Ultra Low Background Cryogenic Test Facility for Far-Infrared Radiation Detectors

The next generation of far infrared radiation detectors is aimed to reach photon noise limited performance in space based observatories such as SPICA and BLISS. These detectors operate at loading powers of the astronomical signal of a few Attowatt (10^?18 W) or less, corresponding to a sensitivity expressed in noise equivalent power as low as $\mathrm{NEP} = 2\times10^{-20}\ \mbox{W}/\sqrt{\mathrm{Hz}}$ . We have developed a cryogenic test setup for microwave Kinetic Inductance Detectors (MKIDs) that aims to reach these ultra-low background levels. Stray light is stopped by using a box in a box design with a sample holder inside another closed box. Microwave signals for the MKID readout enters the outer box through custom made coax cable filters. The stray light loading per pixel is estimated to be less than 60×10^?18 W during nominal operation, a number limited by the intrinsic sensitivity of the MKIDs used to validate the system.     

A study of stabilization of P3HT/PCBM organic solar cells by photochemical active TiOx layer

We describe a study of the stabilization behavior of P3HT/PCBM organic solar cells under air and UV irradiation using a 20 nm thin TiO_x protection layer made by partial hydrolysis of a Ti-alkoxide and spin coating in air. Data on the degradation of solar cell performance under air and under UV exposure are presented indicating that significant improvements are observed with TiO_x layer protection. The protection mechanism has been investigated by transmission IR and UV spectroscopy and by ESR spectroscopy. The results of this study suggest how sol-gel derived TiO_x films containing organic functionalities serve as effective passivation films for protection from oxygen when excited by photons, where the photooxidation of the bound organic moieties causes oxygen gas scavenging.     

Preference Mapping of Fresh Tomatoes Across 3 Stages of Consumption

Tomatoes (Solanum lycoperiscum) are a popular produce choice and provide many bioactive compounds. Consumer choice of tomatoes is influenced by flavor and visual appearance and external texture cues including hand firmness and sliceability. The objective of this study was to determine drivers of liking for fresh tomatoes across 3 stages of consumption. Seven tomato cultivars were ripened to a 6 on the USDA color chart. Trained panelists documented appearance, flavor, and texture attributes of tomatoes in triplicate. Tomato consumers (n = 177) were provided with knives and cutting boards and evaluated tomatoes across 3 stages: appearance (stage 1), slicing (stage 2), and consumption (stage 3). Consumers evaluated overall liking at each stage. Analysis of variance and external preference mapping were conducted. Overall liking was highest during the appearance portion of the test and lowest during the consumption portion (P < 0.05). Drivers of liking at stage 1 were color intensity, even outside color, and overall aroma. Drivers of liking at stage 2 were wetness/juiciness and overall aroma. Wetness/juiciness, seed presence, ripe flavor, and sweet and umami tastes were drivers of liking for tomatoes at consumption (stage 3). Four separate clusters of tomato consumers were identified. Cluster 1 preferred tomatoes with even color, higher color intensity, and flavor intensity. Cluster 2 preferred firm tomatoes. Cluster 3 preferred tomatoes that were soft and at peak ripeness; this cluster also had the highest liking scores for all tomatoes. Cluster 4 consumers generally consumed tomatoes in sandwiches rather than as‐is and preferred tomatoes with even and intense color. Tomato growers can utilize these results to target cultivars that are well liked by consumers.     

Adenoviruses and Ultraviolet Light: An Introduction

Adenoviruses have been shown to be highly resistant to inactivation by ultraviolet (UV) light. While a dose of 40 mJ/cm² is generally considered sufficient to effect at least a 4-log (99.99%) inactivation of most waterborne pathogens (e.g., hepatitis A virus, Salmonella, Cryptosporidium), recent studies have indicated that doses of 120 mJ/cm², and possibly up to 200 mJ/cm² are required to achieve the same level of inactivation of adenoviruses. In order to ensure a high degree of public health protection, the USEPA adopted a UV dose table value of 186 mJ/cm² for 4-log inactivation credit in the Long-Term 2 Enhanced Surface Water Treatment Rule. This may have a significant effect on the number of systems that are able to utilize UV as the disinfectant, due to the higher costs associated with providing the increased UV dosage. This presentation will provide an introduction to the adenoviruses, including their health effects, routes of transmission, and potential for contamination of water.     

