Corrosion resistance of structural materials in high-temperature aqueous sulfuric acids in thermochemical water-splitting iodine–sulfur process

Very harsh environments exist in the iodine–sulfur process for hydrogen production. Structural materials for sulfuric acid vaporizers and concentrators are exposed to high-temperature corrosive environments. Immersion tests were carried out to evaluate the corrosion resistance of ceramics and to evaluate corrosion-resistant metals exposed to environments of aqueous sulfuric acids at temperatures of 320, 380, and 460 °C, and pressure of 2 MPa. The aqueous sulfuric acid concentrations for the temperatures were 75, 85, and 95 wt%, respectively. Ceramic specimens of silicon carbides (SiC), silicon-impregnated silicon carbides (Si–SiC), and silicon nitrides (Si₃N₄) showed excellent corrosion resistance from weight loss measurements after exposure to 75, 85, and 95 wt% sulfuric acid. High-silicon irons with silicon content of 20 wt% showed a fair measure of corrosion resistance. However, evidence of crack formation was detected via microscopy. Silicon enriched steels severely suffered from uniform corrosion with a corrosion rate in 95 wt% sulfuric acid of approximately 1 g m⁻² h⁻¹. Among the tested materials, the ceramics SiC, Si–SiC, and Si₃N₄ were found to be suitable candidates for structural materials in direct contact with the considered environments.     

Structural and magnetic properties of Lix(MnyFe1−y)PO4 electrode materials for Li-ion batteries

A series of LiMn_yFe_1−yPO₄ samples have been prepared in the whole range 0 ≤ y ≤ 1. Chemical delithiation could be achieved to obtain Mn_yFe_1−yPO₄ in the range 0 ≤ y ≤ 0.8, keeping the same crystal phase (olivine structure, space group Pnma). The composition y = 0.8 is the limit where the delithiated phase is still crystallized, but abruptly suffers strains at the molecular scale evidenced by both optical spectroscopy and X-ray diffraction. The analysis of the magnetic properties shows that in all the samples the concentration of impurities is negligible. The concentration of polarons, either holes associated to Li vacancies in LiMn_yFe_1−yPO₄ or electrons associated to the existence of Li left in the matrix of Mn_yFe_1−yPO₄, is found to be small (≤1%) in all the samples. For y ≤ 0.6, all the Mn³⁺ ions Mn_yFe_1−yPO₄ are in the high-spin state (S = 2). At larger manganese concentration, however, the Mn³⁺ ions in excess of the critical concentration y_c = 0.6 undergo a transition to the low-spin state (S = 1). As a consequence, and in contrast with prior works, we find that Mn_0.8Fe_0.2PO₄ has magnetic interactions that are much smaller, and no antiferromagnetic ordering in this compound is detected, at least above 20 K. Antiferromagnetic ordering that had been reported so far for Mn_yFe_1−yPO₄ at large y-composition might come from incomplete delithiation. The spin-transition of Mn³⁺ in concentration (y–y_c) to the low-spin state is at the origin of the strain fields at the molecular scale that increase with y for y > 0.6, and ultimately prevents the full delithiation for y > 0.8. This result sheds light on the reason for the degradation of cathode properties in Mn-rich compounds of the heterosite–purpurite series, while the electrochemical properties are good in the range y ≤ 0.6 but only at slow rates, due to the very small hopping mobility of the small polaron.     

Use of multivariate analysis for the improvement in prediction accuracy of bacterial aerobic plate count by flow cytometry

Flow cytometry (FCM) and aerobic plate count (APC) by the culture method were performed on green tea samples spiked with Escherichia coli type strain NCTC9001 (ATCC11775) solutions of different concentrations. In FCM, fluorescence signals from multiple stained bacteria and other fluorophores are detected using detector channels, and recorded as events with a voltage at each channel. FCM data were analyzed in two ways: conventional and multivariate analysis. In the former, the number of events with voltages larger than the defined threshold values was regarded as the predicted APC. In the latter, voltage histograms of all channels were obtained and merged horizontally to serve as explanatory variables. Then a partial least squares regression (PLSR) model was built to predict APC from the histogram data. The coefficient of determination (R²) and the root mean square error (RMSE) between APC by the culture method and that predicted by conventional FCM were 0.916 and 1.08 cfu/ml². The APC values predicted by the PLSR model and those measured were in good agreement with R² of 0.982 and RMSE of 0.417 cfu/ml, which verified the potential of the proposed method for improving APC prediction accuracy by FCM.     

