Facile regeneration vitreous microfibrous entrapped supported ZnO sorbent with high contacting efficiency for bulk H2S removal from reformate streams in fuel cell applications

In this study, a microfibrous carrier consisting of 3 vol.% of 8 μm (diameter) glass fibers is used to entrap 45 vol.% of 150 to 250 μm (diameter) SiO₂ support particulates. ZnO is then nanodispersed onto the support by impregnation at the loading of 17 wt.%. At equivalent bed volumes, ZnO/SiO₂-entrapped materials provide twofold longer breakthrough times for H₂S (with a 67% reduction in sorbent loading) compared with packed beds of 1 to 2 mm commercial extrudates. Five-log reductions in H₂S concentration with up to 75% ZnO utilization at breakthrough are achieved. H₂S concentrations from 60 to 2000 parts per million in volume (ppmv) can be reduced to as little as 0.6 ppmv at 400°C in 30% H₂O at a face velocity of 1.7 cm/s for layers as thin as 1.0 mm. At 500 to 600°C, ZnO/SiO₂-entrapped materials provide much higher regenerability in air than do 1 to 2 mm commercial extrudates. The use of glass fibers permits greater than 50 regeneration cycles. This paper was presented at the ASM Materials Solutions Conference & Show held October 18–21, 2004 in Columbus, OH.     

加工TiNi形状记忆丝的新工艺

采用模拟试样研究了Ti/TiAl、Nb/TiAl和NbTi/TiAl 3种复合材料的界面特性。结果表明,爆炸试样的界面反应层厚度远小于热等静压试样的界面反应层厚度。在同一条件下热等静压成型的这3种复合材料,其界面差异明显:Ti/TiAl和NbTi/TiAl试样的界面反应层较厚,界面结合强度较高;Nb/TiAl试样的界面反应层较薄,界面结合强度较低。     

Evolution of {001 } （110） orientation and related lattice rotation of A1 alloy 6111 during rolling

The texture evolution and lattice rotation in A1 alloy 6111 with an initial {001} （110）component during symmetrical and asymmetrical roiling were investigated by means of orientation distribution function（ODF）. The results show that the as-rolled initial {001 } （110） orientation evolves into not only the copper orientation but also all the other orientations along the β fiber, including the brass orientation, by lattice rotation around special directions. Compared with the symmetrical rolling, the {001 } （110）component in the surface layer on the slower roller side evolves more quickly into the orientations along the β fiber during asymmetrical rolling, while that in the surface layer on the faster roller side evolves more slowly.     

The effect of casting temperature on the properties of squeeze cast aluminium and zinc alloys

Gravity casting and squeeze casting were carried out on an aluminium alloy with 13.5% silicon and a zinc alloy with 4.6% aluminium with different temperatures, 660, 690 and 720 °C for the former and 440, 460 and 480 °C for the latter. A top-loading crucible furnace was used to melt the alloys. The die-preheat temperatures used were 200–220 °C for the aluminium alloy and 150–165 °C for the zinc alloy. A K-type thermocouples with digital indicator were used to measure the die surface temperature and the molten metal temperature; while a 25 t hydraulic press with a die-set containing a steel mould was used to perform the squeeze casting with a pressure of 62 MPa. Tensile, impact and density tests were carried out on the specimens. It was found that casting temperature had an effect on the mechanical properties of both gravity cast and squeeze cast aluminium and zinc alloys. The best temperatures to gravity cast the aluminium alloy and the zinc alloy were 720 and 460 °C, respectively. For the squeeze casting of the aluminium alloy, the best temperature to use was either 690 or 660 °C; the former would give a better property at the top of the casting while the latter, at the bottom of the casting. However, for the squeeze casting of the zinc alloy, the best temperature was again 460 °C.     

捷克锻造技术的发展概况

本文介绍捷克在锻压技术方面的发展情况,主要叙述科研机构与研究开发的业务范围、生产厂家与生产的主要设备以及今后的发展目标。     

三维强化抛光振动台的试验模态分析与有限元分析

对三维强化抛光振动台的初始结构模型进行试验模态分析，获得了各阶模态参数，分析其结构动力特性，并与有限元模态分析结果进行对比，验证了有限元模型的正确性。进而为实现结构的优化设计提供依据。     

HA—微孔钛基涂层种植体的复合强度

研究了羟基磷灰石(HA)和中性玻璃(G)的混合涂料在TC4多孔钛基体上的界面复合强度。探讨了中性玻璃含量、基体表面状态以及烧结工艺对这种涂层复合种植体的复合强度的影响。指出:复合的实质是中性玻璃与基体的润湿结合,最合适的玻璃含量为50 wt%,提高复合强度的关键,在于基体表面的TiN蒸镀处理,当TiN厚度为2～3 μm时,复合强度可达7.2 MPa。最佳烧结工艺为:900～950℃/30 min。     

激光快速成形Ti-6Al-4V合金力学性能

采用实验研究的方法，对激光快速成形Ti-6Al-4V合金的力学性能进行了探讨。结果发现：和锻造件相比，激光快速成形沉积态Ti-6Al-4V合金的拉伸性能具有高强低塑特点和更显著的各向异性；成形试样的组织、氧含量和冶金缺陷都将影响到拉伸性能，其中组织的影响最显著，其次为氧含量和熔合不良缺陷：对于氧含量符合GJBGJB2921-1997标准的激光快速成形Ti-6Al-4V合金，经固溶时效热处理后所获得的网篮组织综合性能最好，不论是强度指标还是塑性指标都高于锻件标准。     

连接温度、压力和保温时间对Ti3SiC2／Ni扩散连接接头性能的影响

利用Gleeble 3500热模拟实验机，在800～1100℃、10～90min和6-20MPa条件下对Ti3SiC2和Ni进行真空扩散连接。通过正交实验，研究了连接温度、连接压力和高温保温时间对试样连接强度的影响，优选出最佳工艺参数。结果表明，扩散连接工艺参数显著影响Ti3SiC2／Ni接头的剪切强度。在1000℃、10min和20MPa实验条件下，获得的Ti3SiC2／Ni接头的剪切强度达到（121±7）MPa，接近Ti3SiC2陶瓷的剪切强度。     

Microstructure and Application of YBCO Superconductive Films with Low Surface Resistance

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