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51.
A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, Mn = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (Mn = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
52.
Porous poly(vinyl alcohol) (PVA) membranes were prepared by a phase‐inversion method. The influence of chemical crosslinking and heat treatments on the swelling degree, resistance to compaction, mechanical strength, and morphology of porous PVA membranes was extensively studied. The crosslinking degree and crystallinity of the membranes, calculated from IR spectra, increased with the treatment time. The porosity, calculated on the basis of swelling experiments, showed a decreasing trend for heat‐treated membranes but remained almost at a constant value for crosslinked membranes. Such a change was further proved with scanning electron microscopy pictures. The behavior was explained by the rearrangement of PVA chains during the heat‐treatment process, which led to morphological changes in the membranes. The mechanical properties of the porous membranes in dry and wet states were measured, and a great difference was observed between crosslinked and heat‐treated membranes in the dry and wet states. The crosslinked membranes showed good mechanical properties in the dry state but became fragile in the wet state. On the contrary, the heat‐treated membranes were more flexible in the wet state than in the dry state. This change was explained by the turnaround of inner stress in the systems during the swelling process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
53.
54.
本文主要介绍了绿化混凝土的概念、分类,绿化混凝土构筑适合于植物生长环境的措施。通过对再生骨料绿化混凝土的原材料和配合比试验以及物理力学性能及耐久性能试验,为进一步的工程应用提供了可靠的依据。 相似文献
55.
风景名胜门票只涨价而不持续发展,势必陷入恶性循环。反之,以大力提高综合效益,则门票可平价,降价,甚至免费,反倒可进入良性互动的循环。 相似文献
56.
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Wenying Wei Zhen Wang Yanhua Yin Jinyu Han Wen Xu 《Korean Journal of Chemical Engineering》2008,25(3):562-567
Composition Group Vector Space (CGVS) method for estimating melting and boiling point T
m
, T
b
of organic compound has been proposed, and the principle of this method has been elucidated. The models for estimating T
m
, T
b
have been established and the numerical values of relative parameters have been presented. The average percentage deviations
of T
m
, T
b
estimation are 7.53 and 1.58, respectively, which show that the present method demonstrates significant improvement in applicability
to predict the above properties, compared to conventional group methods. 相似文献
58.
Summary Well-defined water-soluble poly(styrenesulfonate)-b-poly(ethylene glycol)-b- poly(styrenesulfonate) (PSS-b-PEG-b-PSS) triblock
copolymers with narrow molecular weight distribution (1.29 < Mw/Mn < 1.36) were synthesized in aqueous solution at 70 oC via reversible addition-fragmentation chain transfer (RAFT) polymerization. The complex formed by the PSS-b-PEG-b-PSS triblock
copolymer coordinated with aluminum ion was investigated with turbidimetry, dynamic light scattering (DSL), zeta-potential,
and transmission electron microscopy (TEM). The aggregation formation was based on the neutralization of the SO3- groups in the PSS blocks with Al3+ ions. The appearance, size and stability of the PSS-b-PEG-b-PSS/Al3+ aggregates were controlled by varying the PSS block length and degree of neutralization (DN). At DN = 0.33, where the PSS-b-PEG-b-PSS
copolymer was completely neutralized with Al3+, the aggregate size increased with increasing PSS block length. The transition from the shrinking coil of small size to the
interchain aggregates of large size was found at DN of about 0.33. 相似文献
59.
60.