Pervaporation of 50 wt % ethanol–water mixtures with poly(1‐trimethylsilyl‐1‐propyne) membranes at high temperatures

Poly(1‐trimethylsilyl‐1‐propyne) (PTMSP) membranes have been used to separate ethanol–water mixtures by pervaporation. This polyacetylene is known to present high affinity toward ethanol, showing high selectivity and ethanol permeation flux. The performance of this polymer in the separation of alcohol–water solutions has been evaluated over long periods (572 h) at a high temperature (75°C) to examine the deterioration of the transport properties in the separation of 50 wt % ethanol–water solutions. Although PTMSP membranes present good characteristics for the separation of gases and liquid mixtures, their organic selectivity decrease with the operating time because of the relaxation processes of the polymeric chains, which affect the free volume of the polymer, the deterioration being more evident for concentrated solutions. The effects of the operation temperature on the characteristic parameters of pervaporation have also been studied to establish how this variable affects the performance of PTMSP membranes. The selectivity increases slightly with the operation temperature, but the effect of the temperature on the separation factor decreases as membranes are degraded with the operation time. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2843–2848, 2007     

(CO2 + 2‐propanol) mixture as a foaming agent for polystyrene: A simple thermodynamic model for the high pressure VLE‐phase diagrams taking into account the foam vitrification

The equation of state model developed by Lacombe and Sanchez (J Phys Chem 1976, 80, 2352) is used in the form proposed later by Sanchez and Stone (Polymer Blends, Vol. 1: Formulation, 2000; Chapter 2) to correlate experimental vapor‐liquid equilibrium (VLE) data for the three binaries and the ternary systems. Experimental data from the binary systems carbon dioxide‐isopropyl alcohol (CO₂‐IPrOH), isopropyl alcohol‐polystyrene (IPrOH‐PS), and carbon dioxide‐polystyrene (CO₂‐PS) are used to calculate VLE properties for the ternary system CO₂‐IPrOH‐PS. Two‐dimensional VLE‐phase diagrams were calculated and used to describe from a thermodynamic point of view the pressure, volume, and temperature values that characterize a thermoplastic foam evolution process, from the extruder to the foaming die. For different initial mixture CO₂ + IPrOH concentrations, pressure reduction produces liquid foaming until the vitrification curve arrests the final foam volume expansion. The dependence of the vitreous transition with the system CO₂ + IPrOH concentration while foaming is represented by the Chow (Macromolecules 1980, 13, 362) equation. The calculation procedure is proposed as a design tool to reduce the amount of experimental data usually needed as a requirement previous to the design stage. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2663–2671, 2007     

Detection of beeswax adulterations using concentration guide‐values

The concentrations of 102 chemical compounds (saturated and unsaturated hydrocarbons, palmitates, total and free acids, total hydroxyacids, total and free alcohols, acidic monoesters and monoesterified 1,2,3‐propanetriols) have been determined by GC/FID on white and yellow comb beeswax of Apis mellifera from different regions of Spain. Guide‐value ranges are proposed for its characterization and to discriminate adulterated foundation beeswax sheets. The concentrations of many compounds resulted to be statistically different for white and yellow beeswaxes, while the observation of concentrations out of normal in some marketed foundation beeswax sheets suggested their adulteration. However, the measurement of anomalous concentrations in foundation beeswax sheets did not imply necessarily their rejection by the bees.     

Study of the thermomechanical and electrical properties of conducting composites containing natural rubber and carbon black

This work describes the preparation and characterization of composite materials obtained by the combination of natural rubber (NR) and carbon black (CB) in different percentages, aiming to improve their mechanical properties, processability, and electrical conductivity, aiming future applications as transducer in pressure sensors. The composites NR/CB were characterized through optical microscopy (OM), DC conductivity, thermal analysis using differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMA), thermogravimetry (TGA), and stress–strain test. The electrical conductivity varied between 10^?9 and 10 S m^?1, depending on the percentage of CB in the composite. Furthermore, a linear (and reversible) dependence of the conductivity on the applied pressure between 0 and 1.6 MPa was observed for the sample with containing 80 wt % of NR and 20% of CB. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Cure kinetics of a diglycidyl ether of bisphenol a epoxy network (n = 0) with isophorone diamine

