A Modified Method for the Determination of N‐Nitrosodiethanolamine in Coconut Diethanolamide Using HPLC with Dual‐Wavelength UV–Vis Detector

A simple and novel method based on high‐performance liquid chromatography with dual‐wavelength ultraviolet detection at 234 and 254 nm has been developed for the determination of underivatized N‐nitrosodiethanolamine in coconut diethanolamide. The correlation coefficient obtained shows that the method is correct.     

Estimation of the activation of local reactor shielding concretes

Many elements in reactor shielding concrete become radioactive due to interaction with neutrons during the operation of a nuclear reactor. These radioactive elements will build up over the time due to (n,γ) reaction and contribute to the radioactive waste during decommissioning of the reactor, they will increase the dose from the inner part of the biological shielding (concrete) surrounding a nuclear reactor during maintenance works within reactor containment, and their effect should be taken in the calculations of the dose behind the concrete shield.Six mixtures of local ordinary and special shielding concretes have been investigated in this study. Their compositions were determined using X-ray diffraction and neutron activation analysis using the Syrian Miniature Neutron Source Reactor (MNSR) and consequently the dose rates.Based on the results of the analyses and comparing to the published limits in the references, it has been found that ⁶⁰Co, ¹⁵²Eu, ¹⁵⁴Eu and ¹³⁴Cs will be the most effective radioactive nuclides existing in the local concrete, but Dolomite aggregates contain the minimum limits of them and it has been found that Fe, Mg, and Ti the major elements existing in the local concrete.     

Lumped Parameter Thermal Model for Axial Flux Switched Reluctance Motors

The accurate prediction of temperature rise in various parts of a machine plays a significant role in ensuring that the machine delivers the required performance avoiding failures that arise due to high temperatures. In this paper, a lumped parameter thermal model is presented for exterior-rotor axial flux switched reluctance motors. Depending on its geometry, each part of the motor is modeled as a thermal equivalent circuit based on general cylindrical or cuboidal components. A total thermal network is obtained by proper connection of these sub-circuits. The model was calibrated by a stationary test; then, running conditions were applied to the model. The sensitivity of the model to the heat transfer coefficients was investigated by considering the effect of the coefficient variation on the estimated steady-state temperatures. Results show that the winding temperature, as the hottest part of the motor, is the most sensitive to the frame-to-ambient heat transfer coefficients.     

Large particle effects in chemical/biochemical heap leach processes - A review

The application of heap leach technology to recovery of economically important metals, notably copper, gold, silver, and uranium, is wide-spread in the mining industry. Unique to heap leaching is the relatively coarse particle size, typically 12-25 mm top size for crushed and agglomerated ores and larger for run-of-mine dump leaching operations. Leaching from such large particles is commonly assumed to follow shrinking core type behaviour, although little evidence for the validity of this assumption exists. This review investigates the current state of knowledge with respect to the understanding of the characteristics and mineralogy of large particles and how these influence leaching in a heap context and the tools to characterize these. This includes the study of ore and particle properties, visualization techniques for ore characterization, the connection between comminution and leaching behaviour, as well as particle models within heap leach modelling. We contend that the economics of heap leaching are strongly governed by the trade-off between the slow rate and limited extent of leaching from large particles and the cost of crushing finer. A sound understanding of the underlying large particle effects will therefore greatly inform future technology choices in the area of heap leaching.     

Making concrete with saline well-water

Permitted limits of salt concentrations in water used for making mortar and plain concrete differ from one country to another, but in any event geographical conditions prevent this guidance being applied directly to Saudi Arabia. Comparing the effects on compressive strength of saline well-water and drinking quality water, scientists at the Department of Building Research in the Saudi Arabian Standards Organisation show in this article that well-water with total dissolved salts (TDS) concentrations up to 4500 ppm can be suitable for mixing and curing mortars and plain concrete.     

