Sulfonation degree determination of polystyrene ionomers by using adiabatic bomb calorimeter

Sulfonation degree determination of sulfonated polystyrene and the corresponding ionomers are performed by adiabatic bomb calorimeter. The theoretical calculations from the band energies for the combustion enthalpy values (calorific values) and the experimental values are compared, and a linear relation between the values is found. Sulfonation and neutralization processes are examined by elemental sulfur analysis and atomic absorption spectroscopy (AAS). It was obvious that increasing sulfonation degree yields a decrease in the combustion enthalpy values, as it is expected from the theoretical calculations. In addition, metal ion incorporation to the structure deviates the experimental combustion enthalpy values especially for the ionomers which have higher sulfonation degrees. This is due to the formation of a higher degree aggregation. © Wiley Periodicals, Inc. J Appl Polym Sci 100: 4684–4688, 2006     

Effects of psyllium and cellulose fibres on thermal,structural, and in vitro digestion behaviour of wheat starch

The study investigated the effects of adding different types of fibre (psyllium and cellulose) on in vitro digestion behaviour of wheat starch with its thermal and structural properties. Psyllium and cellulose fibres interfered with the wheat starch differently. Psyllium fibre hindered starch gelatinisation, restricted the loss of starch crystallinity, and decreased the accessibility of enzymes to starch. In contrast, cellulose fibre had no significant effect on gelatinisation and loss of crystallinity but limited the digestive enzyme mobility. The impact of psyllium was more pronounced than cellulose on reducing starch digestibility. Rapidly digestible starch fractions of the cooked starch reduced from between 57.90 ± 0.60–69.72 ± 0.46 (% in starch) to between 28.06 ± 0.36–46.34 ± 1.10 (% in starch) and 53.23 ± 0.36–66.71 ± 0.24 (% in starch) for psyllium and cellulose fibre, respectively. This information could be helpful to design foods containing starch with reduced digestibility for a healthy diet.     

Oleogel production based on binary and ternary mixtures of sodium caseinate,xanthan gum,and guar gum: Optimization of hydrocolloids concentration and drying method

We report the optimization of oleogel formulation based on sodium caseinate (CN, 0–4 g/100 g), xanthan gum (XG, 0–1 g/100 g), guar gum (GG, 0–1 g/100 g), and drying method (freeze and oven drier) using response surface methodology to achieve the desired oil binding capacity, textural, and rheological attributes. All the selected responses were successfully fitted by a quadratic model with determination coefficient values higher than .95 with the exception of firmness values which was fitted by linear model. There were considerable increases in all the responses for the samples containing ternary mixtures of protein-gum (CN:XG:GG) as well as binary mixtures (CN:GG and CN:XG) compared to samples containing protein or gums alone due to the synergistic effect of CN and gums on formation of highly ordered and strong gel network. Regression modeling demonstrated that freeze drying method led to significantly greater structure recovery values than those of oven drying method. The best formulation was the freeze dried oleogel containing 4 g/100 g CN, 0.43 g/100 g XG, and 0.98 g/100 g GG. Results showed that fabrication of oleogels with at least 94.5 g/100 g sunflower oil and characteristics similar to industrial shortening is feasible.     

Exergetic assessment of EAHEs for building heating in Turkey: A greenhouse case study

The present study undertakes an exergy analysis of earth to air heat exchanger (EAHE) and applies to a local one in Turkey. Namely, the exergy performance of an EAHE has been evaluated in a demonstration in Solar Energy Institute of Ege University, Izmir, Turkey. Exergetic efficiencies of the system components are determined as an attempt to assess their individual performances. The daily maximum heating coefficient of performance (COP) value for the system is obtained to be 6.18. The total average COP in the experimental period is found to be 4.74.     

An implementation methodology for supervisory control theory

In this study, a methodology for PLC implementation of Supervisory Control Theory is introduced and realized on a pneumatic manufacturing system. The implementation methodology resolves the problem of avalanche effect and enhances program readability. We use local modular approach, which exploits modular structure of the plant and of the specifications. Local modular approach, together with the implementation methodology presented in this study provides an effective way for synthesizing and realizing supervisors for Discrete Event Systems (DES) control problems. The resulting PLC program is also modular in structure, making it handable for modification and error detection.     

Microfluidic‐Based Approaches in Targeted Cell/Particle Separation Based on Physical Properties: Fundamentals and Applications

Cell separation is a key step in many biomedical research areas including biotechnology, cancer research, regenerative medicine, and drug discovery. While conventional cell sorting approaches have led to high‐efficiency sorting by exploiting the cell's specific properties, microfluidics has shown great promise in cell separation by exploiting different physical principles and using different properties of the cells. In particular, label‐free cell separation techniques are highly recommended to minimize cell damage and avoid costly and labor‐intensive steps of labeling molecular signatures of cells. In general, microfluidic‐based cell sorting approaches can separate cells using “intrinsic” (e.g., fluid dynamic forces) versus “extrinsic” external forces (e.g., magnetic, electric field, etc.) and by using different properties of cells including size, density, deformability, shape, as well as electrical, magnetic, and compressibility/acoustic properties to select target cells from a heterogeneous cell population. In this work, principles and applications of the most commonly used label‐free microfluidic‐based cell separation methods are described. In particular, applications of microfluidic methods for the separation of circulating tumor cells, blood cells, immune cells, stem cells, and other biological cells are summarized. Computational approaches complementing such microfluidic methods are also explained. Finally, challenges and perspectives to further develop microfluidic‐based cell separation methods are discussed.     

A tabu search approach for buffer allocation in production lines with unreliable machines

The optimal allocation of buffers is an important research issue in designing production lines. In this study, a tabu search (TS) algorithm is proposed to find near-optimal buffer allocation plans for a serial production line with unreliable machines. The main objective is to maximize the production rate, i.e. throughput, of the line. The efficiency of the proposed method is also tested to solve buffer allocation problems with the objective of total buffer size minimization. To estimate the throughput of the line with a given specific buffer allocation, an analytical decomposition approximation method is used. The performance of the tabu search algorithm is demonstrated on existing benchmark problems. The results obtained by the TS algorithm are clearly encouraging, as the TS algorithm is much better than the other algorithms for all considered benchmark problems.     

Preparation of electrospun nanofibers of star-shaped polycaprolactone and its blends with polyaniline

The electrospun nanofibers of synthetic star-shaped poly(?-caprolactone) (PCL) and its blends with polyaniline (PANI) were prepared. We utilized the advantages of star-shaped PCL and benefits of electrospinning method for obtainment of the uniform nanofibers with improved properties for tissue engineering. Biodegradable star-shaped PCL with four arms was synthesized by Sn(Oct)₂-catalyzed ring-opening polymerization (ROP) of ?-caprolactone (CL) from a pentaerythritol core. The chemical structure of star-shaped PCL was investigated by FTIR, and average molecular weight of polymer was determined by ¹HNMR (about 38000 g mol^?1). Thermal behavior of star-shaped PCL was also studied by Thermogravimetric Analysis (TGA). Moreover, the cyclic voltammetry (CV) measurement confirmed the preparation of electroactive nanofibers. The scanning electron microscopy (SEM) was also used to investigate the morphology of electrospun nanofibers produced from star-shaped PCL and its blends with PANI with different feed ratios. The presence of PANI resulted in fibers with diameters less than 100 nm and significant decrease of bead formation.