Field trial of cyfluthrin as an effective and safe insecticide for control of malaria vectors in triple insecticide resistant areas

Cyfluthrin (Solfac**) 10 wp, a synthetic pyrethroid was evaluated for its efficacy in malaria control through primary health centre approach, and for its acceptance by the community and effect on human health, and non target organisms, in predominantly tribal areas of Maharashtra and Gujarat from 1988 to 1990. Two dosage schedules; 2 rounds of indoor residual sparying a year, at 25 mg/sq. m2 in Maharashtra, and 3 rounds a year at 15 mg/sq. m2, in Gujarat were followed. There was significant reduction in per man hour densities of An. culicifacies the principal malaria vector, and collaterally of C. quinquefasciatus also. Significant reductions in slide positivity rates and slide falciparum rates were observed in both the areas as compared to the controls. The community acceptance of Cyfluthrin in terms of room coverage was 96% in Gujarat, and 89% in Maharashtra, as against average 68.5% and 55% in case of DDT and Malathion respectively. There were no reported ill-effects on humans or non-target organisms.     

Anodic polarization of HgTe,CdTe and Hg0.8Cd0.2Te — Oxide formation kinetics and composition

A comparative study of the anodic polarization behaviour of HgTe, CdTe and Hg_0.8Cd_0.2Te at constant current density was undertaken. It is argued that metal dissolution starts first, which renders the semiconductor surface negatively charged and tellurium rich. The process continues until the overpotential across the interface rises sufficiently to dissociate the tellurium at which point tellurium dissolution and oxidation begins. The continuation of this process evidently requires that the metal dissolution follows. This dissolution-precipitation mechanism for oxide nucleation is supported here. It is predicted that the molar ratio of HgTeO₃ to CdTeO₃ in the anodic oxide on Hg_0.8Cd_0.2Te should be 1.1. This is in good agreement with the experiments. The overvoltages required to initiate oxidation are shown to decrease when the current density is increased.     

Time-dependent structural modifications in tin oxide thin films under environmental conditions

Time-dependent crystalline structure and surface morphology of transparent conducting thin films of undoped tin oxide have been studied under environmental conditions by X-ray diffractometry and scanning electron microscopy. Tin oxide thin films were produced, via chemical vapour deposition, in three batches; two batches with single deposition at substrate temperatures of 400 C and 560 C, respectively, and the third batch produced by double deposition firstly at 560 C and then at 400 C substrate temperature. It is found that the crystallinity of the as-grown tin oxide thin films produced by single deposition degrades with shelf-life period and an amorphous phase is developed under environmental conditions. In the tin oxide films produced by double deposition there was no degradation in the crystallinity of the films, but a change in the preferential crystallite orientation was observed. The implications are discussed.     

Machining of a hybrid–metal matrix composite using an erosion–abrasion-based compound wheel in electrical discharge grinding

Machining of the composites made of matrix and reinforcement is always difficult for manufacturing industries due to their unusual properties. Among various existing traditional and non-traditional machining processes, erosion-based machining process i.e., Electrical Discharge Grinding (EDG) and the abrasion-based process i.e., Diamond Grinding (DG) have been shown their potential to machine such difficult-to-machine materials. The aims of the present study are to analyze the performances of the erosion–abrasion-based compound wheel during machining of the hybrid–metal matrix composite made of Aluminum–Silicon Carbide–Boron Carbide (Al/SiC/B₄C) by the stir casting method. The performances of the compound wheel have been tested on the EDM machine in the face grinding mode. The role of pulse current, pulse on-time, pulse off-time, wheel RPM, and abrasive grit number have been analyzed on the material removal rate (MRR) and average surface roughness (Ra). The experimental results showed that the machining with compound wheel gives higher MRR with better surface finish as compared to the uniform wheel. It has also been observed that MRR and Ra are highly affected by the pulse current, pulse on-time, and wheel RPM.     

