Graft copolymerization of methyl methacrylate onto starch using a Ce(IV)–glucose initiator system

Graft copolymerization of methyl methacrylate onto starch was carried out in aqueous medium using Ce(IV)–glucose initiator in the temperature range 40–60°C. Effects of concentration of Ce(IV), glucose, H₂SO₄, monomer, and starch on grafting were investigated. Percentages of grafting were evaluated and compared. The overall energy of activation was calculated from the effects of time and temperature of polymerization. The reaction mechanism was also discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 981–990, 2004     

Role of dopant cations in the gelation behaviour of silica sols

Gelation times of tetraethyl orthosilicate-derived sols containing selected di- to tetravalent cations as dopants were noted at different temperatures (15°–50°C). An analysis of these data, in conjunction with relevant published information, led to the tentative conclusions that (i) unhydrolyzed cations in bare form linked negatively charged silicate polymers in sols, thereby accelerating gelation and (ii) hydrolyzed cations retarded the process by offering molecular size-related hindrance and competition for the available water for hydrolysis.     

Red edge excitation shift emission spectroscopic investigation of serum albumins and serum albumin-bilirubin complexes

The microenvironments around the intrinsic and extrinsic fluorophores in bovine and human serum albumins as well as their complexes with bilirubin have been visualized by red edge excitation shift (REES) emission spectroscopic investigation. The two albumins and their bilirubin complexes in aqueous buffered solutions (pH 7.5) do not exhibit any appreciable shift in their emission maxima, upon gradual change in excitation wavelength towards the red edge of their respective absorption band. The addition of Triton X-100 triggers REES emission in both the fluorophores. The observations suggest that the microenvironment around the flurophores are not so rigid, and even the extrinsic flurophore bilirubin having two carboxylic acid groups acts as a hydrophobic non-polar molecule when bound to albumins. The ligand binding domains (receptor sites) are large enough and incorporation of Triton X-100 makes the fluorophore environments rigid and subtle polarity may also be induced. Whereas small polar molecules like CHCl3, ANS and L-trp fail to induce REES emission in either of the fluorophores.     

Enhanced Channel Division Method for Estimation of Discharge in Meandering Compound Channel

Accurate prediction of shear force distribution along the boundary in open channels is a key to the solution of numerous hydraulic problems. The problem becomes more complicated for meandering compound channels. A model is developed for predicting the percentage of shear force at the floodplain (%S_fp) of two-stage meandering channels using gene-expression programming (GEP) by considering five dimensionless parameters viz. the width ratio, relative depth, sinuosity, bed slope, and meander belt width ratio as the inputs in the model. Basing on the %S_fp, the apparent shear force along the division lines of separation in compound channels is selected for discharge calculation using the conventional channel division methods. An Enhanced Channel Division Method (ECDM) is introduced to calculate discharge by assuming interface line at main channel and floodplain junction. A modified variable-inclined (MVI) interface is suggested having zero apparent shear determined from flow contribution in the main channel and floodplain. The MVI interface is further used to calculate discharge in the meandering compound channels. Performance of the GEP model is tested against other analytical methods of calculating %S_fp. Error between the observed and calculated discharges using the MVI interface is found to be the minimum when compared to other interface methods. The enhance channel division method is successfully applied for validating the two available overbank discharge values for the river Baitarani at Anandapur (drainage area of 8570 sq. km), giving the minimum errors of 0.31% and 1.02% for flow depths of 7.5 m and 8.63 m, respectively.

     

Real time estimation of task specific self-confidence level based on brain signals

Multimedia Tools and Applications - Self-confidence is one’s own belief of success with respect to a specific task. Cognitive tasks like decision making, problem solving etc. are influenced a...     

Determination of reference values of apparent mass responses of seated occupants of different body masses under vertical vibration with and without a back support

