Assessing the efficiency of supply chain scheduling algorithms using data envelopment analysis

Where different supply chain planning algorithms are used, generally similar results may pose some challenges on the differentiating powers of evaluating different production schedules because of the increasing complexity of a supply chain network structure. For the comparison purpose, performance evaluation of different supply chain planning algorithms aims to use different supply chains models with different demands, capacities, and commonality through efficiency perspective by using a modified network rational data envelopment analysis (DEA) model. The proposed DEA model has the abilities: (1) to treat only undesirable outputs that exist without normal output, and the situation where input and output are both zero by introducing two new parameters to denote the maximum inventory and amount of delayed demands of a given node in a given time period; and (2) to evaluate the effect of the undesirable outputs/inputs on efficiency with assumption that they leave the system at the end of the current time period and re-enter the system at the beginning of the next time period. To prove the effectiveness of this DEA model, eighteen scenarios with different demands, capacities, and multiple periods are compared. In addition, this study tests the DEA model on a wafer testing/probing operation of a leading global semiconductor manufacturing and testing company in Taiwan by internal supply chain perspective. Results show that the DEA model proposed in this study can be used to assess the efficiency of a real-world operation with undesirable outputs/inputs, such as inventory and delayed demands.     

Ecological footprint of Taiwan: A discussion of its implications for urban and rural sustainable development

Ecological footprint is a vital index for measuring whether an area is developing in a sustainable manner. This study calculates and analyzes the ecological footprint of Taiwan from 1994 to 2007. The per capita ecological footprint of Taiwan was 5.09 global hectares in 1994, and increased to 5.52 global hectares in 2005 and 6.54 global hectares in 2007. Based on the 2007 figure an area 42 times the size of Taiwan is needed to sustain the consumption of Taiwan. Moreover, the per capita ecological deficit in Taiwan also worsened during this period, from 3.09 global hectares in 1994 to 3.71 global hectares in 1994 and 4.74 global hectares in 2007, indicating resource overshooting and placing further pressure on the Earth. The calculation of ecological efficiency reveals that the poorest performance occurred in 1997, while performance was improved in 2003.     

Evaluating the criteria for human resource for science and technology (HRST) based on an integrated fuzzy AHP and fuzzy DEMATEL approach

This study intends to use a combination of fuzzy Analytic Hierarchy Process (AHP) and fuzzy Decision-making Trial and Evaluation Laboratory (DEMATEL) method in human resource for science and technology (HRST). Specifically, this study first uses AHP to evaluate the weighting for each criterion and then use DEMATEL method to establish contextual relationships among those criteria. We find out Infrastructure might be more critical since it is a cause and will directly influence human resource for science and technology performance. For human resource for science and technology (HRST), improving Infrastructure might be a better choice for the long period of time. Moreover, Education, R&D Expenses and Immediate output are more important second-tier criteria than Value, Cooperation, Labor Market, Human Capital and Intermediate output. Therefore, the improvement should be started with Infrastructure, particularly on identification of the Education, R&D Expenses and Immediate output.     

Photoactive Earth‐Abundant Iron Pyrite Catalysts for Electrocatalytic Nitrogen Reduction Reaction

The generation of ammonia, hydrogen production, and nitrogen purification are considered as energy intensive processes accompanied with large amounts of CO₂ emission. An electrochemical method assisted by photoenergy is widely utilized for the chemical energy conversion. In this work, earth‐abundant iron pyrite (FeS₂) nanocrystals grown on carbon fiber paper (FeS₂/CFP) are found to be an electrochemical and photoactive catalyst for nitrogen reduction reaction under ambient temperature and pressure. The electrochemical results reveal that FeS₂/CFP achieves a high Faradaic efficiency (FE) of ≈14.14% and NH₃ yield rate of ≈0.096 µg min^?1 at ?0.6 V versus RHE electrode in 0.25 m LiClO₄. During the electrochemical catalytic reaction, the crystal structure of FeS₂/CFP remains in the cubic pyrite phase, as analyzed by in situ X‐ray diffraction measurements. With near‐infrared laser irradiation (808 nm), the NH₃ yield rate of the FeS₂/CFP catalyst can be slightly improved to 0.1 µg min^?1 with high FE of 14.57%. Furthermore, density functional theory calculations demonstrate that the N₂ molecule has strong chemical adsorption energy on the iron atom of FeS₂. Overall, iron pyrite‐based materials have proven to be a potential electrocatalyst with photoactive behavior for ammonia production in practical applications.     

