Synthesis and properties of organotin epoxy polymers from tri-n-butyltin esters of ω - amino acids

Structure-property relationships in a series of thermoset organotin polymers have been investigated. The tri-n-butyltin esters of glycine, 4-aminobutanoic, 6-aminohexanoic, and 11-aminoundecanoic acids were synthesized and reacted with diepoxides to prepare prepolymers carrying epoxide end groups. The prepolymers were crosslinked by diethylenetriamine or metaphenylenediamine. Similar epoxy network polymers were prepared directly from the tributyltin ester of 3,5-diaminobenzoic acid which was also synthesized. The strength, moduli, toughness, glass transition and dynamic mechanical response of the polymers were investigated, and correlated with structural changes introduced in the network. The results establish the utility of the adopted synthesis schemes in exercising considerable control over the bulk polymer properties, and consequently, in modifying the controlled release of organotin groups from the crosslinked network.     

Nitriding of steel parts for machine construction in an endothermic atmosphere

Conclusion To ensure the required characteristics of the diffusion layer in heat-resistant steels, it is recommended to subject them to two-stage nitriding: saturation at 950°C for 2 h in endogas with an addition of 12% natural gas and 4% ammonia, lowering the temperature to 900°C, holding for 5 h in endogas with an addition of 6% natural gas and 4% ammonia; exchange of gas 6 times.Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 4, pp. 34–36, April, 1982.     

Natural convection from a semi-infinite flat plate inclined at a small angle to the horizontal in a saturated porous medium

Summary The free convection boundary layer on a semi-infinite heated flat plate which is inclined at a small angle to the horizontal in a saturated porous medium is considered. When the plate is inclined upwards, series solutions, one valid near the leading edge and the other valid at large distances from it, are obtained. Sufficient terms in the leading edge solution are taken so that the two asymptotic solutions may be joined. When the plate is inclined downwards the series solution valid near the leading edge is again obtained and sufficient terms are again employed to investigate the nature of the boundary layer separation. There is no evidence of a singularity at the separation point and a mathematical explanation of the behaviour at separation is presented.With 10 Figures     

Substrate preparation for thin film deposition—a survey

Surface preparation is an integral part of any thin film deposition process. As the technological demands on films and coatings increase, the need for better and more reproducible surface preparation techniques is also increased. There is a wide variety of approaches to surface preparation and each film-substrate couple and function require specific development. This paper outlines the problems to be considered and some general approaches to surface preparation technologies.     

Psychology and the threat of nuclear war.

Discusses what is known about the effect of nuclear war on survivors' behavior, the effect of the threat of nuclear war, reducing the threat of nuclear war, and psychology's role in reducing the threat of nuclear war. It is concluded that although psychology has a certain level of understanding of the causes and consequences of nuclear war, its ability to provide counsel is limited. (55 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Synthesis and characterisation of copolyesters from poly(ethylene terephthalate) and poly(hexamethylene terephthalate)

Copolyesters containing poly(ethylene terephthalate) and poly(hexamethylene terephthalate) (PHT) were prepared by a melt condensation reaction. The copolymers were characterised by infrared spectroscopy and intrinsic viscosity measurements. The density of the copolyesters decreased with increasing percentage of PHT segments in the backbone. Glass transition temperatures (T_g). melting points (T_m) and crystallisation temperatures (T_c) were determined by differential scanning calorimetry. An increase in the percentage of PHT resulted in decrease in T_g, T_m and T_c. The as-prepared copolyesters were crystalline in nature and no exotherm indicative of cold crystallisation was observed. The relative thermal stability of the polymers was evaluated by dynamic thermogravimetry in a nitrogen atmosphere. An increase in percentage of PHT resulted in a decrease in initial decomposition temperature. The rate of crystallisation of the copolymers was studied by small angle light scattering. An increase in percentage of PHT resulted in an increase in the rate of crystallisation.     

Effects ofSolanum glycoalkaloids on chemosensilla in the Colorado potato beetle

Steroidal glycoalkaloids, found in species of the Solanaceae, elicit bursting activity in galeal and tarsal chemosensilla of adult Colorado potato beetles. The effect has an average latency of 6–12 sec, depending on the sensillum/alkaloid combination. A 20-sec alkaloid treatment is often suffficient to render galeal sensilla unresponsive to gamma-aminobutyric acid, normally an effective stimulant. The alkaloids have similar effects on galeal sensilla of larval Colorado potato beetles and on labellar chemosensilla of the blowfly. It is concluded that these compounds act independently of any specialized chemoreceptor in the Colorado potato beetle, and that association of the Colorado potato beetle with solanaceous plants has not led to evolution of a specific receptor forSolanum glycoalkaloids.     

Occupational airway diseases in the metalworking industry Part 1: Respiratory infections, pneumonia, chronic bronchitis and emphysema

Occupational airway diseases are now receiving attention in industry, although study is hampered by a lack of readily-available data. The interpretation of the data that is available, and also of the root problems themselves, is itself a difficult problem. This paper has been written as a literature review which it is hoped that other researchers can take either as a starting point or as a refresher.