Tribological Behavior of Composites Based on ZA-27 Alloy Reinforced with Graphite Particles

The objective of this investigation is to assess the influence of graphite reinforcement on tribological behavior of ZA-27 alloy. The composite with 2 wt% of graphite particles was produced by the compocasting procedure. Tribological properties of unreinforced alloy and composite were studied, using block-on-disk tribometer, under dry and lubricated sliding conditions at different specific loads and sliding speeds. The worn surfaces of the samples were examined by the scanning electron microscopy (SEM). The obtained results revealed that ZA-27/graphite composite specimens exhibited significantly lower wear rate and coefficient of friction than the matrix alloy specimens in all the combinations of applied loads (F _n ) and sliding speeds (v) in dry and lubricated tests. The positive tribological effects of graphite reinforcement of ZA-27 in dry sliding tests were provided by the tribo-induced graphite film on the contact surface of composite. In test conditions, characterized by the small graphite content and modest sliding speeds and applied loads, nonuniform tribo-induced graphite films were formed leading to the increase of the friction coefficient and wear rate, with increase of the sliding speed and applied load. In conditions of lubricated sliding, the very fine graphite particles formed in the contact interface mix with the lubricating oil forming the emulsion with improved tribological characteristics. Smeared graphite decreased the negative influence of F _n on tribological response of composites, what is manifested by the mild regime of the boundary lubrication, as well as by realization of the mixed lubrication at lower values of the v/F _n ratio, with respect to the matrix alloy.     

The effect of processing conditions on the morphology, thermomechanical, dielectric, and piezoelectric properties of P(VDF-TrFE)/BaTiO3 composites

In this study (0–3) P(VDF-TrFE)/BaTiO₃ composites containing up to 60 vol% of ceramic phase were prepared by solvent casting or compression molding. Their thermomechanical, dielectric, and piezoelectric properties were investigated, and discussed in the light of the properties of the basic components, the processing route and the resulting morphology. The crystalline structure of the P(VDF-TrFE) matrix was found to be highly dependent on the processing route, while the structure of BaTiO₃ was not affected by any of the processing steps. The mechanical properties of the solvent cast materials showed a maximum at 30 vol% BaTiO₃, while they increased monotonically with BaTiO₃ content for compression molded materials. This difference was attributed to a higher amount of porosity and inhomogeneities in the solvent cast composites. Permittivity as high as 120 and piezoelectric coefficient d ₃₃ up to 32 pC/N were obtained for compression molded composites, and the observed decrease in d ₃₃ with aging time was attributed to the effect of mechanical stress release in the polymer matrix.     

Phase transformations in the ternary Ag–Ga–Sb system

Phase diagram of the Ag–Ga–Sb ternary system was extrapolated using calculation of phase diagrams (CALPHAD) method. Phase transition temperatures of the alloys with compositions along three vertical sections with constant molar ratios Ga/Sb = 1, Ag/Ga = 1 and Ag/Sb = 1 were measured using differential scanning calorimetry (DSC). Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX) was used for identification of phases in equilibrated samples. Experimental results were compared with thermodynamic prediction.     

Prospects of wind energy sector development in Serbia with relevant regulatory framework overview

The growth of the renewable energy sector in the world in the first decade of the twenty-first century was rapid. Wind energy sector was one of the fastest growing renewable energy technologies. In this paper, authors have tried to review the current state of wind power utilization in Serbia as one of the most penetrating RES technologies in the world. The brief overview of electric power sector in Serbia was given in order to describe the environment for emerging wind energy sector development. Sufficient wind energy resources were identified in several regions of the country. Current energy policy in Serbia was reviewed in terms of the regulations that have to be followed in order to meet the requirements for RES power plants, i.e. wind power plant construction. In subsequent section short reviews of wind energy projects which are in their initial phases are provided. The wind energy sector in Serbia is emerging despite the difficulties faced by the investors, regulatory bodies and other shareholders, in the course of the past several years. There is an urgent need of a broader transfer of specific knowledge and technologies related to wind farms and wind turbines in order to speed up the current wind energy sector development.     

Perspective on the Development of Lead-free Piezoceramics

A large body of work has been reported in the last 5 years on the development of lead-free piezoceramics in the quest to replace lead–zirconate–titanate (PZT) as the main material for electromechanical devices such as actuators, sensors, and transducers. In specific but narrow application ranges the new materials appear adequate, but are not yet suited to replace PZT on a broader basis. In this paper, general guidelines for the development of lead-free piezoelectric ceramics are presented. Suitable chemical elements are selected first on the basis of cost and toxicity as well as ionic polarizability. Different crystal structures with these elements are then considered based on simple concepts, and a variety of phase diagrams are described with attractive morphotropic phase boundaries, yielding good piezoelectric properties. Finally, lessons from density functional theory are reviewed and used to adjust our understanding based on the simpler concepts. Equipped with these guidelines ranging from atom to phase diagram, the current development stage in lead-free piezoceramics is then critically assessed.     

Preparation and Characterization of KNbO3 Ceramics

The processing and characterization of electrical properties of potassium niobate ceramic, KNbO₃ (KN) have been studied. The difficulty of obtaining dense samples by conventional methods limits the knowledge on electrical properties of this material. In this paper, a complete route for processing of KN with density over 94% is described. Piezoelectric and dielectric data are presented. It is observed that the major problem concerning the density is related to incorrect stoichiometry, which is believed to be a more critical issue for this system compared with other electro-ceramics.     

Towards Weak Bisimulation For Coalgebras

This paper contains a novel approach to observational equivalence for coalgebras. We describe how to define weak homomorphisms, weak bisimulation, and investigate the connection between them as well as the relation to the known theory of bisimulation for coalgebras. The ultimate result of the paper is the correctness-proof for a weak coinduction proof principle.     

A receding horizon control approach to sampled-data implementation of continuous-time controllers

We propose a novel way for sampled-data implementation (with the zero order hold assumption) of continuous-time controllers for general nonlinear systems. We assume that a continuous-time controller has been designed so that the continuous-time closed-loop satisfies all performance requirements. Then, we use this control law indirectly to compute numerically a sampled-data controller. Our approach exploits a model predictive control (MPC) strategy that minimizes the mismatch between the solutions of the sampled-data model and the continuous-time closed-loop model. We propose a control law and present conditions under which stability and sub-optimality of the closed loop can be proved. We only consider the case of unconstrained MPC. We show that the recent results in [G. Grimm, M.J. Messina, A.R. Teel, S. Tuna, Model predictive control: for want of a local control Lyapunov function, all is not lost, IEEE Trans. Automat. Control 2004, to appear] can be directly used for analysis of stability of our closed-loop system.     

Variable neighborhood search and local branching

In this paper we develop a variable neighborhood search (VNS) heuristic for solving mixed-integer programs (MIPs). It uses CPLEX, the general-purpose MIP solver, as a black-box. Neighborhoods around the incumbent solution are defined by adding constraints to the original problem, as suggested in the recent local branching (LB) method of Fischetti and Lodi (Mathematical Programming Series B 2003;98:23–47). Both LB and VNS use the same tools: CPLEX and the same definition of the neighborhoods around the incumbent. However, our VNS is simpler and more systematic in neighborhood exploration. Consequently, within the same time limit, we were able to improve 14 times the best known solution from the set of 29 hard problem instances used to test LB.