共振散射光谱法研究槲皮素与DNA相互作用

在BR缓冲液中,槲皮素存在微弱的共振散射现象,分别在288 nm、466 nm、562 nm处出现共振散射峰,随着DNA的加入,散射信号逐渐增强,且以上3处的峰值明显增加,并且562 nm处的增加值与DNA在3.024×10-7 mol/L～9.072×10-5 mol/L范围内呈现出良好的线性关系.在20℃时,通过Scatchard方程计算出槲皮素与DNA结合常数K=9.91×106 mol-1.L.     

高校“三困生”思想政治教育工作有效途径

高校＂三困生＂是大学生中的弱势群体,有其自身鲜明特点。根据对＂三困生＂形成发展的内、外因素分析,笔者认为,心理困难是大学生由＂单困＂到＂三困＂的重要原因,也是新时期＂三困生＂思想政治教育的重点和难点。高校要做好＂三困生＂思想政治教育,应该以加强大学生心理健康教育为重点,同时加强对贫困学生的经济资助与大学生养成教育,并充分发挥＂社会—高校—家庭＂的宏观体系的育人功能,促进＂三困生＂全面发展。     

2-巯基-5-甲氧基咪唑并[4,5-b]吡啶的合成

以2,6-二氯吡啶为原料,经过硝化、氨解、甲氧基取代、还原和环化5步反应制得泰妥拉唑重要中间体2-巯基-5-甲氧基咪唑并[4,5-b]吡啶,总收率达40.2%.通过红外光谱、核磁共振氢谱对部分中间体及最终产品的结构进行表征,证明结果正确.     

Spatial distribution and environmental characterization of sediment-associated metals from middle-downstream of Xiangjiang River, southern China

The contamination and environmental risk assessment of the toxic elements in sediments from the middle-downstream (Zhuzhou—Changsha section) of the Xiangjiang River in Hunan Province of China were studied. The results show that As, Cd, Pb and Zn are major contaminants in sediments, and average concentrations of these elements significantly exceed both the Control Standards for Pollutants in Sludge of China (GB4284-84) for agricultural use in acidic soils and the effect range median (ERM) values. The average concentrations of As, Cd and Pb in the river water slightly exceed the limit of Surface Water Environment Quality Standard (GB3838—2002). The concentrations of As and Cr in depth profiles extensively change, but slight changes are observed in Pb and Zn. Cd and Zn in most sediment samples can easily enter the food-chain and bring possible ecotoxicological risk to organisms living in sediments according to the risk assessment code.     

Preparation,characterization and salt-resistance of a coal based super absorbent composite

Potassium humate was extracted from brown coal.A novel super absorbent composite,poly (acrylic acid-co-acrylamide)/potassium humate (PAA-AM/KHA),was prepared by graft polymerization of acrylic acid,acrylamide and coal based potassium humate using N,N'-methylenebisacrylamide as a crosslinker and potassium peroxydisulfate as an initiator.The effects of reaction temperature,degree of neutralization of the poly (acrylic acid) and the amounts of crosslinker,initiator and potassium humate were investigated.Salt resistance tests were also carried out.The composite prepared under optimal conditions had a potassium humate content of 10% and exhibited a water absorption of 770 g/g in distilled water,and 349,286 and 41 g/g in 0.5 mol/L KC1,MgCl2 and AlCl3 solutions respectively.The results indicate that the salt resistance of PAA-AM/KHA was superior to that of poly (acrylic acid-co-acrylamide) because of the collaborative effect of functional groups of the coal based potassium humate.The PAA-AM/KHA micro powder was characterized by IR spectroscopy and the micrographic surface was characterized by scanning electron microscopy.Introduction of potassium humate into the poly (acrylic acid-co-acrylamide) structure creates a composite more suitable for use as a water-managing material in the renewal of arid and desert environments.The salt resisting property of the composite is improved,production costs are reduced and the growth stimulant effect is still present.     

多重网格法在地球物理正反演应用研究中的进展

现阶段地球物理三维勘探面临越来越复杂的问题,其要求更精细的三维网格剖分,现有的一些方法随着网格节点的增加其收敛速度相应减慢。对于应用中更复杂实际模型、更细密网格剖分以及更快收敛速度要求,难于有进一步提高。要有所突破,需借助计算数学最新进展,引入新的高效算法。多重网格法是近二十年迅速发展的一种求解微分方程近乎最优的新算法。本文首先简单介绍了多重网格法基本原理和运算格式,着重介绍了当前国内外多重网格法在地球物理正反演中的应用成果和发展现状。此外,对多重网格法在地球物理正反演中的应用前景及发展趋势进行了展望。     

中国现代漆画的发展历程

中国现代漆画走的是一条由"工艺"而为"绘画"的发展之路.本文回顾了中国现代漆画独立与发展的历程,把重要的展览及事件一一列出,旨在为中国漆画梳理出一条清晰的发展脉络.     

源于自然的服装设计

大自然是人类生活的基础,自然界中的各种事物为服装设计师提供了取之不竭的灵感来源。从设计的形式、风格、理念三个方面分析自然对服装设计的启示,并以此指导服装设计的实践活动。自然这个主题一直以不同的方式出现在各种形态的服饰文明中,对自然生活的渴望、对无拘无束人生的向往、对自然清晰的认识与创造、对科技客观的评价与把握、对精神空间的深层探寻、对古老文明的继承和反思等等都是我们设计服装的最初的理念。     

Tests and numerical simulation on curved blade of super-critical adjust stage

Tests and numerical simulations of super-critical adjust stage blade were carried out and the effect of bowed blade on flow characteristics and the secondary flow were analyzed. The simulation and test results show that the adjust stage blade with aft-loading and big front-edge radius has good flow characteristics by meridian shrink. The numerical studies were carried out with software of NUMECA in order to investigate the aerodynamic characteristics of adjust stage blades,which include prototype blade(tested blade) ,positive curved blade (15°) and negative curved blade(-15°) . The simulation results show that the positive curved blade forms a negative static pressure gradient in the lower region of the cascade along the blade height and a positive static pressure gradient in the upper region. This leads to the reduction of the streamwise vortices intensity and the aerodynamic load on both sides of the blade and the endwall. Therefore,the crosswise secondary flow losses of endwall can be decreased considerably.     

含砷废水砷铁分离的研究

以氢氧化钠作为沉淀剂,对含砷废水进行选择性沉淀研究,考察了pH值、搅拌速度、温度等因素对砷、铁分离效果的影响,确定了合适的工艺条件：温度25℃,pH=13.5,搅拌速度500 r/min.此工艺条件下铁的回收率达到99.9%以上,实现了砷、铁的有效分离.