The first measurement of an absolute surface concentration of reaction intermediates in ethylene hydrogenation

The first measurement of a turnover rate with respect to surface intermediate concentration in a high pressure heterogeneous catalytic reaction is reported. By using infrared-visible sum frequency generation to study the hydrogenation of ethylene on Pt(111), it was found that the surface concentration of -bonded ethylene, the key reaction intermediate, represented approximately 4% of a monolayer. Thus the absolute turnover rate per surface adsorbed ethylene molecule is 25 times faster than the rate measured per platinum atom. To explain these results, we propose a model of weakly adsorbed ethylene intermediates reacting on atop sites.     

Jordan surfaces in simply connected digital spaces

Certain tasks in multidimensional digital image analysis, in particular surface detection and volume estimation, lead us to the study of surfaces in the digital environment. It is desirable that these surfaces should have a Jordan property analogous to that of simple closed curves in two dimensions-namely, that they should partition the underlying space into an inside and an outside which are disconnected from each other. A version of this property, called near-Jordanness, has been previously defined and has been shown to be useful within a general theory of surfaces in digital spaces. The definition of a near-Jordan surface is global: it demands that all paths from the interior to the exterior cross the surface. This makes it difficult in many practical applications to check whether surfaces are near-Jordan. The work reported in this paper is motivated by the desire for a local condition, such that if a surface satisfies this condition at each of its elements, then it is guaranteed to be near-Jordan. In the search for such a condition, we were led to a concept of simple connectedness of a digital space, which resembles simple connectedness in ordinary topological spaces. We were then able to formulate the desired local condition for simply connected digital spaces. Many digital spaces, in particular those based on the commonly-studied tessellations of n-dimensional Euclidean space, are shown to be simply connected and thus our theory yields general sufficient conditions for boundaries in binary pictures to be near-Jordan.     

Approximating Euclidean circles by neighbourhood sequences in a hexagonal grid

In this paper the nodes of the hexagonal grid are used as points. There are three types of neighbours on this grid, therefore neighbourhood sequences contain values 1, 2, 3. The grid is coordinatized by three coordinates in a symmetric way. Digital circles are classified based on digital distances using neighbourhood sequences. They can be triangle, hexagon, enneagon and dodecagon. Their corners and side-lengths are computed, such as their perimeters and areas. The radius of a digital disk is usually not well-defined, i.e., the same disk can have various radii according to the neighbourhood sequence used. Therefore the non-compactness ratio is used to measure the quality of approximation of the Euclidean circles. The best approximating neighbourhood sequence is presented. It is shown that the approximation can be improved using two neighbourhood sequences in parallel. Comparisons to other approximations are also shown.     

A heuristic method for the vehicle routing problem with mixed deliveries and pickups

The vehicle routing problem with deliveries and pickups is a challenging extension to the vehicle routing problem that lately attracted growing attention in the literature. This paper investigates the relationship between two versions of this problem, called “mixed” and “simultaneous”. In particular, we wish to know whether a solution algorithm designed for the simultaneous case can solve the mixed case. To this end, we implement a metaheuristic based on reactive tabu search. The results suggest that this approach can yield good results.     

Common coupling and pointer variables,with application to a Linux case study

Both common coupling and pointer variables can exert a deleterious effect on the quality of software. The situation is exacerbated when global variables are assigned to pointer variables, that is, when an alias to a global variable is created. When this occurs, the number of global variables increases, and it becomes considerably harder to compute quality metrics correctly. However, unless aliasing is taken into account, variables may incorrectly appear to be unreferenced (neither defined nor used), or to be used without being defined. These ideas are illustrated by means of a case study of common coupling in the Linux kernel.

Candide's Practical Principles of Experimental Pattern Recognition

This correspondence calls attention to several frequently used assumptions and techniques culled from the pattern recognition literature.     

Synthesis and characterization of ET(P)S-4 and ET(P)S-10

Phosphorus containing ET(P)S-4 and ET(P)S-10 were synthesized from gels of composition xNa₂O–0.6KF–0.2TiO₂–(1.28 − 4y)xHCl–yP₂O₅–1.49SiO₂–39.5H₂O at 190 °C for 3 days. The XRD patterns are almost identical to the corresponding ETS samples. The presence of phosphorus in the initial gel influences the kinetic parameters of the crystallization process, the morphology and the size of the crystals. The ³¹P-NMR of the samples show that part of the phosphorus is attached at the siliceous surface as dihydrogenophosphate SiOPO(OH)₂ groups and cannot be introduced in a tetrahedral or octahedral framework position.     

Influence of inhomogeneous static magnetic field-exposure on patients with erosive gastritis: a randomized,self- and placebo-controlled,double-blind,single centre,pilot study

This pilot study was devoted to the effect of static magnetic field (SMF)-exposure on erosive gastritis. The randomized, self- and placebo-controlled, double-blind, pilot study included 16 patients of the 2nd Department of Internal Medicine, Semmelweis University diagnosed with erosive gastritis. The instrumental analysis followed a qualitative (pre-intervention) assessment of the symptoms by the patient: lower heartburn (in the ventricle), upper heartburn (in the oesophagus), epigastric pain, regurgitation, bloating and dry cough. Medical diagnosis included a double-line upper panendoscopy followed by 30 min local inhomogeneous SMF-exposure intervention at the lower sternal region over the stomach with peak-to-peak magnetic induction of 3 mT and 30 mT m⁻¹ gradient at the target site. A qualitative (post-intervention) assessment of the same symptoms closed the examination. Sham- or SMF-exposure was used in a double-blind manner. The authors succeeded in justifying the clinically and statistically significant beneficial effect of the SMF- over sham-exposure on the symptoms of erosive gastritis, the average effect of inhibition was 56% by p = 0.001, n = 42 + 96. This pilot study was aimed to encourage gastroenterologists to test local, inhomogeneous SMF-exposure on erosive gastritis patients, so this intervention may become an evidence-based alternative or complementary method in the clinical use especially in cases when conventional therapy options are contraindicated.