Sondermetalle und ihre Anwendung im Chemieapparatebau

Refractory Metals and their Application in the Chemical Process Industry Special metals, such as titanium, zirconium and tantalum, are being used increasingly for chemical plant. The exceptional resistance of special metals to many corrosive chemicals - they show it even at high temperatures and pressures - arises not from natural immunity but from the formation of a protective oxide passive layer on the metal surface. Special metals are well suited for welding. Their reactions with gases of the atmosphere must be taken into account though. Welding is therefore possible only under inert gas or a high vacuum. Similarly, alloying with iron-based materials during welding must be avoided under all circumstances. It should be taken into consideration that the melting point of tantalum, for example, is about twice as high as that of steel. Tantalum and niobium are machined with high-speed cutting steels; the cutting speed and cutting angle are similar to those used for stainless steels. In detail, the outstanding properties of special metals in chemical plant are as follows:

• — the stability of titanium under oxidizing conditions
• — the stability of zirconium under reducing and alkaline conditions
• — the resistance of molybdenum to hydrofluoric acid and fluoride
• — the stability of tantalum under oxidizing and reducing conditions.

In pure mineral acids the passive behaviour generally improves in the order titanium - zirconium - tantalum. Except where molybdenum is concerned, the medium should not contain fluoride. The material with the widest range of applications is tantalum. The addition of niobium as an alloying element leads to favourably priced but similarly resistant materials whose prospects of becoming established in the chemical industry and playing a part similar in importance to that of tantalum itself are good.     

Digital parallelism, perpendicularity, and rectangles

The slope of digital line segments is defined and an algorithm to evaluate it is presented. Parallelism and perpendicularity of two digital line segments are also defined. Finally, rectangular digital regions are defined and characterized, and an algorithm that determines whether or not a given digital region is a digital rectangle is presented.     

Localizing overlapping parts by searching the interpretation tree

This paper discusses how local measurements of positions and surface normals may be used to identify and locate overlapping objects. The objects are modeled as polyhedra (or polygons) having up to six degrees of positional freedom relative to the sensors. The approach operates by examining all hypotheses about pairings between sensed data and object surfaces and efficiently discarding inconsistent ones by using local constraints on: distances between faces, angles between face normals, and angles (relative to the surface normals) of vectors between sensed points. The method described here is an extension of a method for recognition and localization of nonoverlapping parts previously described in [18] and [15].     

Tests in an MR reactor of experimental fuel elements of the VVÉR-1000 reactor

Conclusions In an MR reactor performance tests of 16 fuel assemblies, with elements having essentially the same structure as standard VVÉR-100 fuel elements, were carried out. Tests of five more fuel assemblies are continuing. Of the 16 assemblies, 13 were studied in a hot laboratory.The tests in the MR, carried out at high loads and with a large number of transition processes, as well as the postreactor studies, indicated that fuel elements of the specified design (with initial helium pressures of 1.96–2.45 MPa) have a high reliability. None of the elements of the fuel assemblies studied malfunctioned due to design defects or faults in their fabrication. During the tests the jackets were subject to a little oxidation and hydrogenation (zirconium-oxide film<3 m thick, hydrogen content less than 0.008% by mass), and their plasticity remained high (the relative elongation at the working temperature remained at the 20% level).Translated from Atomnaya Énergiya, Vol. 62, No. 5, pp. 312–317, May, 1987.     

Evaluation of the parameters of an experimental tokamak fusion-reactor and the influence of the indeterminacy of the plasmaphysical data

Conclusion Analysis using a simplified technicoeconomic model of a tokamak reactor and the procedures of graphic processing of the results allow the regions of the optimum parameters of an experimental minimum-cost reactor with various limitations to be determined. When refined and ignition scalings are taken into account simultaneously and an appropriate optimization is made we get the parameters of the experimental reactor, which differ slightly from the basic variant (in particular, a lower neutron load on the first wall). The reactor cost in this case should increase by 15–25% in comparison with the basic variant and remains virtually constant when the most favorable ignition scaling (ASDEX) is realized.Translated from Atomnaya Énergiya, Vol. 62, No. 1, pp. 22–28, January, 1987.     

A theoretical and experimental investigation of the plastic deformation process of sintered composite materials. III. An investigation of the spatial redistribution of the phases of a composite material in plastic deformation of it

Conclusions As in porous bodies, in dense composite materials plastic deformations may cause an increase in the local concentration (density) of elements of the hard phase in zones of active flow of the material. The intensity of structural rearrangement (regrouping) of the phases in a composite material is determined by the character of the relationship of the function of plasticity of the medium to the amount of the average (hydrostatic) stresses in the body being deformed and is related to the degree of deformation obtained by this body through the derivative (_ij)/_ii. The mutual disposition of the elements of the hard phase in a material may be fixed in any stage of the process of working by pressure if the conditions are created for combined flow of the different phases in the body being deformed.Translated from Poroshkovaya Metallurgiya, No. 10(298), pp. 53–57, October, 1987.     

Tri-Reforming of Methane over NdM0.25Ni0.75O3 (M = Cr,Fe) Catalysts and the Effect of CO2 Composition

Catalysis Letters - The NdM0.25Ni0.75O3 (M?=?Cr, Fe) named NCN and NFN catalysts precursors were synthesized and characterized. The CO2 utilization in the feed was studied in the...