云母填料尺寸效应对水在环氧涂层中扩散行为的影响

以3种不同尺寸（124μm、38μm和19μm）的片状云母粉为填料，应用质量法和电化学阻抗法（EIS）研究云母填料尺寸效应对水在环氧涂层中的扩散行为的影响。结果表明在几种涂层中，水的扩散总是分为两个阶段：扩散初期阶段和平衡扩散阶段。浸泡初期水在涂层中的扩散行为除了124μm云母环氧涂层基本符合理想菲克扩散行为外，38μm云母环氧涂层和19μm云母环氧涂层均符合理想的菲克扩散定律，即涂层的吸水与浸泡时间的1／2次方成正比。但是水在几种涂层中的扩散系数却各不相同，其中38μm云母环氧涂层的扩散系数最小。     

Preparations and properties of thermosensitive terpolymers of N‐isopropylacrylamide,sodium 2‐acrylamido‐2‐methyl‐propanesuphonate,and N‐tert‐butylacrylamide

Terpolymers based on N‐isopropylacrylamide, sodium 2‐acrylamido‐2‐methyl‐propanesulfonate, and N‐tert‐butylacrylamide were synthesized by free‐radical copolymerization with 2,2′‐azobisisobutyronitrile as an initiator. The lower critical solution temperatures (LCSTs) of the linear polymer aqueous solutions were determined by the measurement of the transmittance on UV at different temperatures. The influence of the polymer concentration, polymer composition, and ionic strength on the LCSTs of the linear polymers was investigated. The LCST decreased with increases in the hydrophobic monomer N‐tert‐butylacrylamide, polymer concentration, and ionic strength. The phase transition became sharp when the polymer concentration and ionic strength increased. Meanwhile, the crosslinked hydrogels were prepared with the same recipe used for the linear terpolymers, but a crosslinker was added to the reaction system. The swelling ratios of the hydrogels at various temperatures and salt solutions were determined. The hydrogels possessed both high swelling ratios and thermosensitivity. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

聚天冬氨酸的合成与表征

以L-天冬氨酸为原料,热缩合成聚天冬氨酸酐,水解得到聚天冬氨酸。采用凝胶色谱法(GPC)测定了聚天冬氨酸的分子量,并用核磁共振(NMR)对其进行了表征。     

基于双天线GNSS/SINS组合的风速测量运动补偿方案设计

以基于浮标平台的动态风速测量为背景,根据运动姿态补偿的原理和实际需要,设计了一套双天线GNSS/SINS组合姿态测量系统,采用卡尔曼滤波实现信息融合,通过在卡尔曼滤波的观测量中引入双天线GNSS输出的航向角信息,解决了惯性系统航向角可观测性较弱的问题,并通过实验验证了系统的有效性。实验结果表明,该运动补偿设计方案能够提高平台姿态测量的精度和稳定性,准确测量平台的姿态信息,并有效降低平台运动对风速测量的影响,风速测量误差低于4%,满足了海洋浮标观测的需求。     

核壳型乳液聚合研究进展

综述了近年来核/壳结构聚合物乳液的聚合工艺、性能及核/壳结构的表征方法进行,讨论了影响核/壳结构聚合物乳胶粒子形态的各种因素。     

含异氰脲酸酯基环氧树脂的合成

为了改善环氧树脂的耐热性与韧性 ,以三羟乙基异氰脲酸酯 (THEIC)为原料 ,与环氧氯丙烷 (ECH)合成了氯化聚醚多元醇 (CPP) ,CPP与氢氧化钠反应制备了一种新型的含异氰脲酸酯基和醚键的液体环氧树脂 (EP) ,并通过IR确定了结构。CPP与氢氧化钠的摩尔比为 1∶3.2 5,在 2 50ml乙醇 ( 0 .1molCPP)中 ,室温反应 3h ,产率 87.7% ,环氧值 0 .36 87。     

丙交酯的合成

以DL－乳酸为原料在催化剂存在下，加热、减压脱水合成了DL－丙交酯，研究了温度、压力、反应时间等反应条件对丙交酯产率的影响，用IR等分析测试仪器对丙交酯进行了表征。     

有机玻璃的增韧研究

研究了不同聚合方法制备的聚丙烯酸丁酯（PBA）对浇铸型有机玻璃（PMMA）的增韧改性，研究结果表明，当PBA以纳米粒子簇分散在PMMA基体中时，对PMMA有较好的增韧改性效果。当PMMA中无皂乳液聚合PBA（e-PBA)的质量分数为0.5%时。改性PMMA的冲击强度比基体提高38%。SEM观察表明，本体聚合PBA（b-PBA)橡胶粒子以独特的纳米簇状结构均匀分布在PMMA基体中，大量的微裂纹以b-PBA粒子为中心呈放射状向外辐射，这些微裂纹在试样破坏的过程中吸收了大量的冲击能，使改性PMMA韧性得以提高。     

注塑模微机CAD系统

本文介绍了一个微机上运行的注塑模ＣＡＤ系统，此系统主要解决了四个难点，浇注系统设计，冷却系统分析，型腔，型芯的曲面造型设计，装配图和零件工作图的设计绘制，经厂家实际运用证明，该系统使用方便，结果正确，能提高设计效率，降低生产成本。     

Development of polarization ratio model for sea surface wind field retrieval from TerraSAR-X HH polarization data

In this article, the polarization ratio (PR) of TerraSAR-X (TS-X) vertical–vertical (VV) and horizontal–horizontal (HH) polarization data acquired over the ocean is investigated. Similar to the PR of C-band synthetic aperture radar (SAR), the PR of X-band SAR data also shows significant dependence on incidence angle. The normalized radar cross-section (NRCS) in VV polarization data is generally larger than that in HH polarization for incidence angles above 23°. Based on the analysis, two PR models proposed for C-band SAR were retuned using TS-X dual-polarization data. A new PR model, called X-PR hereafter, is proposed as well to convert the NRCS of TS-X in HH polarization to that in VV polarization. By using the developed geophysical model functions of XMOD1 and XMOD2 and the tuned PR models, the sea surface field is retrieved from the TS-X data in HH polarization. The comparisons with in situ buoy measurements show that the combination of XMOD2 and X-PR models yields a good retrieval with a root mean square error (RMSE) of 2.03 m s^–1 and scatter index (SI) of 22.4%. A further comparison with a high-resolution analysis wind model in the North Sea is also presented, which shows better agreement with RMSE of 1.76 m s^–1 and SI of 20.3%. We also find that the difference between the fitting of the X-PR model and the PR derived from TS-X dual-polarization data is close to a constant. By adding the constant to the X-PR model, the accuracy of HH polarization sea surface wind speed is further improved with the bias reduced by 0.3 m s^–1. A case acquired at the offshore wind farm in the East China Sea further demonstrates that the improvement tends to be more effective for incidence angles above 40°.