Performance improvement of the filter-type ‘transXend’ energy-resolving detector by considering noise sensitivity

The filter-type ‘transXend’ detector is an energy-resolving X-ray detector consisting of an energy-integrating flat-panel detector and multiple filters. In our previous studies, we have shown the effectiveness of the transXend detector, but the filters used were not optimized. To obtain better performance, the filters, especially their thickness and material, should be considered. In this paper, we present a method that can preliminarily estimate filter performance by comparing their noise sensitivity before carrying out numerous experiments. Two kinds of filter sets, Cu–Sn and W–Ag, with various thicknesses were evaluated. The results suggest that to image a 20-cm-thick object with 120-kV X-rays, an unfiltered channel and a channel filtered with 0.5-mm-thick Sn or 0.4-mm-thick Ag may be the best combination. The optimal filter thickness will be smaller if the object is thinner and the tube voltage is lower. For applications that require a wide dynamic range of detector response, a channel with a W filter may be better than an unfiltered channel. To verify the calculation results, computed tomography imaging experiments with a 3-cm-diameter phantom were also performed, and the experimental results showed good agreement with the calculation results.     

Experimental studies of optical Raman amplifiers for 1.3‐µm wavelength band and its application to 20 Gbit/s × 2 WDM transmission

Configurations of a Raman amplifier suitable for a 1.3‐µm wavelength band are discussed and their properties are experimentally investigated. Pump light with a wavelength of 1.23 µm that is necessary for the Raman amplification in the 1.3‐µm wavelength band is obtained using a 1.06‐µm fiber laser and Raman laser technique. Concerning the Raman laser, wavelength conversion from 1.06 µm to 1.23 µm is effectively achieved using a cavity configuration including fiber Bragg gratings and a dispersion‐shifted fiber. On the other hand, a conventional dispersion compensation fiber which has an essential property of high nonlinearity is applied in order to obtain large gain at 1.3 µm. Net gain of 35 dB and output power of 15 dBm are achieved. To confirm the applicability of the Raman amplifiers to high‐speed optical transmissions, experiments of 20 Gbit/s × 2 WDM repeaterless transmission through a 80‐km conventional single‐mode fiber are carried out. The 1.3‐µm signal should be degraded due to the dispersion caused by the dispersion compensation fiber in the Raman amplifier; However, bit error rate of less than 10 to 12 is obtained at both wavelengths, which is sufficient performance for practical uses. © 2003 Wiley Periodicals, Inc. Electr Eng Jpn, 143(1): 58–65, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10137     

Application of conventional activated carbon loaded with dispersed Pt to PEFC catalyst layer

Improvement of the polymer electrolyte fuel cell (PEFC) requires development of highly active electrodes of low cost to facilitate its widespread use. In the present study, the possibility of applying conventional activated carbon particles loaded with Pt to the electrode catalyst layer was tested because the particles were promising in dispersion of Pt and preparation cost. The catalyst layer was formed from the particles and Nafion® and was supported as a thin film on a rotating glassy carbon disk electrode (GC RDE). Activity for oxygen reduction was evaluated by the hydrodynamic voltammetry in perchloric acid to give a current free of the influence of mass transfer in the solution. Compared with a conventional catalyst layer formed from carbon black loaded with Pt, the new catalyst layer exhibited a significant, approximately 6-fold increase in current in the high potential region corresponding to a 100 mV increase in electrode potential. Activity, however, was retarded in the low potential region. This disadvantage was overcome by mixing a conductive agent into the layer and covering it with another layer containing carbon black loaded with Pt. This double catalyst layer exhibited increased activity across all potential regions, indicating the availability of the activated carbon in the electrodes.     

