全文获取类型
收费全文 | 42175篇 |
免费 | 541篇 |
国内免费 | 788篇 |
专业分类
电工技术 | 724篇 |
综合类 | 52篇 |
化学工业 | 6378篇 |
金属工艺 | 3094篇 |
机械仪表 | 1386篇 |
建筑科学 | 863篇 |
矿业工程 | 151篇 |
能源动力 | 1429篇 |
轻工业 | 2265篇 |
水利工程 | 356篇 |
石油天然气 | 1386篇 |
无线电 | 3976篇 |
一般工业技术 | 10665篇 |
冶金工业 | 7220篇 |
原子能技术 | 788篇 |
自动化技术 | 2771篇 |
出版年
2021年 | 340篇 |
2020年 | 276篇 |
2019年 | 373篇 |
2018年 | 665篇 |
2017年 | 657篇 |
2016年 | 743篇 |
2015年 | 539篇 |
2014年 | 807篇 |
2013年 | 2388篇 |
2012年 | 1405篇 |
2011年 | 1884篇 |
2010年 | 1489篇 |
2009年 | 1781篇 |
2008年 | 1624篇 |
2007年 | 1768篇 |
2006年 | 1400篇 |
2005年 | 1226篇 |
2004年 | 1178篇 |
2003年 | 1078篇 |
2002年 | 1066篇 |
2001年 | 1119篇 |
2000年 | 964篇 |
1999年 | 999篇 |
1998年 | 2117篇 |
1997年 | 1657篇 |
1996年 | 1440篇 |
1995年 | 983篇 |
1994年 | 757篇 |
1993年 | 774篇 |
1992年 | 597篇 |
1991年 | 572篇 |
1990年 | 524篇 |
1989年 | 485篇 |
1988年 | 369篇 |
1987年 | 402篇 |
1986年 | 364篇 |
1985年 | 381篇 |
1984年 | 305篇 |
1983年 | 300篇 |
1982年 | 301篇 |
1981年 | 296篇 |
1980年 | 349篇 |
1979年 | 341篇 |
1978年 | 294篇 |
1977年 | 415篇 |
1976年 | 629篇 |
1975年 | 308篇 |
1974年 | 292篇 |
1973年 | 311篇 |
1972年 | 272篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Two‐dimensional arrangements of molecules can show remarkable cooperative electronic effects. Such effects can serve to achieve direct electronic sensing of chemical and physical processes via electrostatic effects, i.e., without transfer of charge or matter between the locus of sensing and that of detection. 相似文献
32.
33.
34.
35.
Thin films on aluminum-tungsten alloys were prepared by co-deposition of pure aluminum and pure tungsten, each sputtered by an independently controlled magnetron source, on glass and sapphire substrates. Completely amorphous films were obtained in the Al80W20-Al67W33 composition range. Passivity and corrosion behavior of amorphous Al-W alloys were investigated in 1 M deaerated hydrochloric acid solution using polarization and impedance spectroscopy measurements and have been correlated with the properties of pure alloy components. Tungsten and sputter-deposited Al-W thin films are inherently passive materials while aluminum undergoes pitting corrosion in hydrochloric acid solution. The passive film formed at the OCP on each alloy possesses excellent electric and dielectric properties comparable to those of the isolating film on tungsten. The absolute impedance increases with increasing tungsten content in the alloy. According to electrochemical polarization measurements, alloying Al with W in solid solution significantly enhances the material's resistance to pitting corrosion by shifting the breakdown potential above 2000 mV (Al67W33) and lowering the corrosion rate at the OCP by more than two orders of magnitude. The most likely mechanism explaining the passivity of amorphous Al-W alloys, the Solute Vacancy Interaction Model (SVIM), involves the formation of complexes between highly oxidized solute atoms (W+6) and mobile cation vacancies, which restrict the transport of Cl− through the oxide film and inhibit its breakdown in hydrochloric acid solution. The role that film stress relaxation effects and microscopic defects in amorphous Al-W films, of the some composition, and deposited on various substrates play in their corrosion resistance is discussed. 相似文献
36.
