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101.
提出了一种镁合金管材转角焊合室分流挤压新工艺,该工艺可在有效延长焊合室长度和焊合时间前提下保证舌针刚度,从而保证管材尺寸精度,并且可通过转角剪切变形机制增加预焊合金属变形量和动态再结晶程度,从而有利于提高管材性能和焊缝焊合性能。利用有限元法揭示了转角焊合室分流挤压成形过程中金属的流动特征,应变分布特征和焊合室内的静水压力分布特征。结果表明,整个挤压过程无金属折叠,从而保证管材的表面质量;流经转角后预焊合金属变形量明显增加,有利于提高管材质量和焊缝质量。最后,研究揭示了坯料初始温度,挤压速度和模具转角对焊合室内静水压力的影响规律。结果表明,随着挤压速度的增加和模具转角的增大,转角焊合室内静水压力增大;随着坯料预热温度的增加,转角焊合室内静水压力呈先增大后减小的趋势。 相似文献
102.
对赵固一矿12051回风巷和运输巷掘进工作面瓦斯涌出来源进行了分析研究,提出了进行本煤层条带预抽煤层瓦斯和巷帮抽采煤层瓦斯的治理方法,并对抽放钻孔进行了设计和实施。采取措施后,掘进工作面风排瓦斯量明显减少,保证了工作面的安全生产。 相似文献
103.
Xiangrong Ma Rui Dang Ning Yang Xiao Li Ya zhang Ying Gong Zhipan Liu Wei Guo Yuanyuan Zhang Chunyan Li 《International Journal of Hydrogen Energy》2021,46(44):22842-22851
The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag3VO4 have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag3VO4 (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H2 production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H2 evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H2 evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions. 相似文献
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105.
Artworks based on Xuan paper or silk and painted by organic or inorganic pigments are highly responsive to light due to their materials and manufacturing technologies. They belong to the highest level of light responsive exhibits stipulated by International Commission on Illumination (CIE) and are vulnerable to fading and discoloration caused by radiation from light sources. The choice of light sources is the key of protection for artworks. It is indispensible and urgent to choose the lowest damage light sources according to the material characteristics of artworks. In this article, long-term irradiation of typical light sources on various substrates and pigments was used as experimental method, and CIE DE2000 color difference formula was used as the evaluation index. The laws of the influence of different light sources on the color change of various materials were obtained, and the relative damage coefficients of light sources were calculated. Finally, eight kinds of light sources suitable for illuminating responsive artworks with typical material combinations were proposed. However, there are some limitations in the study, because the ancient Chinese Xuan paper and silk used as experimental objects in the experiment are yellowish. Thus, the models derived in this article are not suitable for choosing reasonable display light sources for other works of art. However, suitable light sources for different materials could be obtained by the calculation method used in this article. 相似文献
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107.
萘降解菌的筛选及降解性能的初步研究 总被引:6,自引:0,他引:6
微生物降解是多环芳烃从土壤和水环境中消失的主要途径。本文从加油站废油排放口附近被污染土壤中筛选到两种降解萘的混合菌H1、H2并从中分离出一株纯菌C_1。研究发现,利用纯无机盐培养基加萘作为唯一碳源要比加入其它营养物质的培养基对于筛选萘降解菌更为有利。H_1、H_2和C_1均能以萘为唯一碳源生长,在萘初始浓度为1000mg/L的纯无机盐培养基中培养40h后,培养液中微生物数量分别增长10倍以上,利用气相色谱测得萘的降解率都达到99.6%以上。 相似文献
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110.
Discovery of a Short‐Chain Dehydrogenase from Catharanthus roseus that Produces a New Monoterpene Indole Alkaloid 下载免费PDF全文
Dr. Anna K. Stavrinides Dr. Evangelos C. Tatsis Dr. Thu‐Thuy Dang Dr. Lorenzo Caputi Dr. Clare E. M. Stevenson Dr. David M. Lawson Dr. Bernd Schneider Prof. Sarah E. O'Connor 《Chembiochem : a European journal of chemical biology》2018,19(9):940-948
Plant monoterpene indole alkaloids, a large class of natural products, derive from the biosynthetic intermediate strictosidine aglycone. Strictosidine aglycone, which can exist as a variety of isomers, can be reduced to form numerous different structures. We have discovered a short‐chain alcohol dehydrogenase (SDR) from plant producers of monoterpene indole alkaloids (Catharanthus roseus and Rauvolfia serpentina) that reduce strictosidine aglycone and produce an alkaloid that does not correspond to any previously reported compound. Here we report the structural characterization of this product, which we have named vitrosamine, as well as the crystal structure of the SDR. This discovery highlights the structural versatility of the strictosidine aglycone biosynthetic intermediate and expands the range of enzymatic reactions that SDRs can catalyse. This discovery further highlights how a sequence‐based gene mining discovery approach in plants can reveal cryptic chemistry that would not be uncovered by classical natural product chemistry approaches. 相似文献