A global approach to the physics validation of simulation codes for future nuclear systems

This paper presents a global approach to the validation of the parameters that enter into the neutronics simulation tools for advanced fast reactors with the objective to reduce the uncertainties associated to crucial design parameters. This global approach makes use of sensitivity/uncertainty methods; statistical data adjustments; integral experiment selection, analysis and “representativity” quantification with respect to a reference system; scientifically based cross-section covariance data and appropriate methods for their use in multigroup calculations. This global approach has been applied to the uncertainty reduction on the criticality of the Advanced Burner Reactor (both metal and oxide core versions) presently investigated in the frame of the GNEP initiative. The results obtained are very encouraging and allow to indicate some possible improvements of the ENDF/B-VII data file.     

Fast Separation of Capsaicinoids from Peppers by Reversed Phase Ultra-Performance Liquid Chromatography: Comparation with Traditional High-Performance Liquid Chromatography Methods

A new chromatographic method for the separation of major capsaicinoids in peppers has been developed. Nordihydrocapsaicin, capsaicin, dihydrocapsaicin, homocapsaicin, and homodihydrocapsaicin have been separated by reversed-phase ultra-performance liquid chromatography. A gradient method has been developed using two solvents: 0.1% acetic acid in water and 0.1% acetic acid in methanol. The developed method allows the full separation of capsaicinoids in less than 3 min, with high reproducibility (relative standard deviation < 4.3%) and repeatability (relative standard deviation < 3.6%). Robustness regarding the total amount of methanol in the sample was determined. Comparison with previous reversed-phase high-performance liquid chromatography methods using both monolithic and conventional columns was also studied. Finally, the method was applied in the determination of major capsaicinoids in 16 hot pepper samples produced in Spain.     

Restarted Iterated Pareto Greedy algorithm for multi-objective flowshop scheduling problems

Multi-objective optimisation problems have seen a large impulse in the last decades. Many new techniques for solving distinct variants of multi-objective problems have been proposed. Production scheduling, as with other operations management fields, is no different. The flowshop problem is among the most widely studied scheduling settings. Recently, the Iterated Greedy methodology for solving the single-objective version of the flowshop problem has produced state-of-the-art results. This paper proposes a new algorithm based on Iterated Greedy technique for solving the multi-objective permutation flowshop problem. This algorithm is characterised by an effective initialisation of the population, management of the Pareto front, and a specially tailored local search, among other things. The proposed multi-objective Iterated Greedy method is shown to outperform other recent approaches in comprehensive computational and statistical tests that comprise a large number of instances with objectives involving makespan, tardiness and flowtime. Lastly, we use a novel graphical tool to compare the performances of stochastic Pareto fronts based on Empirical Attainment Functions.     

The ideal reporting interval for an epidemic to objectively interpret the epidemiological time course

The reporting interval of infectious diseases is often determined as a time unit in the calendar regardless of the epidemiological characteristics of the disease. No guidelines have been proposed to choose the reporting interval of infectious diseases. The present study aims at translating coarsely reported epidemic data into the reproduction number and clarifying the ideal reporting interval to offer detailed insights into the time course of an epidemic. We briefly revisit the dispersibility ratio, i.e. ratio of cases in successive reporting intervals, proposed by Clare Oswald Stallybrass, detecting technical flaws in the historical studies. We derive a corrected expression for this quantity and propose simple algorithms to estimate the effective reproduction number as a function of time, adjusting the reporting interval to the generation time of a disease and demonstrating a clear relationship among the generation-time distribution, reporting interval and growth rate of an epidemic. Our exercise suggests that an ideal reporting interval is the mean generation time, so that the ratio of cases in successive intervals can yield the reproduction number. When it is impractical to report observations every mean generation time, we also present an alternative method that enables us to obtain straightforward estimates of the reproduction number for any reporting interval that suits the practical purpose of infection control.     

