Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

火焰原子吸收光谱法测定硅粉中的铜

介绍了用火焰原子吸收法测定工业硅粉中微量铜的具体方法和过程，同时也给出了最佳实验条件。实验中采用新的样品处理方法，得到了令人满意的结果。其中样品回收率为99．8％—104．0%，相对标准偏差为0．31％—0.38％。本方法在实际应用过程中，简单、快速、     

纳米稀土复合固体超强酸催化合成乙酸苄酯

采用共沉淀法制备了纳米稀土复合固体超强酸SO4^2-／ZrO2-2％Nd2O3催化剂，电镜分析表明，催化剂颗粒直径在25nm左右，比表面积测定：71．03m^2／g。酸强度-12．70〈Ho〈-11．99。并对合成乙酸苄酯的最佳反应条件进行了研究。研究表明：当苯甲醇与乙酸的物质的量比为1：2，反应时间为5h，反应温度为120℃，催化剂用量为6％苯甲醇的质量时，酯化率可达92．04％。研究发现，该催化剂可重复使用并可活化再生。     

钛酸铝材料性能及合成工艺

着重介绍了钛酸铝（Al2TiO3）陶瓷的结构、性能和合成工艺，并对今后发展趋势提出了基本观点。     

Preparation of micro-patterned surfaces of Si-N-O films and their influence on adhesion behavior of endothelial cells

Microgrooves were prepared on Si(100) surface by photolithography and wet etching.Subsequently,Si-N-O films were deposited on the microgrooves by unbalanced magnetron sputtering(UBMS) and micro-patterned surfaces of Si-N-O films were obtained.The size of the micropatterns was measured by surface profilometer.The chemical composition of Si-N-O films were characterized by X-ray photoelectron spectrometry(XPS) and the wettability of the micropatterned surfaces was evaluated by contact angle measurement.The beh...     

Dynamic equivalent method of interconnected power systems with consideration of motor loads

The existing equivalent methods usually only deal with static load models and neglect the dynamic characteristics of loads such as induction motors.This paper presents a dynamic equivalent method which considers motor dynamics.At first,the clustering criterion of motor loads is given.The motors with similar dynamic characteristics are classified into one group.Then,reduction of motors in the same group is carried out.Finally,parameters of the equivalent motor are calculated and the equivalent system is thus...     

一种高效的网格资源监测算法ACTC的改进算法

资源监控是网格计算的关键组成部分。资源监控算法既要保证网格系统中资源信息高保真度又要考虑资源信息在网络传输中的负担最低。ACTC算法就是为实现以上目的而被提出,但是算法中对资源信息更新量的动态门槛值(d_threshold)计算方式不合理,有可能导致算法演变成低级的单纯依靠时间敏感机制(TSM)来发送资源更新通知,并且算法中遗漏了一些极端情况的考虑。提出了新的d_threshold计算公式和限制条件,进行性能改进和完善,并对改进前后两算法进行实验对比。实验表明,改进后算法提高了资源信息准确性,并使监控系统     

Application of open-pit and underground mining technology for residual coal of end slopes

Given the conditions of residual coal from the boundary of a flat dipping open-pit mine,which uses strip areas mining and inner dumping with slope-covering,we propose an open-pit and underground integrated mining technology for residual coal of end slopes.In the proposal a conveyance road and ventilation conveyance near the slope are built,corresponding to the pit mining area and the surface coal mine dump,as well as an interval haulage tunnel and air-inlet tunnel.The outcome shows that such mining method may reduce the effect to slope stability from underground mining,it does not affect the dumping advance and has a high recovery rate of residual coal resources.The working face is timbered by single hydraulic props,transported by a scraper conveyor and supported by coal walls.This method of mining is one of layered top coal caving,with high resource recovery,low production cost where positive economic benefit can be realized.     

Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

An improvement to the simulation of phase-change heat-transfer during soil freezing and thawing

A new variable time step method, which is called the backwards calculating time step method, is presented in this paper. It allows numerical simulation of soil freezing and thawing while avoiding "phase change missing and overflowing". A sensitive heat capacity model is introduced through which the calculation errors are analyzed. Then the equation using the self-adjusted time step is presented and solved using finite differences. Through this equation, the time needed for a space cell to reach the phase change point temperature is calculated. Using this time allows the time step to be adjusted so that errors caused by "phase change missing and overflowing" are successfully eliminated. Above all, the obvious features of this method are an accelerated rate for adjusting the time step and simplifing the computations. An actual example proves that this method can accurately calculate the temperature fields during soil freezing and thawing. It is an improvement over traditional methods and can be widely used on com- plicated multi-dimensional phase change problems.