The study of the cure reaction of a diglycidyl ether of bisphenol A epoxy network with isophorone diamine is interesting for evaluating the industrial behavior of this material. The total enthalpy of reaction, the glass‐transition temperature, and the partial enthalpies at different curing temperatures have been determined with differential scanning calorimetry in dynamic and isothermal modes. With these experimental data, the degree of conversion and the reaction rate have been obtained. A kinetic model introduces the mechanisms occurring during an epoxy chemical cure reaction. A modification of the kinetic model accounting for the influence of the diffusion of the reactive groups at high conversions is used. A thermodynamic study has allowed the calculation of the enthalpy, entropy, and Gibbs free energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Mechanical and Morphological Studies of Poly(propylene)‐Filled Eggshell Composites

Poly(propylene) (PP) composites were prepared by using eggshell (ES) as filler and their mechanical properties were compared with those using talc (TA) and calcium carbonate (CC) of different grain sizes (X₅₀). A decrease in impact strength and deformation at break with increase in filler content was observed. The PP composite with ES (X₅₀ = 8.4 µm) was stiffer than those with CC (X₅₀ = 0.7 µm). The hybrid composite PP‐ES‐TA showed a similar stiffness as the PP‐TA composites due to the similar morphology of TA (X₅₀ = 0.5 µm) and ES, when TA was replaced up to 75 wt.‐% by ES. SEM study revealed evidence of improved interfacial bonding between PP and ES in theirs composites.

     

EVA Nanocomposites Elaborated with Bentonite Organo‐Modified by Wet and Semi‐Wet Methods

EVA copolymer/organoclay nanocomposites were prepared using melt‐compounding. Organoclays were obtained using wet and semi‐wet modification methods. These methods enable us to obtain organoclays with adequate modifier incorporation, but organoclays with a homogeneous and narrow agglomeration size distribution were obtained only with the wet method. TS and EB were higher for nanocomposites obtained with organoclays prepared using the wet method. Analysis of Limiting Oxygen Index, UL94 test and Cone Calorimeter test showed that the retardant properties of nanocomposites were also influenced by the kind of modifiers and the modification method.

     

Assessment of weld line performance of PP/Talc moldings produced in hot runner injection molds

Weld lines are weak regions in thermoplastic injection moldings caused by low molecular entanglement and unfavorable orientation. Their occurrence may lead to a significantly reduced mechanical performance of the products. Therefore, when weld lines are likely to occur in molded products, they must be taken into account during the mechanical and technological design processes. The weld lines become more critical when particulate fillers are compounded with the polymer. The performance of weld lines in talc‐filled polypropylene box moldings produced with a double‐gated hot runner mold is assessed in this work. The processing conditions were varied in order to cause morphology and tensile‐impact resistance changes. The weld performance at room temperature was assessed in terms of the energy absorbed in the impact tests. It was found that the performance depends on the injection temperature, the injection rate, and the orientation of the talc particles in the weld‐line plane. J. VINYL ADDIT. TECHNOL., 13:159–165, 2007. © 2007 Society of Plastics Engineers     

Modelling of Self-Induced Oscillations in the Mixing Head of a RIM Machine

In this paper, the self-induced oscillations in the mixing head of a RIM machine were modelled. An analytical and simple correlation was derived between the Strouhal number and the averaged pressure drop along the amplitude of the oscillation in the mixing chamber. This correlation theoretically identified that the frequency of the oscillations could be well correlated by the jet Reynolds number, Re_d, and the dimensionless distance between the two jets as proposed by Denshchikov et al., Fluid Dyn. 3 , 460-462 (1983). The flow field dynamics in the mixing head was simulated successfully by Fluent and the computed pressure fluctuations were used to calculate the frequencies of the oscillations in the mixing head. The calculated Strouhal numbers are in good agreement with the dominant frequency from the power spectra of the measured velocity component u_x (Santos, 2003). Finally, the effect of Re_d and Froude number, Fr, on the Strouhal number was investigated in the impingement region. The average Strouhal number showed a decrease with the Reynolds numbers, due to the increasing randomness of flow field in the impingement region. It was also found that the operations at lower values of Fr presented an increasing stability up to the point where the system is unable to present dynamic evolution. The model in this paper provides a theoretical starting point towards understanding of the quantities of the oscillatory flow in the mixing head, as well as a numerical approach to evaluate the dominant frequency in the mixing chamber.     

Proton conductivity in perovskite type yttrium doped barium hafnate

Yttria doped Ba-hafnates were prepared by solid state route and the proton conductivity of pressed samples of yttria doped barium hafnate was determined with impedance spectroscopy. The results are compared with existing data for cerates and zirconates. It was found that Ba-hafnates show a level of proton conduction that is comparable to that of doped Ba-zirconates at low and slightly higher at high temperatures. This is in agreement with the prediction based on the ionic radius of the tetravalent atom in the perovskite.