Tea and coffee consumption in relation to vitamin D and calcium levels in Saudi adolescents

ABSTRACT: BACKGROUND: Coffee and tea consumption was hypothesized to interact with variants of vitamin D-receptor polymorphisms, but limited evidence exists. Here we determine for the first time whether increased coffee and tea consumption affects circulating levels of 25-hydroxyvitamin D in a cohort of Saudi adolescents. METHODS: A total of 330 randomly selected Saudi adolescents were included. Anthropometrics were recorded and fasting blood samples were analyzed for routine analysis of fasting glucose, lipid levels, calcium, albumin and phosphorous. Frequency of coffee and tea intake was noted. 25-hydroxyvitamin D levels were measured using enzyme-linked immunosorbent assays. RESULTS: Improved lipid profiles were observed in both boys and girls, as demonstrated by increased levels of HDL-cholesterol, even after controlling for age and BMI, among those consuming 9--12 cups of coffee/week. Vitamin D levels were significantly highest among those consuming 9--12 cups of tea/week in all subjects (p-value 0.009) independent of age, gender, BMI, physical activity and sun exposure. CONCLUSION: This study suggests a link between tea consumption and vitamin D levels in a cohort of Saudi adolescents, independent of age, BMI, gender, physical activity and sun exposure. These findings should be confirmed prospectively.     

Investigations of the Failure in Boilers Economizer Tubes Used in Power Plants

In this study, failure of a high pressure economizer tube of a boiler used in gas-Mazut combined cycle power plants was studied. Failure analysis of the tube was accomplished by taking into account visual inspection, thickness measurement, and hardness testing as well as microstructural observations using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and x-ray diffraction (XRD). Optical microscopy images indicate that there is no phase transformation during service, and ferrite-pearlite remained. The results of XRD also revealed Iron sulfate (FeSO₄) and Iron hydroxide sulfate (FeOH(SO₄)) phases formed on the steel surface. A considerable amount of Sulfur was also detected on the outer surface of the tube by EDS analysis. Dew-point corrosion was found to be the principal reason for the failure of the examined tube while it has been left out-of-service.     

Non-invasive monitoring of water content and textural changes in clay-rocks using spectral induced polarization: A laboratory investigation

Seven well-characterized clay-rocks have been taken from three test sites to perform spectral induced polarization (SIP) measurements during desiccation of these samples. These test sites include (1) the Tournemire site (IRSN) located in south of France, (2) The Bure test site (ANDRA) located in west of France, and (3) the Super-Sauze earthflow located in south western of France. We dried the samples at ambient temperature followed by heating between 65 °C and 105 °C. The quadrature conductivity, at very low-frequency, was able to discriminate between the loss of free water from the macropores and the loss of water in the micropores associated with textural changes. The calcite and quartz grain size distributions had a significant effect on the low-frequency spectrum. The inversion of our SIP data demonstrated that the generalized Cole–Cole model is an appropriate empirical and practical model for monitoring changes in water content of clay-rocks.     

Adaptive fuzzy semi‐decentralized control for a class of large‐scale nonlinear systems with unknown interconnections

In this paper, a general method is developed to generate a stable adaptive fuzzy semi‐decentralized control for a class of large‐scale interconnected nonlinear systems with unknown nonlinear subsystems and unknown nonlinear interconnections. In the developed control algorithms, fuzzy logic systems, using fuzzy basis functions (FBF), are employed to approximate the unknown subsystems and interconnection functions without imposing any constraints or assumptions about the interconnections. The proposed controller consists of primary and auxiliary parts, where both direct and indirect adaptive approaches for the primary control part are aiming to maintain the closed‐loop stability, whereas the auxiliary control part is designed to attenuate the fuzzy approximation errors. By using Lyapunov stability method, the proposed semi‐decentralized adaptive fuzzy control system is proved to be globally stable, with converging tracking errors to a desired performance. Simulation examples are presented to illustrate the effectiveness of the proposed controller. Copyright © 2006 John Wiley & Sons, Ltd.     

Putting labs online with Web services

This paper describes an online experiment system that is based on Web services designed to support interoperable, machine-to-machine interaction over a network, and can also integrate heterogeneous resources. A service-oriented architecture was devised for online experiment systems, enabled by Web service protocols, and a methodology for wrapping the operations of the instruments into Web services. Although these methods aren't suitable for time-critical missions or applications that need real-time control, they do work for controlling standard commercial instruments over low-speed or unreliable communication networks. Using this framework, an online experiment system for students can be created that incorporates a great variety of instruments and that users can access without installing special software.