Regression of left ventricular hypertrophy prevents ischemia-induced lethal arrhythmias. Beneficial effect of angiotensin II blockade

To evaluate the preventive effect of regression of left ventricular hypertrophy (LVH) on sudden cardiac death (SCD), the incidence of ventricular tachycardia or ventricular fibrillation (VT/Vf) after left coronary artery occlusion in Langendorff preparations was studied in the following five groups: (1) spontaneously hypertensive rats (SHR) without treatment (SHR-N), (2) SHR treated with captopril (SHR-C), (3) SHR treated with the angiotensin II receptor antagonist TCV-116 (SHR-A), (4) SHR treated with hydralazine (SHR-H), and (5) Wistar-Kyoto (WKY) rats. Although blood pressure was equally lowered in all treated groups, SHR-C and SHR-A but not SHR-H showed regression of LVH. The incidence of VT/Vf was 5% in WKY rats, 63% in SHR-N (P < .005 versus WKY rats), 0% in SHR-C, 10% in SHR-A, and 45% in SHR-H (P < .05 versus WKY rats). Further evaluation of the effect of TCV-116 revealed that SHR treated with a low dose of TCV-116 (1 mg/kg per day) showed a decrease in left ventricular mass with only a little decrease in blood pressure and that the incidence of VT/Vf was reduced in association with the degree of regression of LVH. Electrophysiological study using microelectrode techniques revealed that in the LVH groups (SHR-N and SHR-H), the action potential duration (APD) of the left ventricular papillary muscle was more prolonged than in WKY rats, whereas APD shortened to a greater extent during superfusion with a hypoxia/no-glucose solution. APD showed no difference in the regression groups (SHR-C and SHR-A) compared with the WKY group.(ABSTRACT TRUNCATED AT 250 WORDS)     

A research program for dynamic fracture evaluation of Japanese carbon steel pipes

A research program was developed to investigate the dynamic load effect on fracture behavior of Japanese carbon steel STS410 pipe. The program comprises material tests, pipe fracture tests and development of estimation scheme. Material property tests showed that the flow stress was nearly constant or slightly increased with strain rate. Pipe tests showed that fracture load was nearly predicted by the net-section collapse criterion for both quasi-static and dynamic loading. Significant dynamic effect was not observed for STS410 carbon steel piping. Crack growth was well formulated by using J-integral parameter for low cycle fatigue with large scale yielding. Combining the crack growth behavior and unstable fracture criterion, an estimation scheme was newly developed and validated for constant amplitude cyclic loading conditions.     

Electrical conductivity of tetragonal stabilized zirconia

The electrical conductivity change on annealing for tetragonal stabilized zirconia (TZP) was studied with the help of a.c. impedance dispersion analysis techniques. The dependences of the conductivity on annealing time at 1000 ° C and on temperature cycling between room temperature and 1000 ° C were investigated. A decrease in conductivity of about 30% at 1000 ° C of TZP with 3 mol% Y₂O₃ was observed during the first 200 h of annealing at 1000 ° C, and no change was observed during further annealing. A similar result was observed for TZP with 2.9 mol% Sc₂O₃. For TZP with 3.0mol% Yb₂O₃, the conductivity decreased gradually during an annealing time of over 2000 h. The impedance dispersion analysis at lower temperature suggested that the decrease in electrical conductivity by annealing at 1000 ° C could be attributed to the increases of both grain boundary and intragrain resistance. No monoclinic phase was observed for the samples annealed at 1000 ° C for 2000 h. On the other hand, a trace of a monoclinic phase was found for TZP with 3mol% Y₂O₃ after the 50th temperature cycling, but no significant decrease in conductivity was observed with the cycling.