The biodynamic response of human body seated without a back support and exposed to vertical whole-body vibration have been standardized in ISO 5982 and DIN 45676 in terms of driving-point mechanical impedance and apparent mass. A comparison of ranges defined in two standards, however, reveal considerable differences in both the magnitude and phase. Greater differences are more evident for the three body mass groups, which suggests the lack of adequate reference values of biodynamic responses of seated human subjects of different body masses. In this experimental study, the biodynamic responses of seated humans within three different body mass ranges are characterized under different magnitudes of vibration and three different sitting postures in an attempt to define reference values of apparent mass for applications in mechanical-equivalent model development and anthropodynamic manikin design. Laboratory measurements were performed with adult male subjects of total body mass in the vicinity of 55, 75 and 98 kg (nine subjects for each mass group) seated with and without an inclined back support and exposed to three different magnitudes of white-noise vertical vibration (0.5, 1.0 and 2.0 m/s² unweighted rms acceleration) in the frequency range between 0.5 and 20 Hz. The measured data were analyzed to derive the mean magnitude and phase responses for the three body masses, posture and excitation conditions. The mean magnitude responses of subjects within three mass groups were compared with idealized ranges defined in ISO 5982 and mean values described in DIN 45676 for no back support condition. The results revealed significant differences between the mean measured and standardized magnitudes, suggesting that the current standardized values do not describe the biodynamic responses of seated occupant of different masses even for the back not supported condition. The mean measured responses revealed most important effect of body mass, irrespective of the sitting posture. The reference values of apparent mass responses of seated body subject to vertical whole-body vibration are thus defined for three mass groups and different back support conditions that may be considered applicable for ranges of excitations considered. The responses of the body seated without a back support, also revealed notable influences of excitation magnitude, particularly on the primary peak frequencies.     

A‐shaped wideband dielectric resonator antenna for wireless communication systems and its MIMO implementation

In this article, a new A‐shaped dielectric resonator antenna (DRA) excited by a conformal strip is proposed for wideband applications. The wide bandwidth is achieved by combining two adjacent modes that is, TM₁₀₁ and TM₁₀₃. The experimental results demonstrate that the proposed DRA offers an impedance bandwidth (for S11?10 dB) of 59.7% (3.24‐6.0 GHz), covering IEEE 802.11 and U‐NII bands. The antenna provides a fairly stable radiation pattern with the gain ranging from 5.29 to 7 dBi across the operating bandwidth. A dual‐element multiple‐input multiple‐output (MIMO) system is also realized using the proposed wideband DRA. The impedance bandwidth of the dual‐element MIMO antenna is 59.2% and 60.9% for Port1 and Port2, respectively and the isolation between the ports is better than 20 dB across the bandwidth. For Port1, the gain of the MIMO antenna ranging from 6.03 to 7.45 dBi is obtained across the bandwidth. Furthermore, the diversity performance of the MIMO antenna is found to be good with envelope correlation coefficient below 0.003 over the operating band. The proposed antenna could be the potential candidate for worldwide interoperability for microwave access (WiMAX), wireless local area network (WLAN) and lower European UWB frequency band (3.4‐5.0 GHz) applications.     

A closed-loop data based test for robust performance improvement in iterative identification and control redesigns

In robust iterative identification and control redesign techniques, a stabilizing controller connected in a closed loop is normally replaced by an alternative attractive stabilizing controller to improve robustness and performance of the closed-loop system. In this paper, novel test methods are proposed to check whether a new stabilizing controller improves performance or not when the existing controller is replaced by this new controller in the closed loop. The proposed tests are based on closed-loop data and no plant model, and can be used for both the SISO and MIMO linear time-invariant systems. For the proposed tests, the plant dynamics is assumed to be unknown whereas the existing and new controller transfer function matrices are known to the designer. These assumptions are common in iterative identification and control redesign techniques. The performance improvement test methods proposed in this paper build on the experimental set-up proposed in Dehghani, Lecchini, Lanzon, and Anderson (2009) which was used to only check whether controllers ensure internal stability of a feedback interconnection or not. In this paper, new test methods are proposed to ascertain robust performance improvement that cannot be obtained from test results of Dehghani et al. (2009). A numerical example is illustrated to show effectiveness of the proposed test methods.     

Tl(III) initiated polymerization of methyl methacrylate in micellar phase

The polymerization kinetics of methyl methacrylate (MMA) was studied, using Tl(III)‐cyclohexanone (CH) redox system as initiator, in the presence of emulsifier [i.e., sodium dodecyl sulfate (SDS), cetyltrimethylammonium bromide (CTAB), and thallium triacetate (TX‐100)] over a temperature range of 25–45°C. The effect of various concentrations of MMA, Tl(III), cyclohexanone, H⁺, and varying ionic strengths on the rate of polymerization, rate of Tl(III) consumption (?R_Tl), and the percentage of monomer conversion were examined in the presence of 0.015M SDS. The kinetic results of polymerization in the absence and presence of 0.015M SDS were compared in terms of overall activation energy (E_a) for the process. The viscosity‐average molecular weight (M_V) of the polymers, obtained in the presence of varying concentrations of anionic surfactant (SDS), was also determined. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 2480–2485, 2004