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51.
A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the Tm and Tc of microPCMs were in the range of 29.8–31.0oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006 相似文献
52.
活性炭单柱提取肌苷新技术研究 总被引:1,自引:0,他引:1
活性炭单柱提取肌苷新技术研究李永泉,张进,姚恕,郑莲英,俞峰(杭州大学生物系杭州310028)(浙江大学化工系杭州310027)关键词:肌苷,提取技术,活性炭单柱1前言目前,国内肌苷发酵后处理工艺落后,在分离提取工序中肌苷损失严重,收率一般只有50%... 相似文献
53.
1 IntroductionWiththerapiddevelopmentofInternetandmobilecommunications,theresearchonwirelessmobilenetworkshasbecomethenewhotspotinin formationtechnologyfield .Asweknow ,mobileterminals (mobilephone,forexample)arethetooltohelppeopletoaccessanyinformationtheyneedbyanymediaatanytimeandanywhere .However,itissometimesdifficultformobileterminalstoplaysucharolebecauseofthelimitationssuchaslimitedca pacity ,lowpower,andinconvenienceinoperating .So,peoplehopetofindanotherwaytoaccessnet workinformatio… 相似文献
54.
55.
High-k材料是指介电常数k高于SiO2的材料。使用high-k材料做栅绝缘层,是减小MOS器件栅绝缘层直接隧道击穿(DirectTunneling,DT)电流的有效方法。文章在二维器件模拟软件PISCES-II中添加了模拟以high-k材料为栅绝缘层的MOS器件模型,并对SiO2和high-k材料的MOS晶体管器件特性进行了模拟比较,成功地验证了所加high-k材料MOS器件模型的正确性。改进后的PISCES-II程序,可以方便地对以各种high-k材料为栅绝缘层的器件性能进行模拟。 相似文献
56.
此文为李桢教授在2004年11月时寄予本刊。我们在“干燥刊中刊”发表此文以纪念为中国干燥行业作出巨大贡献的李桢教授。下附李桢教授写给本刊编辑的亲笔信: 相似文献
57.
油气运移的条件和油气运移的特征决定了油气藏的形成与分布。沾化凹陷南斜坡不整合面、断层以及各层系储集砂体的空间配置构成复杂的立体网络通道,决定了油气的运移,控制了油气分布。以断层为垂向运移通道的油气藏常在断层带附近多层叠置;以连通砂体为主要运移通道的油气藏常形成于距烃源层较近或相邻的层位;以不整合面作为运移通道往往可使油气长距离运移形成各种地层油气藏。沾化凹陷南斜坡的油气藏都是油气经过两种或多种输导层阶梯式运移而形成的。砂体、断层和不整合面组成的输导系统的末端和边缘是油气运移的重要指向区。 相似文献
58.
大规模定制为生产带来了变革和影响。针对新的生产方式的要求,根据推动大规模定制的过程方法和技术来分析他们对于质量控制产生的影响和要求,给出了大规模定制条件下的质量控制系统的建议,并给出了一个简要的系统模型。 相似文献
59.
A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, Mn = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (Mn = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
60.
Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献