An Approximation of Volterra Series Using Delay Envelopes, Applied to Digital Predistortion of RF Power Amplifiers With Memory Effects

In this letter, a new model for digital predistortion (DPD) of radio frequency power amplifiers for wide-band applications is proposed. The model is based on a spline approximation of Volterra series by considering second-order cross-terms. The advantage of the spline cross-term model is a reduction in the number of model parameters. We further reduce the model order by operating on delayed envelope samples, rather than the complex baseband samples. A block of wide-band code-division multiple access signal is sent through a 90 W class-AB power amplifier, based on the freescale LDMOS output device, and the input/output baseband samples were used to identify the DPD parameters.     

Raman study of aluminum speciation in simulated alkaline nuclear waste

The chemistry of concentrated sodium aluminate solutions stored in many of the large, underground storage tanks containing high-level waste (HLW) at the Hanford and Savannah River Nuclear Reservations is an area of recent research interest. Not only is the presence of aluminate in solution important for continued safe storage of these wastes, the nature of both solid and solution aluminum oxyhydroxides is important for waste pretreatment. Moreover, for many tanks that have leaked high aluminum waste in the past, little is known about the speciation of Al in the soil. In this study, Raman spectroscopy has been used to investigate the speciation of the aqueous species in the Al2O3-Na2O-H2O system over a wide range of solution compositions and hydration. A ternary phase diagram has been used to correlate the observed changes in the spectra with the composition of the solution and with dimerization of aluminate that occurs at elevated aluminate concentrations (>1.5 M). Dimerization is evidenced by growth of new Al-O stretching bands at 535 and 695 cm(-1) at the expense of the aluminate monomer band at 620 cm(-1). The spectrum of water was strongly influenced by the high concentrations of Na+ and OH- (>17 M). Upon increasing the concentration of NaOH in solution, the delta-(H-O-H) bending band of water (v2 mode) increased in frequency to 1663 cm(-1), indicating that the water contained in the concentrated caustic solution was more strongly hydrogen bonded at the higher base content. In addition, the sharp, well-resolved band at 3610 cm(-1), assigned to the v(O-H) of free OH-, increased in intensity with increasing NaOH. Analysis of the v(O-H) bands in the 3800-2600 cm(-1) region supported the overall increase in hydrogen bonding as evidenced by the increase in relative intensity of a strongly hydrated water band at 3118 cm(-1). Taking into consideration the activity of water, the molar concentrations of the monomeric and dimeric aluminate species were estimated using the relative intensities of the Al-O stretching bands from the Raman spectra. A constant apparent log Kdimer value was obtained at aluminate concentrations >1.5 M with a value of 0.97+/-0.04 at approximately 25 degrees C. This study represents the first spectral-based estimation of a thermodynamic equilibrium constant for the Al2O3-Na2O-H2O system.     

A robust digital baseband predistorter constructed using memory polynomials

Power amplifiers (PAs) are inherently nonlinear devices and are used in virtually all communications systems. Digital baseband predistortion is a highly cost-effective way to linearize PAs, but most existing architectures assume that the PA has a memoryless nonlinearity. For wider bandwidth applications such as wideband code-division multiple access (WCDMA) or wideband orthogonal frequency-division multiplexing (W-OFDM), PA memory effects can no longer be ignored, and memoryless predistortion has limited effectiveness. In this paper, instead of focusing on a particular PA model and building a corresponding predistorter, we focus directly on the predistorter structure. In particular, we propose a memory polynomial model for the predistorter and implement it using an indirect learning architecture. Linearization performance is demonstrated on a three-carrier WCDMA signal.     

Scaling of the discrete-time algebraic Riccati equation to enhancestability of the Schur solution method

A simple scaling procedure for discrete-time Riccati equations is introduced. This procedure eliminates instabilities which can be associated with the linear equation solution step of the generalized Schur method without changing the condition of the underlying problem. A computable bound for the relative error of the solution of the Riccati equation is also derived     

The use of modified divinylbenzene-polystyrene resins in the separation of fermentation products. A case study utilizing amino acids and a dipeptide

The adsorption of phenylalanine, aspartic acid, asparagine and aspartame from phosphate-buffered aqueous solutions with modified divinyl-benzene-polystyrene resins has been investigated using high pressure liquid chromatography (HPLC). The pH studied was 2.8, the temperature range was 293-313 K and the ionic strength was maintained at 1.0 mol dm^?3. Over the range of variables investigated, the adsorption isotherms are linear and may be characterized by temperature and pH-dependent apparent adsorption equilibrium constants, characteristic of the resin-adsorbate system. By studying the dependence on temperature of this adsorption constant, heats of adsorption and entropy of adsorption have been estimated. In terms of the heat liberated on adsorption, the amino acids and a dipeptide can be ranked thus: aspartame > phenylalanine > aspartic acid > asparagine.     

