Ni,Cr, and Fe surfaces corroded by molten ZnCl2

Understanding the corrosion of molten ZnCl₂ on metal surfaces is significant for the corrosion protection of metals, sustainable use of molten salts, preparation of ZnO coatings, and so on. In this paper, surfaces of pure Ni, Cr, and Fe corroded by molten ZnCl₂ were investigated. The results show that Ni suffered very slight corrosion, while Cr experienced more serious corrosion than Ni, but lighter corrosion than Fe. The morphology of the corrosion of Cr and Fe, respectively, presented pitting and intergranular corrosion characteristics. Furthermore, nanostructured ZnO coatings were obtained on the surfaces of Ni and Fe, but not on the surface of Cr. The ZnO coating on the Ni surface was doped with a small amount of Zn₅(OH)₈Cl₂, and the ZnO coating on the Fe surface was doped with ZnFe₂O₄ and Zn₂OCl₂. The coatings on the Ni and Fe surfaces had an average thickness of 1.5 and 50 μm, respectively.     

基于Q-learning的不确定环境BDI Agent最优策略规划研究

BDI模型能够很好地解决在特定环境下的Agent的推理和决策问题,但在动态和不确定环境下缺少决策和学习的能力。强化学习解决了Agent在未知环境下的决策问题,却缺少BDI模型中的规则描述和逻辑推理。针对BDI在未知和动态环境下的策略规划问题,提出基于强化学习Q-learning算法来实现BDI Agent学习和规划的方法,并针对BDI的实现模型ASL的决策机制做出了改进,最后在ASL的仿真平台Jason上建立了迷宫的仿真,仿真实验表明,在加入Q-learning学习机制后的新的ASL系统中,Agent在不确定环境下依然可以完成任务。     

Facile construction of composition-tuned ruthenium-nickel nanoparticles on g-C3N4 for enhanced hydrolysis of ammonia borane without base additives

Developing high-efficiency and low-cost catalysts for hydrogen evolution from hydrolysis of ammonia borane (AB) is significant and critical for the exploitation and utilization of hydrogen energy. Herein, the in-situ fabrication of well-dispersed and small bimetallic RuNi alloy nanoparticles (NPs) with tuned compositions and concomitant hydrolysis of AB are successfully achieved by using graphitic carbon nitride (g-C₃N₄) as a NP support without additional stabilizing ligands. The optimized Ru₁Ni_7.5/g-C₃N₄ catalyst exhibits an excellent catalytic activity with a high turnover frequency of 901 min^?1 and an activation energy of 28.46 kJ mol^?1 without any base additives, overtaking the activities of many previously reported catalysts for AB hydrolysis. The kinetic studies indicate that the AB hydrolysis over Ru₁Ni_7.5/g-C₃N₄ is first-order and zero-order reactions with respect to the catalyst and AB concentrations, respectively. Ru₁Ni_7.5/g-C₃N₄ has a good recyclability with 46% of the initial catalytic activity retained even after five runs. The high performance of Ru₁Ni_7.5/g-C₃N₄ should be assigned to the small-sized alloy NPs with abundant accessible active sites and the synergistic effect between the composition-tuned Ru–Ni bimetals. This work highlights a potentially powerful and simple strategy for preparing highly active bimetallic alloy catalysts for AB hydrolysis to generate hydrogen.     

横泉水库大坝土料碾压试验

在取得土料场土料物理力学性质参数的情况下，遵循碾压试验基本原理、方法及参数组合，进行了现场碾压试验，通过试验成果的分析，得出了大坝碾压试验结论，为大坝土方填筑提供了技术依据。     

柯克亚油气田混合来源天然气的地球化学特征

柯克亚油气田是我国开发比较早的一个油气田,但由于受混源和其他因素的影响,对气源的认识众说纷纭。通过对天然气的地球化学特征的分析,并参照国内外关于甲烷、乙烷、丙烷碳同位素关系方面的资料,提出了如下看法:柯克亚天然气碳同位素相对较重,与塔里木盆地下古生界海相天然气的碳同位素组成区别较大;根据天然气40Ar/36Ar组成,柯克亚油气田的气源不是单一来源;柯克亚油气田绝大多数天然气的甲烷和乙烷碳同位素值关系符合Faber推断的 型有机质方程直线关系,说明有机质属于较好的有机质类型,或者是由原油裂解形成的天然气;除了K2井和K18井天然气成熟度较低以外,绝大多数天然气的成熟度大约在1.8%～2.2%之间,属于高过成熟气,但也混有一些成熟度在0.9%～1.2%的源岩形成的天然气;推测天然气主要来源于石炭系―二叠系源岩,而混有成熟度低的源岩形成的天然气则有可能来自侏罗系源岩。     

Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

液压多功能小件落物打捞器的研制与应用

由于侧钻井、水平井特殊井身结构限制，常规的小件落物打捞器打捞成功率低。为此经过认真分析和现场实践，将常规机械操作的一把抓改成液压操作，常规强磁打捞器的圆柱形平面磁铁改成具有伸缩性的磁针，同时结合套铣筒，研制出一种液压多功能小件落物打捞器，克服了侧钻井、水平井井身结构的限制，大大提高了一次打捞成功率，现场应用效果明显。     

重复压裂裂缝转向时油藏数值模拟研究

裂缝转向的实现及选井、选层、优化设计等的数值模拟和机理是转向重复压裂需进一步研究解决的问题,为此,采用黑油模型,研究了在反九点注采井网中,不同储集层渗透率下,转向重复压裂的裂缝穿透率和导流能力等对采油动态的影响。研究表明,不论是渗透率高的地层还是渗透率低的地层,不利裂缝方位的边井最适合实施转向重复压裂且需要比常规重复压裂更大的缝长,而有利裂缝方位的边井和角井只需要与常规重复压裂相当的缝长;同时,转向重复压裂需要比常规重复压裂更高的裂缝导流能力。     

SIMPLIS环境中开关电源集成电路控制器模型的开发及应用

介绍现代开关电源行业仿真工作的意义和现状,以及专用仿真软件包SIM etrix/SIMPLIS的优点和不足。通过实例给出SIMPLIS环境中集成电路控制芯片的建模过程,并就其中的关键技术予以简单讨论。     

没有SDC的(t，n)门限秘密共享方案

利用椭圆曲线离散问题对数问题的难解性,给出了基于椭圆曲线密码体制的(t,n)门限秘密共享方案。基于门限秘密共享方案一般分为需要SDC和不需要SDC两类,在分布式环境下,一个被所有成员信任的SDC并不存在,不需要SDC的门限秘密共享方案的安全性得到很大的提高,该方案中由组成员共同生成群公钥和私有密钥。并给出了当新成员加入时,无SDC下的周期密钥分片的更新方案。还给出了一个本方案数据实例,最后对本方案的安全性进行了分析。