全文获取类型
收费全文 | 24047篇 |
免费 | 1921篇 |
国内免费 | 902篇 |
专业分类
电工技术 | 1157篇 |
技术理论 | 5篇 |
综合类 | 1333篇 |
化学工业 | 4324篇 |
金属工艺 | 1606篇 |
机械仪表 | 1447篇 |
建筑科学 | 1794篇 |
矿业工程 | 676篇 |
能源动力 | 778篇 |
轻工业 | 1586篇 |
水利工程 | 367篇 |
石油天然气 | 1647篇 |
武器工业 | 150篇 |
无线电 | 2441篇 |
一般工业技术 | 3042篇 |
冶金工业 | 1373篇 |
原子能技术 | 251篇 |
自动化技术 | 2893篇 |
出版年
2024年 | 121篇 |
2023年 | 479篇 |
2022年 | 722篇 |
2021年 | 1006篇 |
2020年 | 828篇 |
2019年 | 693篇 |
2018年 | 803篇 |
2017年 | 824篇 |
2016年 | 711篇 |
2015年 | 960篇 |
2014年 | 1144篇 |
2013年 | 1551篇 |
2012年 | 1494篇 |
2011年 | 1569篇 |
2010年 | 1378篇 |
2009年 | 1316篇 |
2008年 | 1256篇 |
2007年 | 1214篇 |
2006年 | 1289篇 |
2005年 | 1116篇 |
2004年 | 683篇 |
2003年 | 634篇 |
2002年 | 584篇 |
2001年 | 468篇 |
2000年 | 536篇 |
1999年 | 651篇 |
1998年 | 550篇 |
1997年 | 410篇 |
1996年 | 397篇 |
1995年 | 332篇 |
1994年 | 273篇 |
1993年 | 189篇 |
1992年 | 156篇 |
1991年 | 107篇 |
1990年 | 88篇 |
1989年 | 49篇 |
1988年 | 66篇 |
1987年 | 41篇 |
1986年 | 29篇 |
1985年 | 32篇 |
1984年 | 28篇 |
1983年 | 16篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 13篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1974年 | 3篇 |
1959年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
A simple method has been devised for immobilization of acetylcholinesterase (AChE) covalent bonding to a multiwall carbon
nanotube (MWNT)-cross-linked cellulose acetate composite on a screen-printed carbon electrode (SPCE) and a sensitive and disposable
amperometric sensor for rapid determination of carbaryl pesticide is proposed. The immobilized enzyme was preserved on this
film because of the excellent biocompatibility and non-toxicity of cellulose acetate. Based on the inherent conductive properties
of the MWNT, the immobilized AChE had greater affinity for ATCl and excellent catalytic effect in the hydrolysis of ATCl.
MWNT improved the interface enzymatic hydrolysis reaction and increased the amperometric response of the sensor. Under optimum
conditions, the inhibition of carbaryl on AChE increased linearly with the increasing concentration of carbaryl in two ranges,
from 0.01 to 0.5 μg mL−1 and from 2 to 20 μg mL−1, with the correlation coefficients of 0.9985 and 0.9977, respectively. The detection limit was 0.004 μg mL−1 taken as the concentration equivalent to 10% decrease in signal. The sensor showed acceptable stability, accuracy and could
be fabricated in batches, thus it is economic and portable. This type of disposable enzyme-based amperometric sensor has extensive
application potential in environmental monitoring of pesticides. 相似文献
42.
Yongxian Zhao Baochen Huang Wei Yao Hailin Cong Huafeng Shao Aihua Du 《应用聚合物科学杂志》2008,107(5):2986-2993
A new organic‐solvent‐free water‐phase suspension method was used to synthesize partially epoxidized high trans‐1,4‐polyisoprene (TPI) to improve its properties, including oil resistance and wet‐skid resistance. The epoxidation was conducted in an aqueous peracetic acid solution and on the TPI granules prepared by a bulk precipitation method with supported titanium catalyst. The effects of the synthesis conditions, including reaction temperature, reaction time, and pH value, on the epoxy content were investigated. Epoxidized trans‐1,4‐polyisoprene (ETPI) with epoxy contents between 10 and 80% were obtained within 4 h. Both the amorphous and crystalline regions of TPI were epoxidized. The crystallization properties decreased with increasing epoxy content. ETPIs possessed lower mechanical properties than TPI but could be enhanced by vulcanization. The oil resistance and wet‐skid resistance were significantly improved after epoxidation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
43.