Anodic potential on dual-chambered microbial fuel cell with sulphate reducing bacteria biofilm

Dual chamber microbial fuel cell reactors were inoculated with a mixed culture of sulfate-reducing bacteria with anode potential being the controlling parameter. A negative poised anode potential enhanced the performance of this fuel cell while a positive poised anode potential had adverse effects on cell performance. Negative anodic potential affects the biofilm characteristics, as evidenced by electrochemical analysis. Microbial community was changed accordingly.     

Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor

Defect engineering represents a significant approach for atomically thick 2D semiconductor material development to explore the unique material properties and functions. Doping-induced conversion of conductive polarity is particularly beneficial for optimizing the integration of layered electronics. Here, controllable doping behavior in palladium diselenide (PdSe₂) transistor is demonstrated by manipulating its adatom-vacancy groups. The underlying mechanisms, which originate from reversible adsorption/desorption of oxygen clusters near selenide vacancy defects, are investigated systematically via their dynamic charge transfer characteristics and scanning tunneling microscope analysis. The modulated doping effect allows the PdSe₂ transistor to emulate the essential characteristics of photo nociceptor on a device level, including firing signal threshold and sensitization. Interestingly, electrostatic gating, acting as a neuromodulator, can regulate the adaptive modes in nociceptor to improve its adaptability and perceptibility to handle different danger levels. An integrated artificial nociceptor array is also designed to execute unique image processing functions, which suggests a new perspective for extension of the promise of defect engineered 2D electronics in simplified sensory systems toward use in advanced humanoid robots and artificial visual sensors.     

Antioxidant activities of chicken liver hydrolysates by pepsin treatment

This study was divided into two parts: (i) an optimal hydrolysing procedure of chicken liver hydrolysates (CLHs) and (ii) the in vivo antioxidant properties of CLHs via a D‐galactose‐induced mouse model. A pepsin‐to‐raw chicken liver mass ratio (1:400, w:w) and 2‐h hydrolysing period were chosen to manufacture CLHs based on yield, peptide level and antioxidant effect. Molecular masses of CLHs were lower than 10 kDa. CLH was rich in aspartic acid and glutamic acid, and also contained both manganese and selenium, which are essential cofactors of superoxide dismutase and glutathione peroxidase, respectively. The contents of cadmium, mercury, tin, and arsenic in CLHs were very low and even no detectible. Regarding the in vivo antioxidant activity of CLHs, a dosage of 1.2 g D‐galactose kg^?1 body weight increased (P < 0.05) 2‐thiobarbituric acid reactive substances values and decreased (P < 0.05) glutathione and Trolox equivalent antioxidant capacity values, as well as superoxide dismutase, catalase, and glutathione peroxidase activities in serum and organs of mice. However, the in vivo antioxidant capacities were improved (P < 0.05) by supplementing CLHs.     

Epoxidation of Butadiene Over Nickel Modified TS-1 Catalyst

Abstract  

Nickel modified Titanium silicalite 1 (TS-1) catalysts provided an environmentally benign and effective method for butadiene epoxidation. Certain loading of modified Ni in our system significantly promoted TS-1 catalytic activity. The product vinyloxirane (VO) was obtained with high yield of 0.49 mol/L (theoretic equilibrium value 0.52 mol/L). The turnover number (TON, determined as the molar VO obtained per molar Ti atom) reached 1,140. Besides, the catalyst kept high activity during five runs of reusability test. XRD, N₂ adsorption and desorption, TPR, XPS, FT-IR and DR UV–Vis were employed to characterize the specific Ni role to Ti-site in Ni/TS-1 catalysts.     

HMM-based ball hitting event exploration system for broadcast baseball video

With the dramatic growth of fandom population, a considerable amount of research efforts have been devoted to baseball video processing. However, little work focuses on the detailed follow-ups of ball hitting events. This paper proposes a HMM-based ball hitting event exploration system for broadcast baseball video. Utilizing the strictly-defined layout of the baseball field, the proposed system first detects the game-specific spatial patterns in the field, such as the field lines, the bases, the pitch mound, etc. Then, the play region—the currently camera-focused region of the baseball field is identified for frame type classification. Since the temporal patterns of presenting the game progress follow a prototypical order, we consider the classified frame types as observation symbols and recognize ball hitting events using HMM. Experiments conducted on broadcast baseball video show encouraging results in frame type classification and ball hitting event recognition. Three practical applications, including highlight clip extraction by user-designated query, storyboard construction, and similar event retrieval, are introduced to address the applicability of our system.