Synthesis of p-cymene from limonene, a renewable feedstock

Highly selective limonene conversions to p-cymene in short reaction times were achieved under “solvent free” conditions over mesoporous silica–alumina supports heated by microwave irradiation. An increase in the silica content of these mixed oxides led to increases in the specific surface area, porosity (pore size and volume) and the surface acidity. The conversion and selectivity of limonene to p-cymene under microwave irradiation was also found to rise as the silica content in these mixed oxides was increased. By careful choice of the solid and reaction parameters the activities for the conversion of limonene and selectivity to p-cymene (used as an intermediate in fine chemical syntheses) could be fine tuned. Results are presented under both dry media and reflux conditions.     

Uncertainty in macroeconomic policy-making: art or science?

Uncertainty is pervasive in economic policy-making. Modern economies share similarities with other complex systems in their unpredictability. But economic systems also differ from those in the natural sciences because outcomes are affected by the state of beliefs of the systems' participants. The dynamics of beliefs and how they interact with economic outcomes can be rich and unpredictable. This paper relates these ideas to the recent crisis, which has reminded us that we need a financial system that is resilient in the face of the unpredictable and extreme. It also highlights how such uncertainty puts a premium on sound communication strategies by policy-makers. This creates challenges in informing others about the uncertainties in the economy, and how policy is set in the face of those uncertainties. We show how the Bank of England tries to deal with some of these challenges in its communications about monetary policy.     

Psychometric properties of the Hawaiian Culture Scale—Adolescent Version.

This article reports on the psychometric properties of a newly constructed Hawaiian Culture Scale—Adolescent Version. A total of 2,272 Native Hawaiian and 1,170 non-Hawaiian adolescents were administered this 50-item inventory that measures the source of learning the Hawaiian way of life, how much Hawaiian beliefs are valued and important to maintain, how much non-Hawaiian beliefs are valued, Hawaiian blood quantum, and specific cultural traditions (seven subscales?=?Lifestyles, Customs, Activities, Folklore, Causes—Locations, Causes—Access, and Language Proficiency). The results strongly supported the internal consistency and validity of the measures for both the Hawaiian and non-Hawaiian groups. On the basis of the demographic data, partial support was offered for cross-cultural theories of ethnic identity. More consistent support was found for multiculturalism in Hawai'i's adolescents. Further research is needed to link these measures with indicators of psychological adjustment (e.g., depression, anxiety, substance use). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Power control for an asynchronous multirate decorrelator

For code-division multiple-access (CDMA) wireless systems employing multiuser detection, the varied bit-error rate (BER) requirements of multimedia traffic dictate the use of transmitted power control. Using a decorrelator in an asynchronous multirate direct-sequence CDMA system, it may be necessary for different users to combat the noise enhancement and the propagation losses to varying degrees depending on individual requirements. In this context, we propose a power control algorithm for a multirate decorrelator that is suitable for a class of BER-based link quality objectives. If the uplink channel gain of the desired user is known, then it is straightforward for each user to choose the transmitted power needed to meet its target BER objective. In practice, however, the uplink channel gain is often difficult to measure. To avoid this measurement, we employ stochastic approximation methods to develop a simple iterative power control algorithm. In this algorithm, each mobile uses the output of its own decorrelator to update its transmitted power in order to achieve its BER objective. We show that when a user's bits have nonzero asymptotic efficiencies, the power control algorithm converges quickly in the mean square sense to the minimum power at which a user achieves its quality-of-service objective     

An asynchronous multirate decorrelator

This paper examines truncated window decorrelators for an asynchronous direct-sequence code-division multiple-access system supporting users transmitting at different bit rates. We decode a user by extending the observation window over a sufficient number of its bits. To characterize practical window sizes, simple upper and lower bounds for the asymptotic efficiency of both the truncated window and infinite window decorrelators are developed. Empirical results show that as the length of the observation window increases, the bounds converge rapidly to the asymptotic efficiency of the infinite window decorrelator. The complexity of the receiver depends strongly on the ratio of the maximum to minimum bit rates     

Pillared clay and zirconia-based monolithic catalysts for selective catalytic reduction of nitric oxide by methane

New monolithic catalysts based on zirconia and pillared clays (PILC) have been studied for NO_x removal by CH₄ in the presence of oxygen. A comparative study of the influence of ZrO₂ from various commercial sources for the system Pd–ZrO₂ and the effect of the noble metal chosen for the system NM–PILC was carried out, trying to correlate the catalytic activity with the physico-chemical properties of these catalysts. The obtained results indicate that structure and surface acidity of the support plays an important role on the selectivity to NO_x reduction, although properties such as the surface area or pore volume could also determine the overall activity of the monolithic catalysts.