‐(dicyanomethylene)‐2‐tert‐butyl‐6‐(1,1,7,7,‐tetramethyljulolidyl‐9‐enyl)‐4H‐pyran (DCJTB), one of the most efficient red‐emitting dopants, DCQTB exhibits red‐shifted fluorescence but blue‐shifted absorption. The unique characteristics of DCQTB with respect to DCJTB are utilized to achieve a red OLED with improved color purity and luminous efficiency. As a result, the device that uses DCQTB as dopant, with the configuration: indium tin oxide (ITO)/N,N′‐bis(1‐naphthyl)‐N,N′‐diphenyl‐1,1′‐biphenyl‐4,4′‐diamine (NPB; 60 nm)/tris(8‐quinolinolato) aluminum (Alq₃):dopant (2.3 wt %) (7 nm)/2,9‐dimethyl‐4,7‐diphenyl‐1,10‐phenanthroline (BCP; 12 nm)/Alq₃(45 nm)/LiF(0.3 nm):Al (300 nm), shows a larger maximum luminance (L_max = 6021 cd m^–2 at 17 V), higher maximum efficiency (η_max = 4.41 cd A^–1 at 11.5 V (235.5 cd m^–2)), and better chromaticity coordinates (Commission Internationale de l'Eclairage, CIE, (x,y) = (0.65,0.35)) than a DCJTB‐based device with the same structure (L_max = 3453 cd m^–2 at 15.5 V, η_max = 3.01 cd A^–1 at 10 V (17.69 cd m^–2), and CIE (x,y) = (0.62,0.38)). The possible reasons for the red‐shifted emission but blue‐shifted absorption of DCQTB relative to DCJTB are also discussed.     

Highly Ordered Mesoporous Silicon Carbide Ceramics with Large Surface Areas and High Stability

Highly ordered mesoporous silicon carbide ceramics have been successfully synthesized with yields higher than 75 % via a one‐step nanocasting process using commercial polycarbosilane (PCS) as a precursor and mesoporous silica as hard templates. Mesoporous SiC nanowires in two‐dimensional (2D) hexagonal arrays (p6m) can be easily replicated from a mesoporous silica SBA‐15 template. Small‐angle X‐ray diffraction (XRD) patterns and transmission electron microscopy (TEM) images show that the SiC nanowires have long‐range regularity over large areas because of the interwire pillar connections. A three‐dimensional (3D) bicontinuous cubic mesoporous SiC structure (Ia3d) can be fabricated using mesoporous silica KIT‐6 as the mother template. The structure shows higher thermal stability than the 2D hexagonal mesoporous SiC, mostly because of the 3D network connections. The major constituent of the products is SiC, with 12 % excess carbon and 14 % oxygen measured by elemental analysis. The obtained mesoporous SiC ceramics are amorphous below 1200 °C and are mainly composed of randomly oriented β‐SiC crystallites after treatment at 1400 °C. N₂‐sorption isotherms reveal that these ordered mesoporous SiC ceramics have high Brunauer–Emmett–Teller (BET) specific surface areas (up to 720 m² g^–1), large pore volumes (～ 0.8 cm³ g^–1), and narrow pore‐size distributions (mean values of 2.0–3.7 nm), even upon calcination at temperatures as high as 1400 °C. The rough surface and high order of the nanowire arrays result from the strong interconnections of the SiC products and are the main reasons for such high surface areas. XRD, N₂‐sorption, and TEM measurements show that the mesoporous SiC ceramics have ultrahigh stability even after re‐treatment at 1400 °C under a N₂ atmosphere. Compared with 2D hexagonal SiC nanowire arrays, 3D cubic mesoporous SiC shows superior thermal stability, as well as higher surface areas (590 m² g^–1) and larger pore volumes (～ 0.71 cm³ g^–1).