37.
D. C. Peets R. Liang C. Stock W. J. L. Buyers Z. Tun L. Taillefer R. J. Birgeneau D. A. Bonn W. N. Hardy 《Journal of Superconductivity and Novel Magnetism》2002,15(6):531-534
We have grown cubic centimeter-size crystals of YBa2Cu3O x suitable for neutron studies, by a top-seeded melt-growth technique. Growth conditions were optimized with an eye toward maximizing phase purity. It was found that the addition of 2% Y2BaCuO5 and 0.5% Pt (by mass) were required to prevent melt loss and to obtain the highest crystallinity. A neutron diffraction study on a mosaic of six such crystals found that the final Y2BaCuO5 concentration was 5%, while other impurity phases comprised less than 1% by volume. The oxygen content was set to x = 6.5, the crystals were detwinned, and then carefully annealed to give the well-ordered ortho-II phase. The neutron study determined that 70% of the mosaic's volume was in the majority orthorhomic domain. The neutron (006) and (110) rocking curve widths were ~1° per crystal and ~2.2° for the mosaic, and the oxygen chain correlation lengths were >100 Å in the a- and b-directions and ~50 Å in the c-direction. 相似文献
38.
J.Z. ZhaoT.S. Chen 《International Journal of Heat and Mass Transfer》2002,45(11):2265-2276
The inertia effect on the onset of thermal instability in natural convection flow over heated horizontal and inclined flat plates embedded in fluid-saturated porous media is analyzed. The linear non-parallel flow model is employed in the instability analysis, which takes into account the streamwise variation as well as the transverse variation of the disturbance amplitude functions. The set of partial differential equations for the disturbance amplitude functions are converted to a system of homogeneous linear ordinary differential equations with homogeneous boundary conditions by the local non-similarity method. The resulting eigenvalue problem is then solved by an implicit finite-difference method. Representative neutral stability curves and critical Rayleigh numbers are presented. It has been found that as the angle of inclination relative to the horizontal increases, the surface heat transfer rate increases, whereas the flow becomes more stable to the vortex mode of instability. Also, as the inertia effect, expressed in terms of Forchheimer number, Fr, increases, the heat transfer rate decreases, but the flow becomes more stable. It is demonstrated that the non-parallel flow model predicts a more stable flow than the parallel flow model. 相似文献
39.
Y. G. Wang H. Q. Ye K. H. Kuo X. J. Feng S. Z. Long G. L. Lao 《Journal of Materials Science》1991,26(23):6325-6330
The microstructures of unhydrated calcium aluminosulphate Ca4Al6SO16 and Ca3SrAl6SO16 have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca3SrAl6SO16 and another phase, possibly Sr3Al2O6 existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced. 相似文献
40.
Triton polymers are commercial surfactants whose molecular weight distributions are conventionally determined by means of high-performance liquid chromatography (HPLC). However, in the case of the important octylphenol ethoxylates [p-C8H17-C6H4-O-(CH2CH2O)n-H], HPLC cannot resolve individual oligomers of high molecular weight Triton surfactants (e.g., greater than 2000 u or so; u = unified atomic mass unit). In this paper, we show that laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD/FT/ICR/MS) provides a simple and accurate measure of such Triton surfactant molecular weight distributions up to at least 3500 u, based on a single-shot laser pulse measurement of a few seconds duration. Comparison of LD/FT/ICR/MS and HPLC molecular weight distributions of low molecular weight surfactants shows that laser desorption/ionization produces minimal fragmentation and thus offers an accurate measure of the relative abundances of the neutral oligomers, without the need for prior chromatographic separation of the components. Moreover, for all Triton polymer molecular weight distributions (700-3000 u), LD/FT/ICR/MS provides much more highly resolved profiles of oligomer relative abundances. Finally, LD/FT/ICR/MS reveals the presence of poly(ethylene oxide) side products of the polymerization process, which are not observed by HPLC with conventional ultraviolet absorption detection. 相似文献