Silicon Encapsulated Carbon Nanotubes

A dual stage process of depositing bamboo-like carbon nanotubes (BCNTs) by hot filament chemical vapor deposition (HFCVD) and coating Si using Radio frequency sputtering (RFS) technique. The films were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and electron field emission studies (EFE). SEM results suggest a dense network of homogeneous silicon-coated BCNTs. From the comprehensive analysis of the results provided by these techniques emerges the picture of Si encapsulated BCNTs.     

Cyclic bond behaviour of plain bars. Part I: Experimental investigation

In recent years there has been wide use of non-linear dynamic analysis for the evaluation of existing structures in areas of high seismic risk. In the simulation of the cyclic behaviour of elements in reinforced concrete (RC) its bonding performance cannot be ignored. There are numerous numerical models developed in recent decades which can explicitly account for the slip between reinforcing bars and the surrounding concrete through the definition of the local hysteretic bond–slip relationship. As for plain bars, commonly used in reinforced concrete buildings before the 1970s, there are almost no references to hysteretic bond mechanisms.This paper describes the results of a series of monotonic and cyclic pull-out tests aimed at the assessment of the bond performances of plain round bars. Monotonic behaviour is characterized by a first ascending branch, up to the maximum bond strength; in this phase, as the slip increases, chemical–physical adhesion and micro-interlocking between the cement paste and the indentations of the bar surface progressively activate. During post-peak phase the only frictional contribute is present, gradually degrading towards a minimum value as the slip increases. The two parameters, maximum bond strength and minimum frictional bond, in spite of the high variability shown, seem to reflect well the literature indications about bond performances of plain bars. In cyclic field, where the only frictional mechanism is present, experimental results show a significant degradation of bond capacities. Hysteretic cycles show a singular shape, characterized by a reloading phase showing a slight reduction for slip values approaching zero and a subsequent increase in bond stress towards the maximum imposed slip. Bond stresses in cyclic field show a high variability, but it is generally possible to recognize a decreasing trend both with the number of cycles and with the maximum imposed slip.     

Experimental Analysis of Approximation Algorithms for the Vertex Cover and Set Covering Problems

Several approximation algorithms with proven performance guarantees have been proposed to find approximate solutions to classical combinatorial optimization problems. However, theoretical results may not reflect the experimental performance of the proposed algorithms. As a consequence, a question arises: how “far” from the theoretically proved performance are the experimental results? We conduct a controlled empirical study of approximation algorithms for the Vertex Cover and the Set Covering Problems. Many authors have proposed approximation algorithms for those problems. Our main goal is to better understand their strengths, weaknesses, and operation. Although we implement more than one algorithm to find feasible solutions to either problems, this work does not emphasize competition between them. The quality of the solutions related to the theoretical performance guarantees are analyzed instead. The computational experiments showed that the proven performance guarantees of all tested algorithms did not forecast well the empirical performance.     

The influence of CaCl2 on the crystallization of calcium silicates in autoclave hydration of C3S

The influence of CaCl₂ on the autoclave hydration C₃S (5 hours at 190°C) after different precuring times (0–16 hours) at room temperature has been studied. The addition of calcium chloride retards the autoclave hydration of C₃S and prevents completely the formation of the crystalline hydrated silicates (-C₂SH and C₃SH_1.5). This result has been compared with that observed in the ball-mill hydration of C₃S in the presence of CaCl₂, i.e., the complete absence of crystalline afwillite.

Abstract

On a étudié l'influence du CaCl₂ sur l'hydratation en autoclave du C₃S (5 heures à 190°C) après différents temps de conservation (0–16 heures à température ambiante. L'addition de chlorure de calcium retarde l'hydratation en autoclave du C₃S et empêche complétement la formation des silicates cristallins hydratés -C₂SH et C₃SH_1.5. Ce résultat a été comparé avec le phenomene observé en étudiant l'hydration du C₃S dans un moulin à boulets en presence de CaCl₂, c'est à dire la disparition complète du composé crystallin afwillite.