Survival, growth, and thermal resistance of Listeria monocytogenes in products containing peanut and chocolate

Outbreaks of listeriosis associated with the consumption of ready-to-eat foods have raised interest in determining growth, survival, and inactivation characteristics of Listeria monocytogenes in a wide range of products. A study was undertaken to determine the thermal tolerance of L. monocytogenes in a peanut-based beverage (3.1% fat), whole-fat (3.5%) milk, wholefat (4.0%) and reduced-fat (1.0%) chocolate milk, a chocolate-peanut spread (39% fat), and peanut butter (53% fat). The D60 degrees C value (decimal reduction time at 60 degrees C) in peanut beverage (3.2 min) was not significantly different (P > 0.05) than the D60 degrees C value in whole-fat milk (3.3 min) or whole-fat chocolate milk (4.5 min) but significantly lower (P < or = 0.05) than the D60 degrees C value in reduced-fat chocolate milk (5.9 min). The pathogen was significantly more resistant to heat when enmeshed in chocolate-peanut spread (water activity [aw] of 0.46; D60 degrees C = 37.5 min) and peanut butter (aw of 0.32; D60 degrees C = 26.0 min) than in liquid products. At 10 degrees C, the pathogen grew most rapidly in whole-fat chocolate milk and slowest in peanut beverage. At 22 degrees C, populations increased significantly within 12 and 16 h in whole-fat milk and reduced-fat chocolate milk, respectively, and within 8 h in whole-fat chocolate milk and peanut beverage. Initial populations (3.37 to 4.42 log CFU/g) of L. monocytogenes in chocolate-peanut spread and peanut butter adjusted to an aw of 0.33 and 0.65 declined, but the pathogen was not eliminated during a 24-week period at 20 degrees C. Survival was enhanced at reduced aw. Results indicate that a pasteurization process similar to that used for full-fat milk would be adequate to ensure the destruction of L. monocytogenes in peanut beverage. The pathogen survives for at least 24 weeks in chocolate-peanut spread and peanut butter at an aw range that encompasses that found in these products.     

Location of Escherichia coli O157:H7 on and in apples as affected by bruising, washing, and rubbing

Confocal scanning laser microscopy (CSLM) was used to determine the location of Escherichia coli O157:H7 cells on the surface and in tissue of bruised Red Delicious cv. apples. Undamaged and bruised apples were inoculated by immersing in a suspension of E. coli O157:H7 cells transformed with a plasmid that encodes for the production of a green fluorescent protein. Apples were then washed in 0.1% (wt/vol) peptone water and/or rubbed with a polyester cloth and examined to determine if these treatments removed or introduced cells into lenticels, cutin, and cracks on the skin surface. Optical slices of the apples obtained using CSLM were examined to determine the depth at which colonization or attachment of cells occurred. Populations of E. coli O157:H7 on the surface of apples were determined to assess the effectiveness of washing and rubbing in physically removing cells. The location of cells on or in undamaged and bruised areas of apples that were not washed or rubbed did not differ significantly. However, washing apples resulted in an approximate 2-log reduction in CFU of E. coli O157:H7 per cm2 of apple surface. On unwashed apples, cells were detected at depths up to 30 microm below the surface. No E. coli O157:H7 cells were detected at locations more than 6 microm below the surface of washed apples. Cells that remained on the surface of rubbed apples appeared to be sealed within naturally occurring cracks and crevices in waxy cutin platelets. These cells may be protected from disinfection and subsequently released when apples are eaten or pressed for cider production.     

Frequency response computation via rational interpolation

A simple rational interpolation method is given for estimating a frequency response matrix. The method is based on a generalization of the resolvent identity that avoids the potential inaccuracies introduced by the subtraction of nearly equal values in the calculation of the difference terms. When coupled with a pole cancellation method, the resulting interpolation algorithm is accurate and efficient. The error in this procedure has the form of a modified response matrix, which means that the interpolation algorithm can be used to approximate both the response matrix and the error     

Partial wetting in trickle bed reactors — the reduction of crotonaldehyde over a palladium catalyst

The behavior of a trickle bed in which the catalytic packing was incompletely wetted was investigated using the selective hydrogenation of crotonaldehyde to n-butyraldehyde as a model reaction. The reaction was carried out at near ambient conditions using palladium deposited on porous alumina pellets as the catalyst. It was found that even when the extent of wetting was large, reaction taking place on the dry parts of the catalyst largely dominated the overall reaction rate.