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11.
Xiaojun Hu Hiroyuki Matsuura Fumitaka Tsukihashi 《Metallurgical and Materials Transactions B》2006,37(3):395-401
The interfacial reaction between CO2-CO gas and molten iron oxide containing P2O5 was investigated by the 13CO2-CO isotope exchange technique at 1773 K with CO2/CO=1.0. The apparent rate constant rapidly decreased with the addition of P2O5 up to 2.86 mol pct PO2.5 and the Fe3+/Fe2+ ratio kept constant at approximately 0.2. By the classic site blockage model, in which the reaction only occurs on the vacant
sites, and the modified site blockage model, in which the reaction occurs on the vacant sites and the sites occupied by phosphorus
simultaneously, the effect of the addition of P2O5 was analyzed and the reaction mechanism of CO2 dissociation was discussed. It may be concluded that the dissociation of the adsorbed CO2 molecule is reasonable as a rate-determining step and that the effect of phosphorus on the interfacial reaction is caused
by the decrease in the number of active sites with the increase of phosphorus content as a surface active element in molten
iron oxide. 相似文献
12.
The effect of Zr on reduction of hardness and microstructure in an FS weld of equal channel angular-pressed Al alloy was investigated. Zr addition to Al suppressed dynamic recovery in the thermomechanically affected zone and enabled retention of the high hardness of the ECA-pressed material throughout the weld. 相似文献
13.
14.
Hiroyuki Miki Takanori Takeno Toshiyuki Takagi Alexei Bozhko Mikhail Shupegin Hideya Onodera Takao Komiyama Takashi Aoyama 《Diamond and Related Materials》2006,15(11-12):1898
Superconductivity in a tungsten-containing carbon-oxide film was reported. The film with 500 nm thickness was deposited onto polycrystalline silicon oxides using chemical vapor deposition and the co-sputtering of a tungsten metal target. The bonding state of the carbon atoms and the macroscopic and microscopic crystal structure of the film were investigated by Raman spectroscopy, X-ray diffraction and transmission electron microscopy measurements. From the experimental results, we determined that this film essentially had an amorphous structure. The temperature dependence on resistivity was measured in the temperature range of 2–300 K. Resistive superconducting transition was observed at 3.8 K. The dc magnetizations were measured in the temperature range of 1.8–6.5 K. The diamagnetism resulting from a superconductive state was observed below 3.75 K, which is consistent with a resistive superconducting transition. It is thought that the finite sized clusters of the different superconductive transition temperatures cooperatively produce a macroscopic superconducting phenomenon. 相似文献
15.
本文采用粒子追踪理论对水平管中粒子流动状态进行了数值模拟.文中提出了一种新的粒子碰撞模型,并忽略粒子的旋转和扬力,仅考虑气流阻力和重力对粒子的影响,在输送量为9.13×10~3kg/s,混合比约0.3的条件下,通过数值计算得知:由于粒子间的碰撞,使得异径粒子的速度趋向平均化;粒子间的碰撞是粒子悬浮的原因之一;粒子的浓度沿管轴向是随时间而发生变化的. 相似文献
16.
Tsutomu Takeichi Yuki Saito Tarek Agag Hiroyuki Muto Takehiro Kawauchi 《Polymer》2008,49(5):1173-1179
Two series of high-performance polymer alloys were prepared by mixing typical benzoxine monomers, 3-phenyl-3,4-dihydro-2H-1,3-benzoxazine (P-a) or 6,6-(1-methylethyliden)-bis-(3,4-dihydro-3-phenyl-2H-1,3-benzoxazine) (B-a), with a typical bismaleimide, 4,4-bismaleimidodiphenyl methane by various ratios followed by thermal treatment up to 240 °C. DSC and IR of the alloys were examined to follow the curing reaction. These analyses showed that the obtained polymer alloys are AB co-cross-linked polymer networks through the formation of ether linkage between the hydroxyl group of polybenoxazine and the double bond of bismaleimide. Viscoelastic analysis and softening temperature measurement revealed that the polymer alloys have much higher glass transition temperatures than those of each homopolymer. The thermal stability also increased with the increase of bismaleimide content as evidenced by TGA. 相似文献
17.
The critical conditions in which the classical Flory-Stockmayer gelation theory (F-S theory) is applicable to monovinyl-divinyl copolymerizations were pursued in detail. The resulting prepolymers or precursors of ideal crosslinked-polymers were characterized as standard polymers for the discussion of network formation in free-radical monovinyl-divinyl copolymerizations. Methyl methacrylate was copolymerized with a small amount of ethylene dimethacrylate, butylene dimethacrylate or nonapropyleneglycol dimethacrylate in the presence of lauryl mercaptan, a chain transfer agent to reduce the occurrence of a thermodynamic excluded volume effect and intramolecular crosslinking as the primary and secondary factors, respectively, for the greatly delayed gelation in the free-radical monovinyl-divinyl copolymerizations and, moreover, to keep the primary chain length constant by inhibiting a gel effect. The ratio of the actual gel point to the theoretical one reached 1.1, supporting the validity of F-S theory. The resulting prepolymers were subjected to SEC-MALLS analysis to determine the molecular weights, the molecular-weight distributions and the radii of gyration; the correlations of molecular weight vs. elution volume and radius of gyration vs. molecular weight were useful for the characterization of the precursors of ideal network-polymers. 相似文献
18.
Hiroyuki Nakahira Masakatsu Maruyama Hideshi Ueda Haruyasu Yamada 《The Journal of VLSI Signal Processing》1993,5(2-3):133-140
This paper describes an image processing system using Image Signal Multiprocessors (ISMPs) adapted to gray-level image preprocessing for image analysis and image enhancement. It is composed of four ISMPs, five 1H-delay-lines, two 512×512×8-bit frame memories, a video timing controller (VTC), two 256-word ×8-bit ×8-table Look Up Tables (LUTs) and 80 nsec/sampling A/D and D/A converters. This multiprocessor system performs convolution operations such as spatial filters, contrast enhancement, and binarization for gray-level images, thinning, thickening, pattern matching etc. for binary images, and image quality improvement for moving images such as T.V. images. Otherwise, it performs feature extraction operations such as area calculations, fillet coordination, and moment calculations for objective image data. Moreover, this system is capable of applying color image processing by using a multiboard system. 相似文献
19.
Hiroyuki Kumano Akio SaitoSeiji Okawa 《International Journal of Heat and Mass Transfer》2002,45(7):1467-1475
The direct contact melting of a porous material is investigated experimentally and analytically. The phase change material (PCM) is made of fine ice particles of a nearly uniform diameter, which is changed as a parameter. In the analysis, two models are proposed. One is calculated as the direct contact melting of a monolithic sample and another is treated as an assembly of the direct contact melting of the individual particles. As a result, it was found that the heat flux increased with the diameter, due to increase of permeability in a case of small diameter. But, in a case of large diameter, the heat flux decreased as the particle diameter increased because the direct contact melting occurred independently for the individual particles. 相似文献
20.
A phytoplankton model, which includes a carbon cycle combined with a constant current obtained by the computation of tidal currents, was applied to the coastal region (Hiroshima Bay, Japan). The transformation rate constants for the carbon cycle were experimentally evaluated.The seasonal variations of particulate and dissolved organic matter by the simulation model were reasonably consistent with the field data. Carbon concentration increased by primary production in the upper layer was approx. 10 times that augmented by loading of carbon from land at the shore in summer. Sinking plays an important role in the elimination of particulate organic matter. On the other hand, horizontal advection and turbulent diffusion are important factors for the diminution of dissolved organic matter. 相似文献