Electrical properties of iron (III) molybdate

Electrical transport properties, i.e. a.c. and d.c. electrical conductivities, thermoelectric power and dielectric constant, of Fe₂(MoO₄)₃ have been measured in the temperature range 300 to 1000 K on pressed pellets of a polycrystalline sample, using the two electrode method. Iron (III) molybdate has been found to be a p-type semiconductor with an energy gap of 3.1 eV. Intrinsic conduction occurs at 750 K and the activation energies below and above 750 K are 0.51 and 1.55 eV, respectively. The thermoelectric power increases up to 750 K and after that it decreases with increasing temperature. The dielectric constant increases with temperature over the entire temperature range measured except 650 to 750 K, where it has a constant value.[/p]     

TEMPERATURE DISTRIBUTION DURING ELECTRO-DISCHARGE ABRASIVE GRINDING

The objective of this work is to develop a finite element method (FEM) based mathematical model to simulate the hybrid machining process of grinding and electric discharge machining (EDM), named as Electro-discharge abrasive grinding (EDAG), for temperature distribution in the workpiece. Two different finite element codes have been developed to calculate the temperature distribution due to grinding heat source and EDM heat source separately. The transient temperature field within workpiece due to cut-off grinding is determined due to moving rectangular heat source. Gaussian heat distribution of power within a spark has been considered in the calculation of temperature distribution due to EDM. Temperature distribution in the workpiece due to combined process is obtained by using superposition. The simulation shows a sudden rise in temperature at the spark location. The predicted results can be used for calculation of thermal stresses, which play a major role as far as high-quality product requirements are concerned.     

Robust parameter design and multi-objective optimization of laser beam cutting for aluminium alloy sheet

The application of laser beam for precise cutting of sheet metals, in general, and reflective sheet metals, like aluminium, in particular, has become of interest in the recent past. The optimum choice of the cutting parameters is essential for the economic and efficient cutting of difficult to cut materials with laser beams. In this paper, a robust design and quality optimization tool called the Taguchi methodology has been applied to find the optimal cutting parameters for cutting of a reflective sheet made of aluminium alloy with a Nd:YAG laser beam. All the steps of the Taguchi method, such as a selection of orthogonal array, computation of signal-to-noise ratio, decision of optimum setting of parameters, and the analysis of variance (ANOVA), have been done by a self-developed software called computer aided robust parameter design (CARPD). A considerable improvement in the kerf taper (KT) and material removal rate (MRR) has been found by using Taguchi method-based predicted results. Confirmatory experimental results have shown good agreement with predicted results. Further, the Taguchi quality loss function has also been used for multi-objective optimization of laser beam cutting of Al-alloy sheet. The results of multi-objective optimization are compared with the single-objective optimization and it has been found that the kerf taper was increased by 1.60% in multi-objective optimization while the MRR was same in both cases.     

Variable refractive index optical coatings

The discrete and restricted values of refractive index of the bulk optical materials at present available are a serious limitation on the usefulness of these materials for optical coatings. This limitation can be overcome by utilizing the atom-by-atom condensation feature of the growth of vapour-deposited thin films, which allows the homogeneous mixing of different materials irrespective of their solubility restrictions. We have used this feature of co-deposition of different materials to form mixed optical materials of variable refractive index, the variation being determined by the composition of the source material. Measurements of the optical constants of these films, prepared by co-evaporation of mixtures of ZnS and MgF₂ of various compositions, have been made. The refractive index of the mixed films is found to be in good agreement with the values predicted on the basis of the Lorentz-Lorentz theory. In addition, the optical equivalence of alternate layers of ZnS and MgF₂ with step thicknesses ranging from 5 to 250 Å has been studied. For step thicknesses less than 100 Å, the optical properties of the composite films are equivalent to those for the homogeneously mixed films. For larger step thicknesses, considerable and complicated interference effects are observed. Thus, variable refractive index composite films can be prepared by (a) co-deposition and (b) deposition of alternate discrete layers of different materials as long as the step thickness does not exceed about 100 Å. Furthermore, these techniques of obtaining optical films of mixed materials can be extended to any combination of materials and therefore they open up a new field in materials technology.     

Microstructure-mechanical property relationship to copper alloys with shape memory during thermomechanical treatments

The phase transformations during fabrication and aging after cold deformation in three polychrystalline copper alloys of the Cu-Al-Ni system with shape memory effect (SME) were characterized. Some phase transformations were identified with clear repercussion in their mechanical properties during thermomechanical treatments. Around 430 °C, mutual effects of β-phase recrystallization and precipitation of γ₂ and NiAl phases were observed. Close to 600 °C the dissolution of phase α was observed, beginning transformation into β phase process. Brittle phases such as γ₂ and NiAl began to precipitate during a short exposure time at 380 °C, 585 °C, 600 °C, and 700 °C temperatures. The phase transformations were intensified due to the plastic deformation that acted as a driving force for the diffusion processes. The introduction of chemical elements inhibited the grain growth and increased the structural disorder generating an elevation in the hardness property.