Solution-Processed n-Type Organic Field-Effect Transistors With High on /off Current Ratios Based on Fullerene Derivatives

Solution-processed n-type organic field-effect transistors (OFETs) based on the fullerene derivative {6}-1-(3-(2- thienylethoxycarbonyl)-propyl)-{5}-l-phenyl-[5,6]-C61 (TEPP) and phenyl-C61-butyric acid methyl ester (PCBM) in a multiring source/drain structure are reported. Devices with TEPP show high electron mobility up to 7.8 x 10^-2 cm²/Vs in the saturation regime for bottom-contact OFETs with Au S/D electrodes with a solution-processed fullerene derivative. The ON/OFF ratios reported in this letter, which are in the range of 10⁵ -10⁶, are among the highest values reported for such devices. This mobility is always higher compared to PCBM devices prepared in identical conditions. The mobility of TEPP and PCBM increased with increasing temperatures in the range of 100-300 K with activation energy of 78 and 113 meV, respectively, which suggests that the thermally activated hopping of electrons is dominant in TEPP.     

Performance of space-time codes for a large number of antennas

We study the asymptotic behavior of space-time codes when the number of transmit and receive antennas grows to infinity. Specifically, we determine the behavior of pairwise error probabilities with maximum-likelihood (ML) decoding and with three types of receiver interfaces: the ML interface, the linear zero-forcing (ZF) interface, and the linear minimum-mean-square-error (MMSE) interface. Two situations are studied: when the number of receiving antennas grows to infinity while the number of transmitting antennas is finite, and when both numbers grow to infinity but their ratio remains constant. We show that with ML or linear interfaces the asymptotic performance of space-time codes is determined by the Euclidean distances between codewords. Moreover, with the two linear interfaces examined here the number r of receive antennas must be much larger than the number t of transmit antennas to avoid a sizeable loss of performance; on the other hand, when r ≫ t, the performance of these linear interfaces comes close to that of ML. The dependence of error probabilities on Euclidean distance is valid for intermediate signal-to-noise ratios (SNRs) even when the number of antennas is small. Simulations validate our theoretical findings, and show how asymptotic results may be substantially valid even in a nonasymptotic regime: thus, even for few antennas, off-the-shelf codes may outperform space-time codes designed ad hoc     

Influence of Ti Powder Characteristics on Combustion Synthesis of Porous NiTi Alloy

Porous NiTi shape memory alloy (SMA) is a novel biomedical material used for human hard tissue implant .The influence of elemental titanium powder characteristics such as powder morphology, particle size and specific surface area( SSA) on the minimal ignition temperature ,combustion temperature and final product of porous Ni-Ti SMA fabricated by combustion synthesis method was investigated in this paper by scanning electron microscopy (SEM) and laser diffraction.The preliminary data indicated that the titanium powder characteristics had a strong effect on combustion synthesis of porous NiTi SMA.     

Mechanical and microstructure studies on the modification of CA film by blending with PS

DriedMusa paradiciaca (banana) stem and veins of the leaves, which were hitherto discarded as a waste, were collected and used as starting material for the preparation of cellulose and cellulose acetate. This cellulose acetate was mixed with polystyrene to form blend of cellulose acetate-polystyrene in order to provide enhanced stability and extended utility to the end products. The films of these composites or their individual partners were made separately and studied for their mechanical properties, chemical modification and morphological changes. We report here that banana stem is good source of cellulose and that cellulose completely undergoes modification upon esterification.     

Vapor phase synthesis of ZnO structures

We observed zinc oxide structures formed in an oxygen-containing atmosphere as a result of oxidation of the surface of zinc droplets. The gas-phase oxidation leads to the formation of hollow ZnO whiskers on the metal surface, which grow due to the transport of zinc vapor through their channels. It was found that high partial pressures of zinc and atomic oxygen give rise to fractal structures, which appear in a cascade process involving the sequential formation of zinc oxide vapor, ZnO clusters, and cluster aggregates as a result of the cluster-cluster interaction. A deposit of ZnO synthesized on the cathode surface exhibits a columnar structure.     

The Year 2015 Fusion Power Conversations

Assuming significant technical success in the ITER project by the year 2015, it is likely that governments will want to develop a more comprehensive plan for DT tokamak fusion power commercialization. To provide a glimpse into many of the related issues, we construct conversations between the director of the U.S. fusion program and three specialists key to commercial fusion success: an environment and safety regulator, an environmentalist, and an electric generation investor. The insights from these imagined conversations will hopefully be of value as tokamak fusion power proponents plan beyond ITER.     

Dynamic light scattering by gels under hydrostatic pressure

Measurements of variation with pressure of the collective diffusion constant D_c in polyacrylamide gels using both a good solvent (water) and a theta solvent (methanol 30% - water 70% by volume) are reported. From these observations the variation of ξ_h, the hydrodynamic screening length in the gel, is obtained, and compared with ξ_st, the static screening length. The latter is obtained from measurements of the density of the polymer solutions. In the concentration range studied (3%–10%) and for pressures up to 3 kbar, both ξ_h and ξ_st diminish with increasing pressure (i.e. the solvent quality improves), but the variation of ξ_h is more than an order of magnitude smaller than ξ_st for both the poor and good solvent cases.     

Metabolic-heat relation for aerobic yeast respiration and fermentation

A specially developed temperature control system on a laboratory scale fermenter enabled continuous measurement of the rate of heat production during undisturbed growth of microbial cultures. Apart from being correlated with oxygen uptake rate, the heat of fermentation was established as an additional indicator of metabolic activity. The ‘aerobic respiration’ energetic activity of Candida utilis, Candida lipolytica and Saccharomyces cerevisiae on different carbon substrates was investigated with cultures of the latter species being also studied under the ‘aerobic fermentation’ conditions induced by glucose catabolite repression.     

Microsomal and photochemical oxidation of aflatoxin B1

The UV irradiation (lambda = 362 nm) of aflatoxin B1 (AfB1) dissolved in water resulted in the formation of an oxidized product. The process was not inhibited by ionol, a routine inhibitor of the radical processes. The oxidized product was not found in the system where AfB1 was metabolized by the 3-methylcholanthrene-activated rat liver microsomes. It is suggested that the product is identical with 2,3-dihydrodiol of AfB1.     

Functionalization of soluble polymers

Summary The synthesis of di-(4-formylphenyloxyethyl) poly(oxyethylene) and the corresponding oxime derivative are described. Kinetic aspects of the reaction of the dichloro telechelic with 4-hydroxy benzaldehyde are investigated and discussed.