安阳九天化工集团甲胺/DMF(二甲基甲酰胺)工程是河南省重点建设项目.装置采用先进的甲醇和液氨气相催化胺化法生产混甲胺.一期工程30 kt/a 甲胺/DMF装置于2003年10月建成投产,其合成催化剂选用的是上海石化研究院生产的A-6A甲胺合成催化剂,从投产到现在,合成催化剂共更换了4次,催化剂平均使用寿命为13个月,共生产混甲胺112 kt,达到国内领先水平. 相似文献
44.
以某公司焦化厂焦化DCS控制系统为例,从DCS系统的选型、设计、实施等几方面。阐述焦化DCS控制系统的设计与实现。 相似文献
45.
In order to find out rapidly the causes of the liver diseases suffered by patients with negative hepatitis B surface antigen (HBsAg), nested polymerase chain reaction (PCR) and multiple cloned antibody capture PCR techniques were established to examine serum hepatitis B virus (HBV) DNA. By using both techniques along with the examination of hepatitis C virus (HCV) infection, the causes of chronic liver diseases with negative HBsAg were studied. It is found that nested-PCR can increase the sensitivity of single PCR more than 1,000 fold and multiple cloned antibody capture-PCR can detect concentration of HBV DNA as low as 0.1-0.01 pg/L. HBV DNA positive patients were found in 45.5%, 30.8%, 13.3% and 100% respectively of the patients suffering from liver cirhosis with negative HBsAg (group A, 22 cases), chronic hepatitis with negative HBsAg (group B, 13 cases), normal subjects with negative HBsAg and positive hepatitis B core antibody (HBcAb, group C, 30 cases) and liver cirhosis with positive HBsAg and negative HBeAg (group D, 12 cases). HBV DNA can be also found in the serum of HBsAb positive patients and subjects supposed to be healthy, 81.8% and 53.8% of the patients were infected with HBV and/or HCV in group A and group B respectively. All these results suggest that nested-PCR and multiple cloned antibody capture-PCR are rapid and highly sensitive methods for detection of serum HBV DNA. HBV infection is an important cause of chronic liver diseases in patients with negative HBsAg. The causes of most of the HBsAg-negative chronic liver diseases are related with infection of viruses. The clinical significance of serum HBsAb in naturally infected patients should be reconsidered. 相似文献
46.
47.
一种按时间切换的最速控制方法 总被引:3,自引:1,他引:2
基于初始状态空间下的子空间概念,提出了一种按时间进行切换的最速控制方法,不需要求取开关线或开关面。数字仿真结果表明,采用这一方法是完全可行的。 相似文献
48.
B. Gerharz A. Du Chesne G. Lieser E. W. Fischer W. Z. Cai 《Journal of Materials Science》1996,31(4):1053-1063
The microphase structure of a series of poly (styrene-b-methylphenylsiloxane) (PS-b-PMPS)-diblock copolymers with various compositions and molecular weights has been studied by small-angle X-ray scattering, electron spectroscopic imaging and solid-state nuclear magnetic resonance spectroscopy. This diblock copolymer system is miscible within a distinct range of temperature and molecular weight exhibiting an upper critical solution temperature. The three chosen methods which complement each other can be applied to the chemically unmodified model system. The results of the various measurements correlate to describe the microphase structure, the domain size and the interphase. 相似文献
49.
本文扼要地论述了威远构造从30年代到60年代震旦系最古老气藏发现的漫长历史,以及直到90年代初震旦系天然气勘探重新获得突破的曲折过程。这一历史过程,也是四川盆地复杂碳酸盐岩裂缝性气藏勘探的剪影。 相似文献
50.