Electrochemical micromachining of nitinol by confined-etchant-layer technique

The confined etchant layer technique has been applied to fabricate complex three-dimensional microstructures on nitinol for the first time. HF and HNO₃ were locally and simultaneously electrogenerated at the mold surface to etch a nitinol workpiece. NaOH was used as an efficient scavenger to confine the etchant close to the mold. Cyclic voltammetry was employed to study the electrochemical behavior of a Pt electrode in the etching solution in order to choose an appropriate potential for etchant generation on the mold. The thickness of the confined etchant layer was estimated to be several micrometers by inspecting the deviation of the sizes of the etched spots from the sizes of those on the microelectrode. Thus, the composition of the electrolyte could be optimized for better etching precision. By optimizing the composition of the electrolyte, complex microstructures on a Pt-Ir mold bearing the logo “XMU” of Xiamen University were successfully fabricated on nitinol. The etched patterns were approximately negative copies of the mold, and the precision of duplication could easily reach the micrometer scale.     

Phase separation in polymer blends comprising copolymers: 6. Effect of molecular architecture of block copolymers

To study the effect of the molecular architecture of a copolymer on its miscibility with corresponding homopolymers a series of block copolymers of styrene and isoprene with diblock, triblock and four-arm star architectures have been prepared and the morphologies of the blends of the copolymers and polyisoprene with different molecular weights have been examined by electron microscopy. The results show that miscibility varies in the sequence diblock>triblock>four-arm star copolymers. This sequence is in the opposite direction to the variation of the architectural complexity of the block copolymers, i.e. the more complex is molecular architecture, the greater is conformation restriction in microdomain formation and the less is solubility of homopolymer in corresponding domains.     

CAN总线在细纱机控制系统中的应用

分析了CAN总线在细纱机控制系统中的可行性,介绍了基于ColdFire MCF52235的细纱机控制系统的构成和PLC编程,并给出了单锭CAN节点的软件设计方案。     

Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries

Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles.     

Preparation and characterization of GaN films grown on Ga-diffused Si （111） substrates

Hexagonal GaN films were prepared by nitriding Ga2O3 films with flowing ammonia. Ga2O3 films were deposited on Ga-diffused Si (111) substrates by radio frequency (r.f.) magnetron sputtering. This paper have investigated the change of structural properties of GaN films nitrided in NH3 atmosphere at the temperatures of 850, 900, and 950℃ for 15 min and nitrided at the temperature of 900℃ for 10, 15, and 20 rain, respectively. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) were used to analyze the structure, surface morphology and composition of synthesized samples. The results reveal that the as-grown films are polycrystalline GaN with hexagonal wurtzite structure and GaN films with the highest crystal quality can be obtained when nitrided at 900℃ for 15 min.     

钼磷系缓蚀阻垢剂SK-107的缓蚀、阻垢性能研究

通过大量缓蚀、阻垢实验,着重介绍了钼磷系缓蚀阻垢剂SK-107在高碱度水且局部漏氨的合成氨循环水系统中的缓蚀、阻垢性能。     

新型冷轧(拔)无缝钢管高分子润滑工艺研究

提出了冷轧(拔)无缝钢管高分子润滑工艺。研究了该工艺的PL膜各种特性。介绍了工业实验情况。实验证明,高分子润滑工艺完全满足冷轧(拔)钢管工艺要求,并具有操作简便、环境污染小等优点,完全可以代替传统的磷化-皂化润滑工艺。     

移动定位技术的现状与发展趋势

基于位置服务为人们的日常生活带来了极大的方便,同时也推动了移动定位技术行业的快速发展。针对移动定位技术发展状况,分析目前主流定位技术的优劣,并对取得的突破作简单的总结归纳。     

基于漏磁原理的钢丝绳探伤仪影响因素研究

介绍了钢丝绳探伤仪漏磁检测原理,并使用有限元分析方法分析了传感器零件的材料、钢丝绳的提离距离及断丝根数等对基于漏磁原理的钢丝绳探伤仪检测结果的影响。分析结果表明,提离距离、断丝根数等因素对探伤仪检测结果影响较大,断丝角度、深度等因素影响较小。