Interest in the development of polymeric hydrogels impregnated with carbon-nanotubes (CNTs) is growing rapidly in recent times owing to their usefulness in many fields of human endeavor. This review paper serves as an archive of literature reports of several researchers who have worked on polymeric hydrogels embedded with CNTs for diverse applications. The review covers up to date research advancement on the synthesis and characterization properties of CNTs nanocomposite hydrogels. Besides, this review discusses extensively the various fields in which polymeric hydrogels infused with CNTs have been applied. This unprecedented compilation of CNTs nanocomposite hydrogels information into a single revision allows a straightforward comparison of studies performed for diverse applications. 相似文献
The aim of the present study is to assess the suitability of some waste kaolinitic sand as grog for bricks and concretes. Three samples were selected and their chemical and mineralogical compositions as well as their ceramic and mechanical properties were investigated. The solid phase composition as well as the microstructure of the vitrified samples was also carried out using XRD and SEM methods. Refractoriness under load and thermal shock resistance are also investigated. Chemical and phase composition confirm that two samples (1 and 2) are fireclay with total impurities oxide contents (TIOC) less than 3.0 % while the third is mainly silica with TIOC less than 0.5 %. The microstructure of samples 1 and 2 shows predominant mullite crystals, bonded by silicate phases as confirmed by XRD, whereas silica phases are the main components of the third sample with minor intercalation of mullite phase. It is concluded that samples 1 and 2 fired at 1500 ?C can be used as grog for brick and concrete manufacture in industrial furnaces up to 1400 °C while sample 3 needs some additives to form denser grains. 相似文献
The present paper is focused on exploiting Plackett–Burman design to examine the formulation effect of various chemical components content on the curing characteristics of oil palm ash (OPA)-filled acrylonitrile butadiene rubber (NBR) compound. The filled-NBR compound was prepared by conventional laboratory-sized two roll mill and cured using sulfuric system. Six independent variables such as content of zinc oxide, stearic acid, N-isopropyl-N′-phenyl-p-phenylenediamine, N-cyclohexyl-2-benzothiazole sulfenamide (CBS), sulfur, and even OPA filler were carried out to screen their significant effect on the curing characteristics of NBR compound. The scorch time, optimal cure time, minimum torque, and maximum torque were selected as a response. Results showed that the scorch time and the optimal cure time were significantly affected by CBS, whereas the minimum torque and maximum torque were significantly affected by OPA and sulfur, respectively, within the studied range. Among the chemical components under study, zinc oxide and stearic acid had the least effect on the curing properties of NBR compound. Analysis of variances for all factorial models demonstrated that the model was significant with P value <0.05 while the regularity (R2) of all models was greater than 0.9. Lastly, the optimal chemical concentrations were predicted to acquire the optimal condition of the curing system for filled-NBR compound. 相似文献
Appropriate membrane for blood contacting applications requires hemocompatibility and high permeation flux; it should inhibit proteins or platelets adsorption and still possess high permeability. Aiming to improve the polyethersulfone (PES) hollow fiber membrane hemocompatibility, sulfonated polyether ether ketone (SPEEK) is self‐synthesized in the present research and added to PES in different ratios. Scanning electron microscopy images have revealed significant changes in PES membranes structure after addition of SPEEK, which can influence water permeation property of the membranes. Water contact angles of the membranes have reduced from 75° to 50° after addition of 4 wt% SPEEK. Influence of SPEEK addition on hemocompatibility of the PES membranes is evaluated via protein (bovine serum albumin) adsorption, platelet attachment, and coagulation time (APTT and TT) assays. Obtained results reveal that hemocompatibility of the modified hollow fiber membranes is enhanced as a result of emerging repulsive forces between negative charges on the membranes surface and negatively charge blood components.
This work deals with the synthesis of ZnFe2O4 NPs and studies the effect of addition on the physical properties PVDF/PVC blend. XRD affirmed the formation of ZnFe2O4 NPs and HRTEM shows that the size of the prepared ZnFe2O4 NPs ranged from 20 to 55 nm. The effect of ZnFe2O4 on the behavior of PVDF/PVC was studied through XRD, ATR-FTIR, FESEM and UV–Visible spectroscopy. XRD revealed that the addition of ZnFe2O4 NPs enhanced the crystallinity of PVDF/PVC blend system and also confirmed the incorporation of ZnFe2O4 NPs by appearing a diffraction peak at 2θ equals 35°. ATR-FTIR affirmed the interaction between blend sample and ZnFe2O4 NPs by appearing new bands 554 cm?1 and 421 cm?1 which are corresponded to ZnFe2O4 NPs functional group with appearing a new band at 603 cm?1. FESEM showed that the addition of ZnFe2O4 to PVDF/PVC blend improved surface properties, for example, roughness average has been increased from 319 to 414 nm while maximum height increased from 260 to 473 nm for PVDF/PVC and PVDF/PVC/10% ZnFe2O4, respectively. Optical properties and band gap calculations revealed that addition of ZnFe2O4 NPs changes the structure of polyblend samples which results due to the formation of localized states. The removal efficiency of Cd (II) by using PVDF/PVC/10% ZnFe2O4 reached about 50% at pH 6 after 60 min. the absorption mechanism as well as kinetics isotherm have been studied. It is found that adsorption of Cd (II) occurred through the Langmuir mechanism and fellow pseudo-second order isotherm.
In this study, mercury iodide (HgI2) nanoparticles (NPs) were synthesized by pulsed laser ablation in ethanol at laser fluences of 22.9, 33.1, and 43.3 J/cm2. The effect of laser fluence on the structural and optical properties of HgI2 NPs was studied. X-ray diffraction findings reveal that all synthesized HgI2 samples were polycrystalline in nature with orthorhombic structure. Absorption peak was appeared at 474 nm and the optical energy gap of HgI2 NPs decreases from 2.13 to 2.05 eV as laser fluence increased from 22.9 to 43.3 J/cm2. Zeta potential (ZP) results confirm that the nanoparticles synthesized at 22.9 and 33.1 J/cm2 have high degree of stability. Fluorescence measurements show the presence of several emission bands. Raman spectra of HgI2 NPs show the presence of six vibration modes centered at 15, 29, 37, 44, 51, and 70 cm?1. Fourier transform infrared (FT-IR) results show the presence of two bonds, namely, C–O and Hg-I. Transmission Electron Microscope (TEM) results showed that the formation of spherical nanoparticles for sample prepared at 22.9 J/cm2, 25–75 nm in size. While the nanoparticles synthesized with 33.1 and 43.3 J/cm2 exhibit nanorods and nanotubes morphologies, respectively. The dark I–V characteristics of β-HgI2 NPs/Si heterojunction photodetectors show rectification properties and the junction quality depends on the laser fluence and the best junction characteristics was obtained for heterojunction prepared at 33.1 J/cm2. The white light photosensitivity of the HgI2/p-Si photodetectors was measured at reverse bias under different intensities. The maximum responsivity reached was 3.39A/W at 450 nm for photodetector prepared at 33.1 J/cm2.